金矿样品中金的粒度判定及在标准物质研制中的应用

采用"重复分析测定-筛上残金比-人工重砂鉴定"的方法判断矿石样品中的金是否以微细粒级形式均匀分布,此法可用于指导分析样品制样,提高小试样品的代表性。方法用于金厂金矿标准物质候选物检验,根据小试样品的粒度实验结果选用180目筛和50%过筛率进行人工过筛实验,筛下样品经球磨混匀后可作为该矿金矿石标准物质。

泡塑埋入法找金应用效果及发展前景

本文重点阐明了利用泡塑埋入法找金,从找矿机理和应用效果,均优于土壤测量法。该法能消除“粒金效应”,减少次生晕运移现象,对找隐伏矿体和盲矿体能强化异常,是解决次生晕运移、覆盖厚、找矿难的有效方法之一。在实际找矿应用中,该法具有简单、快速、成本低、找矿周期短、效率高、找矿效果好的特点,获得明显的经济效益和找矿效果。该法进一步改进和完善后,将有广阔的发展前景。

对超痕量金化学光谱分析中结果波动原因的探讨

对超痕量金化学光谱分析中结果波动的原因进行了探讨，指出不正确的制样方法、粒金效应和方法本身的不足是引起数据波动的主要原因。提出通过增加分析取样量，控制灰分及缩短曝光时间有利于提高超痕量金分析结果的可靠性。

佳木斯隆起带乌拉嘎断裂西缘1∶5万水系沉积物测量方法研究

前人研究成果表明,有机质吸附作用使样品中的元素产生一定的富集,这种影响随着有机质含量增加而越加强烈,将掩盖元素真实含量的起伏,造成假异常。通过对佳木斯隆起带乌拉嘎断裂西缘水系沉积物样品的分配及有机质含量特征、主要成矿元素的表生地球化学分布特征的研究,认为野外截取-10^+60目粒级段作为采样介质,可完全满足工作需要,获得真实可靠的地球化学异常,取得较好的地质找矿效果。

Microstructure,mechanical and shape memory properties of Ti-55Ta-xSi biomedical alloys

The effects of Si addition on microstructures, mechanical and shape memory properties of Ti-55Ta biomedical alloy were investigated. The results show that the microstructures consist of mainly α′′ martensite and a little β phase, and the grain size decreases obviously with increasing Si addition. When x = 0.2, small （Ti, Ta）3Si precipitates are formed at grain boundaries. With further increasing Si content, the amount of the precipitates gradually increases. The tensile and yield strength of Ti-55Ta-xSi alloys gradually increase with increasing Si addition, whereas elongation decreases. Ti-55Ta-0.1Si alloy exhibits the lowest elastic modulus and the best shape memory recoverable strain. It is revealed that the refinement of grain and the precipitation of （Ti, Ta）3Si phase are responsible to the changes of their mechanical and shape memory properties.

Ag-Ni alloy nanoparticles for electrocatalytic reduction of benzyl chloride

Ag-based nanocatalysts exhibit good catalytic activity for the electrochemical reduction of organic halides. Ag-Ni alloy nanoparticles（NPs） were facilely prepared by chemical reduction, and the as-prepared nanocatalysts were characterized by X-ray diffraction, ultraviolet-visible spectroscopy, transmission electron microscopy and energy-dispersive X-ray spectroscopy. The electrocatalytic activity of Ag-Ni NPs for benzyl chloride reduction was studied in organic medium using cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy. The results show that the addition of Ni element can obviously decrease the size of Ag-Ni NPs, shift the reduction peak potential（φp） of benzyl chloride positively, and increase the catalytic activity of Ag-Ni NPs. However, when the Ni content reaches a certain value, the catalytic activity of Ag-Ni NPs decreases. Meanwhile, the synergistic catalytic effect of Ag-Ni NPs was also discussed.

FE-based coupling simulation of Ti60 alloy in isothermal upsetting process

A constitutive equation was proposed to describe the effect of grain size on the deformation behavior.And a coupling simulation of deformation with heat transfer and microstructure was carried out in isothermal upsetting process of Ti60 alloy.The effects of processing parameters on the equivalent strain,the equivalent stress,the temperature rise and the grain size distribution in isothermal upsetting process of Ti60 alloy were analyzed.It is concluded that the uniformity of equivalent strain and equivalent stress increases with the increase of deformation temperature.However,the temperature rise and the grain size decreases with the increase of deformation temperature.The non-uniformity of equivalent strain,equivalent stress,temperature field and grain size increases with the increase of height reduction.And the calculated grain size using simulation is in good agreement with the experimental one.

