粘土性能与陶艺造型成型关系研究

不同的粘土材料性能,往往产生不同的陶瓷造型艺术效果。可以在不影响粘土固有的烧成效果的基础上,合理添加有益的化学物质或有机物,以改变粘土的性能,以适合成型方式、烧成制度和最终视觉效果呈现。

浅述陶瓷和瓷器的差别及粘土的性能

一：陶瓷和瓷器的区别 通俗地讲：用陶土烧制的器皿叫陶器，用瓷土烧制的器皿叫瓷器。陶瓷则是陶器、炽器和瓷器的总称。儿是用陶土和瓷土这两种不同性质的粘土为原料．经过配料、成型、干燥、焙烧等工艺流程制成的器物都可以叫陶瓷。

BOND PERFORMANCE EXPERIMENT FOR FLY ASH CONCRETE AND STEEL BAR

The impact of fly ash content on bond performance of steel bars and their surrounding concrete is studied by means of sticking strain gauges on steel bars. The average bond stress-slip curves, the steel strain-anchor location curves, and the bond stress-anchor position curves of the pullout specimens with various fly ash contents are obtained. Results indicate that the bond performance of concrete and steel bars can be improved and the distribution of steel strain along the anchorage length tends to be more uniform by adding fly ash in concrete specimens, and both ultimate bond stress and ultimate slip deformation increase the most when 20% of specimens′ content is fly ash.

Reliability analysis for anchorage of reinforced concrete beams with longitudinal cracks due to corrosion at anchorage zone

An anchorage reliability analysis approach for simply supported reinforced concrete beams under corrosion attack in the anchorage zone is developed.The first-order second-moment method is employed to analyze the effects of various factors on the anchorage reliability.These factors include both the length and width of cover cracking due to reinforcement corrosion,the cover thickness,the anchorage length,and the stirrup ratio.The results show that the effect of corrosion-induced crack length on the reliability index for anchorage,β0,is negligible when the crack on the concrete surface is just appearing,but with the crack widening,the β0 value is reduced significantly;the considerable changes in β0 result from a variation in cover depth and anchorage length;the effect of changes in the diameter or space of stirrups on the anchorage resistance is very limited,and the variation in β0 is also very low.

Experimental research on unloading properties of clay under high stress

Abstract： Mechanical properties of clay under high stress are quite different from those under low stress. It is necessary to investi- gate unloading properties of clay under high stress for the design and construction of deep underground engineering projects. A series of experiments were conducted to investigate the unloading properties of clay under high confining pressures by using a SKA-1 high pressure consolidation instrument designed by us. The stress versus strain relationship and the way that K0 values of clay change during the loading-unloading process were discovered. The results show that there are clear differences in the state of stress and deformation behavior of the clay along different unloading paths.

Membrane behavior of bentonite-amended Fukakusa clay in K, Na and Ca solutions

Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance with regard to the migration of contaminants. In this work, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior toward different kinds of ions： K, Na and Ca. The chemico-osmotic efficiency coefficient, co, was obtained in electrolyte solution with different concentrations of 0.5, 1, 5, 10, and 50 mmol/L. According to the results, solute type and ion valence have a significant effect on membrane behaviors. Additionally, co continually decreased as the Na and Ca concentrations increased, which is consistent with the Gouy-Chapman theory. The membrane behavior toward Na was similar to that toward K, according to the chemico-osmotic efficiency coefficient co. In the case of the divalent ion Ca, the membrane behavior was lower compared to monovalent ions Na and K at the same concentration. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free-swelling results and SEM images.

Thermal Effects on Bond Properties of GFRP Rebars Embedded in Concrete

This paper presents the results of an experimental study on the thermal effects on glass fibre reinforced polymer （GFRP） bars embedded in concrete. The pullout test specimens were subjected to temperatures of 40℃, 60℃ and 80℃ during a continuous four months-period of time. The results were compared to the reference specimens （room temperature）. It was found that up to 60℃, the loss in bond strength due to the temperature is not significant, whereas for the 80℃-temperature a reduction of 14% in the bond strength is observed. Also, the bond-slip relationship was modelled using the CMR-model and new coefficients are proposed for the bond-slip behaviour of GFRP bars.

