The dynamic viscoelastic behavior of polysiloxanes filled with ultrafine SiO 2 has become ever-lasting important due to its unique properties. In present article, the influence of SiO 2 treated with silane coupling ag...The dynamic viscoelastic behavior of polysiloxanes filled with ultrafine SiO 2 has become ever-lasting important due to its unique properties. In present article, the influence of SiO 2 treated with silane coupling agent bis(3-triethoxysilyl)tetrasulfane(TESPT) on dynamic viscoelastic properties of uncured polymethylvinylsiloxane(PMVS)/ultra fine-silica(SiO 2) composites was investigated by using an advanced rheometric expansion system(ARES) under the conditions of temperature 25 ℃, strain(γ) from 0.01% to 100% and frequency(ω) from 0.01 to 100 rad/s. The results reveal that the treated SiO 2 particles leads to the frequency-dependent storage modulus(G′) which approaches linear viscoelastic behavior in the lower frequency region. Based on an examination of the dynamic viscoelastic behavior and TEM observation, we owe these characteristics to improved dispersion of SiO 2 particles in the polymer matrix due to their surface-treatment as compared with the untreated case. On the other hand, dynamic viscoelastic behavior sensitively reflects the dispersion of SiO 2 particles with diameters from 100 to 500 nm, which further evidence the promotion of filler dispersion induced by the incorporation of TESPT.展开更多
Over the past years, great achievements have been made in the development of coating technologies for surface improvement of aluminum alloys. Despite these achievements, the role in the market strongly depends on the ...Over the past years, great achievements have been made in the development of coating technologies for surface improvement of aluminum alloys. Despite these achievements, the role in the market strongly depends on the ability of surface coating technology under technical and economic considerations to meet the increased demands for heavy tribological applications of aluminum alloys. Microplasma oxidation (MPO) technology has recently been studied as a novel and effective means to provide thick and hard ceramic coating with improved properties such as excellent load-bearing and wear resistance properties on aluminum alloys. The present work covers the evaluation of the performances of current single and duplex coatings combining MPO, physical vapor deposition (PVD), and plasma assisted chemical vapor deposition (PACVD) coatings on aluminum alloys. It suggests that the MPO coating is a promising candidate for design engineers to apply aluminum alloys to heavy load-bearing applications. The prospective future for the research on MPO coatings is introduced as well.展开更多
文摘The dynamic viscoelastic behavior of polysiloxanes filled with ultrafine SiO 2 has become ever-lasting important due to its unique properties. In present article, the influence of SiO 2 treated with silane coupling agent bis(3-triethoxysilyl)tetrasulfane(TESPT) on dynamic viscoelastic properties of uncured polymethylvinylsiloxane(PMVS)/ultra fine-silica(SiO 2) composites was investigated by using an advanced rheometric expansion system(ARES) under the conditions of temperature 25 ℃, strain(γ) from 0.01% to 100% and frequency(ω) from 0.01 to 100 rad/s. The results reveal that the treated SiO 2 particles leads to the frequency-dependent storage modulus(G′) which approaches linear viscoelastic behavior in the lower frequency region. Based on an examination of the dynamic viscoelastic behavior and TEM observation, we owe these characteristics to improved dispersion of SiO 2 particles in the polymer matrix due to their surface-treatment as compared with the untreated case. On the other hand, dynamic viscoelastic behavior sensitively reflects the dispersion of SiO 2 particles with diameters from 100 to 500 nm, which further evidence the promotion of filler dispersion induced by the incorporation of TESPT.
文摘Over the past years, great achievements have been made in the development of coating technologies for surface improvement of aluminum alloys. Despite these achievements, the role in the market strongly depends on the ability of surface coating technology under technical and economic considerations to meet the increased demands for heavy tribological applications of aluminum alloys. Microplasma oxidation (MPO) technology has recently been studied as a novel and effective means to provide thick and hard ceramic coating with improved properties such as excellent load-bearing and wear resistance properties on aluminum alloys. The present work covers the evaluation of the performances of current single and duplex coatings combining MPO, physical vapor deposition (PVD), and plasma assisted chemical vapor deposition (PACVD) coatings on aluminum alloys. It suggests that the MPO coating is a promising candidate for design engineers to apply aluminum alloys to heavy load-bearing applications. The prospective future for the research on MPO coatings is introduced as well.