Correlation between catalytic activity of supported gold catalysts for carbon monoxide oxidation and metal–oxygen binding energy of the support metal oxides

The effect of a wide variety of metal oxide （MOx） supports has been discussed for CO oxidation on nanoparticulate gold catalysts. By using typical co‐precipitation and deposition–precipitation methods and under identical calcination conditions, supported gold catalysts were prepared on a wide variety of MOx supports, and the temperature for 50%conversion was measured to qualita‐tively evaluate the catalytic activities of these simple MOx and supported Au catalysts. Furthermore, the difference in these temperatures for the simple MOx compared to the supported Au catalysts is plotted against the metal–oxygen binding energies of the support MOx. A clear volcano‐like correla‐tion between the temperature difference and the metal–oxygen binding energies is observed. This correlation suggests that the use of MOx with appropriate metal–oxygen binding energies （300–500 kJ/atom O） greatly improves the catalytic activity of MOx by the deposition of Au NPs.

Higher Order Multipole Potentials and Electrostatic Screening Effects on Cohesive Energy and Bulk Modulus of Metallic Nanoparticles

Higher order rnultipole potentials and electrostatic screening effects are introduced to incorporate the dan gling bonds on the surface of a metallic nanopaticle and to modify the coulornb like potential energy terms, respectively. The total interaction energy function for any rnetallic nanoparticle is represented in terms of two- and three-body potentials. The two-body part is described by dipole-dipole interaction potential, and in the three-body part, triple-dipole （DDD） and dipole-dipole-quadrupole （DDQ） terrns are included. The size-dependent cohesive energy and bulk modulus are observed to decrease with decreasing sizes, a result which is in good agreement with the experimental values of Mo and W nanoparticles.

Sponge-templating synthesis of sandwich-like reduced graphene oxide nanoplates with confined gold nanoparticles and their enhanced stability for solar evaporation

Solar evaporation based on plasmonic metal nanoparticles(MNPs)is emerging as a promising technology.However,the fine structure of MNPs is unstable,and both the high temperature generated by intensive light and corrosive ions in water could damage them.The performance will decline after recycling and long-time usage.To address these issues,we adopted a sponge-templating method for preparing sandwich-like nanoplates with the gold nanoparticles(Au NPs)confined in reduced graphene oxide(rGO)nanosheets.Due to the confinement effect,both the surface melting and ion diffusion were suppressed.The solar evaporator based on the sandwich-like nanoplates showed a high solar-vapor conversion efficiency of 85.2%under a high light intensity of 10 kW.After 30 times recycle of seawater desalination,the conversion efficiency scarcely decreased.These sandwich-like nanoplates with enhanced thermal and chemical stability of Au NPs are promising in the practical application of seawater desalination.

Electron transport properties of magnetic granular films

In this paper,we present a review of electron transport properties of magnetic granular films.Magnetic granular films are nanocomposite materials which consist of magnetic nanoparticles embedded in a nonmagnetic matrix or assembling of magnetic nanoparticles.According to the style of the nonmagnetic matrix,microstructure and the electron transport mechanism of the films,the magnetic granular films were divided into three groups:(1) magnetic metal-metal granular films,(2) magnetic metal-insulator granular films and(3) magnetic nanocluster-assembled granular films.Moreover,we also systematically review the magnetic properties,transport properties and magnetoresistance effect of size-monodispersed Co and Fe nanocluster-assembled films.

Experimental characterization of the bipolar effect on P-hit single-event transients in 65 nm twin-well and triple-well CMOS technologies

Single-event charge collection is controlled by drift, diffusion and the bipolar effect. Previous work has established that the bipolar effect is significant in the p-type metal-oxide-semiconductor field-effect transistor(PMOS) in 90 nm technology and above. However, the consequences of the bipolar effect on P-hit single-event transients have still not completely been characterized in 65 nm technology. In this paper, characterization of the consequences of the bipolar effect on P-hit single-event transients is performed by heavy ion experiments in both 65 nm twin-well and triple-well complementary metal-oxide-semiconductor(CMOS) technologies. Two inverter chains with clever layout structures are explored for the characterization. Ge(linear energy transfer(LET) = 37.4 Me V cm^2/mg) and Ti(LET = 22.2 Me V cm^2/mg) particles are also employed. The experimental results show that with Ge(Ti) exposure, the average pulse reduction is 49 ps(45 ps) in triple-well CMOS technology and 42 ps(32 ps) in twin-well CMOS technology when the bipolar effect is efficiently mitigated. This characterization will provide an important reference for radiation hardening integrated circuit design.