Digital core approach to the effects of clay on the electrical properties of saturated rocks using lattice gas automation

Clay has a significant influence on the relationship between resistivity index I and water saturation Sw （i.e, I-Sw relationship） of reservoir rocks because it complicates the current paths of these rocks. It is difficult to reveal the physical mechanisms of these clay effects on the conductivities of various rocks by physical laboratory measurements because the pore structure, micro distribution and content of clay inside a rock can not be observed and controlled during the experiments. We present a digital rock approach to study these clay effects on the electrical transport properties of reservoir rocks at pore scale using lattice gas automation （LGA） method. The digital rock samples are constructed with the information of grain size distribution from SEM images of reservoir rocks. The LGA is then applied on these digital rocks fully saturated with fluids to simulate the electrical transport properties for revealing the effects of volume and distribution patterns of clay on the non-Archie behaviors of the I-Sw relationship. The very good agreement between the simulated results and the laboratory measurements clearly demonstrates the validity of the LGA in numerical research of rock physics. Based on these studies, a new model has been developed for quantitatively describing the relationship between the saturation exponent and the volume of clay （Vsh）. This development may improve the evaluation for the fluid saturations in reservoir rocks.

Effect of nanoclay on properties of porous PVdF membranes

The main requirements for battery separators are high porosity which can serve pathways of lithium ion and space for gel electrolytes to impregnate in a membrane and mechanical strength to allow easy handling for battery assembly. Generally, it appears the trade-off relationship between the porosity and mechanical strength of the membrane. PVdF composite membranes containing nano-size clays were used to improve the mechanical strength of the membrane without affecting the membrane porosity. The composite membranes were prepared by phase inversion method controlling the membrane preparation conditions such as retention time. The resultant membranes show increased mechanical properties with similar membrane porosity around 80 % compared to the pristine PVdF membrane. Incorporation of nonoclay can be considered as an effective method to improve the mechanica! strength in porous membrane supports, especially in a separator.

Application of Modified Attapulgite Clay as the Adsorbent in Gasoline Desulfurization

Attapulgite clay is a kind of special silicate mineral with high adsorption capacity thanks to its loose structure and porous surface. In this paper, the attapulgite clay was treated effectively with acid under microwave thermal activation and ultrasonic vibration, respectively, and characterized by XRD, N2 adsorption, FT-IR and SEM. The desulfurization performance of the modified attapulgite clay was then evaluated by using simulated gasoline as the feed. The test results showed that the thiophene removal rate increased with an increasing dosage of hydrochloric acid during microwave modification of attapulgite clay. When the concentration of hydrochloric acid reached 15%, the increase of desulfurization rate became slower, and the desulfurization rate was about 69%.

Modification of HDPE filling with pelagic clay

In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composites of organic pelagic clay/HDPE by inching them in different conditions. The affections of process conditions and quantity of pelagic clay to the properties of composites were analyzed by testing their mechanical properties, thermo stability and barrier properties. According to test the structure of composites, it is indicated that pelagic clay has good compatibility with HDPE. The result shows that the pelagic clay can improve mechanical properties, thermo stability and barrier properties of HDPE properties effectively.

高液限红粘土路用特性与沉降变形规律

贵州遵贵扩容高速公路沿线分布有大量红粘土,其具有高液限、高塑性指数、高天然含水率的特点,为明确其路用性能及路基的沉降变形规律,开展了室内试验、红粘土路基填筑现场试验、路基沉降长期跟踪观测等一系列研究。结果表明:当红粘土稠度在1.10~0.88或含水率在25%~35%之间时,其CBR值满足规范要求,可用于路基填筑;其路基沉降曲线类似于抛物线,呈"先陡后缓"的总体趋势,在填筑施工期间沉降较大,约占总沉降的50%;填筑完成之后在自然沉降期其工后沉降并不大,且自然沉降期头半年的路基沉降占大多部分。因此,对于红粘土填方路基,铺筑路面前宜预留半年的自然沉降稳定期。

Study on the performance of ternary blended cement with calcined clay and recycled concrete powder

Recycled concrete powder (RCP) has a large amount of calcium carbonate, which suggests that it can be used to make limestone - calcined clay (CC) cement (LC^(3)) system by replacing limestone powder. So that it can promote the recycling of construction demolition waste and reduce the requirement of the natural resource for LC^(3). In this study, the fresh and hardened properties of CC-RCP cement system were comprehensively characterized by varying the CC/RCP ratio and dosage, including rheological, mechanical properties, hydration products and pore structure. The results indicate that the addition of CC prolong the setting time, but the effect could be mitigated by the recombination of RCP. By comparing with RCP, CC had a less obvious effect on increasing viscosity, but it could improve the shear thickening behavior of paste. In the case of less total content of CC and RCP, a ratio of 1:1 CC/RCP was better for the development of long-term strength. Whereas, with the increasing of substitution, the mixtures with CC alone or blending with RCP in a 2:1 ratio achieved higher strength. The incorporating of CC and RCP could make the conversion of C4AH13 into hemicarboaluminate (Hc) and monocarboaluminate (Mc), and it resulted in a denser structure with more medium capillary pores and gel pores than that mixtures with CC only.

Effects of Al_2O_3 nanoparticles on properties of self compacting concrete with ground granulated blast furnace slag (GGBFS) as binder

In this work, strength assessments and percentage of water absorption of self compacting concrete containing ground granulated blast furnace slag （GGBFS） and A1203 nanoparticles as binder have been investigated. Portland cement was replaced by different amounts of GGBFS and the properties of concrete specimens were investigated. Although it negatively impacts the physical and mechanical properties of concrete at early ages of curing, GGBFS was found to improve the physical and mechanical properties of concrete up to 45 wt% at later ages. A1203 nanoparticles with the average particle size of 15 nm were added partially to concrete with the optimum content of GGBFS and physical and mechanical properties of the specimens were measured. A1203 nanoparticle as a partial replacement of cement up to 3.0 wt% could accelerate C-S-H gel formation as a result of increased crystalline Ca（OH）2 amount at the early ages and hence increase strength and improve the resistance to water permeability of concrete specimens. The increase of the A1203 nanoparticles＇ content by more than 3.0 wt% would cause the reduction of the strength because of the decreased crystalline Ca（OH）2 content required for C-S-H gel formation. Several empirical relationships have been presented to predict flexural and split tensile strength of the specimens by means of the corresponding compressive strength at a certain age of curing. Accelerated peak appearance in conduction calorimetry tests, more weight loss in thermogravimetric analysis and more rapid appearance of the peaks related to hydrated products in X-ray diffraction results, all indicate that A1203 nanoparticles could improve mechanical and physical properties of the concrete specimens.

Clay-protein ultrathin films:Design and bio-catalytic performance study

In recent years, immense interest has been paid to the biomolecular architecture with the aim of protein assembly in two di- mensions on solid substrates, and the constructions of clay-protein ultrathin films （CPUFs） are particularly concerned. This paper gives an overview of the recent research concerning the protein molecules （lysozyme, papain, protamine, bovine serum albumin） immobilized on clay mineral （Na-saponite） platelets and assembled in monolayered or multilayered hybrid ultrafilms or nanofilms. Two techniques including alternate layer-by-layer （LbL） assembly and the Langmuir-Blodgett （LB） are de- scribed in detail. A variety of means, including UV-vis absorption, attenuated total reflectance Fourier transform infrared （ATR-FTIR） spectroscopy, XRD, AFM and surface chemistry techniques, have been described for characterization of the films in terms of quantification of protein and clay. The result reveals that electrostatic interaction is a prominent but not the only driving force in CPUF construction. In the case of LB technique, we managed to manipulate the elementary clay mineral platelets （1.3 nm in thickness） and assemble proteins into CPUFs with the aid of surfactants, and the formation of CPUFs was monitored via surface pressure vs. time （a--t） kinetics curves and surface pressure vs. area （a--A） isotherms. The factors that in- fluence protein adsorption on the clay layer, such as surfactants, the concentration of clay, equilibrium time, categories of pro- tein, and injection methods, were investigated. The parameters such as protein amount （nS）, packing density （O）, and average surface area per molecule （.（2） of deposited CPUFs were measured via method of surface chemistry and spectroscopy. By comparing the results of surface chemistry with those of adsorption experiments, we demonstrate that the surface chemistry method is a useful tool in investigating CPUFs. We also found that the water soluble protein molecules could form protein-clay hybrid monolayer over the dilute clay dispersions without addition of surfactants, and CPUFs containing elementary clay sheets and protein with great homogeneity were easily prepared by controlling certain surface pressure. To investigate the bio-catalytic performance of the immobilized lysozyme in CPUFs, we deposited CPUFs onto a cover glass, and installed the cover glass in a flow cell-grown reactor for Comamonas testosteroni （WDL7-GFP） incubation. The results show that the pro- liferation of WDL7-GFP is greatly suppressed by lysozyme, which demonstrates that lysozyme still retains its bioactivity after it is immobilized in the CPUFs.

State of the art review on the production and bond behaviour of reinforced geopolymer concrete

Geopolymer is produced through the polymerization of active aluminosilicate material with an alkaline activator,leading to the formation of a green,inorganic polymer binder.Geopolymer concrete(GPC)has become a promising low-carbon alternative to traditional Portland cement-based concrete(OPC).GPC-bonded reinforcing bars offer a promising alternative for concrete structures,boasting excellent geopolymer binder/reinforcement bonding and superior corrosion and high-temperature resistance compared to Portland cement.However,due to differences in the production process of GPC,there are distinct engineering property variations,including bonding characteristics.This literature review provides an examination of the manufacturing procedures of GPC,encompassing source materials,mix design,curing regimes,and other factors directly influencing concrete properties.Additionally,it delves into the bond mechanism,bond tests,and corresponding results that represent the bond characteristics.The main conclusions are that GPC generally has superior mechanical properties and bond performance compared to ordinary Portland cement concrete(OPC).However,proper standardization is needed for its production and performance tests to limit the contradictory results in the lab and on site.