泥质砂岩地层的粘土性质分析

地层中粘土的存在对测井解释结果起着十分重要的影响,是造成测井解释复杂性的重要原因之一。正确地分析地层中的粘土性质,有助于测井解释人员更加全面地进行泥质砂岩储层的油气评价。以粘土测井特征和中子—密度测井交会法为基础,对每个泥质砂岩资料点确定其粘土性质,按合水泥质砂岩模型计算地层粘土含量;用粘土的阳离子交换量与干粘土含氢指数的交会来识别粘土类型。实践证明,该方法对物性较差的低渗透储集层以及低电阻率油气层有优越性,但对含轻烃的地层不适用。

泥质砂岩地层的粘土性质分析

粘土具有复杂的矿物成分和物理化学性质。在地层中，粘土的成分、含量及分布类型又有很大变化，因此，地层中粘土的存在对测井解释结果起着十分重要的影响，是造成测井解释复杂性的重要原因之一。所以，正确地体质地层中的粘土性质，有助于测井解释人员更加合理地进行泥质砂岩储层的油气评价。该文在分析粘土测井特征的基础上，提出了一种利用常规测井资料分析地层粘土性质的方法。

粘土的物理化学性质在窖泥研究中的作用

1.粘土表面的4种作用(1)氢键的相互作用;(2)矿物表面交换性阳离子二的水合作用;(3)矿物表面过剩负电荷产生的电场;(4)水分子和表面氧原子之间的色散力。以上4种作用对培养窖泥和土壤微生物起着重要作用。2.腐植质是窖泥中非常重要的组分在正常情况下,窖泥的质量与腐植质含量成正相关性。四川省五粮液洒厂的百年特曲老窖腐植质含量为7.5～15.2%,较长时间的头曲窖腐植质含量5.5～10.3%。我们在河南伊川杜康酒的研究中,窖泥中腐植质含量表层高于中层,中层高于深层。

粘土结构和粘土-水系统辩证解析及其教学实施

对粘土结构和粘土-水系统性能进行了辩证解析。基于电荷平衡的性质,结合库仑定律,从科学角度和辩证角度对粘土荷电性质进行了分析。在此基础上对粘土结构和粘土-水系统相关性质,即粘性、可塑性、悬浮性的辩证内涵进行了分析。对课程教学中引导学生进行辩证思维以帮助学生提高学习效率的教学方法进行了探索。

铁（Ⅲ）离子与钠─蒙脱土交换反应研究

铁（Ⅲ）离子与钠─蒙脱土交换反应研究陈光明，赵扬，韩布兴，阎海科（中国科学院化学研究所北京１０００８０）在能源、环境等许多重大领域都涉及粘土问题。蒙脱土是一种重要的粘土，其结构和性质与它所带金属离子的种类直接相关。因此，前人在多属离子与蒙脱土交换反应...

Parametric Study on the Effects of Pile Inclination Angle on the Response of Batter Piles in Offshore Jacket Platforms

Offshore jacket-type platforms are attached to the seabed by long batter piles. In this paper, results from a finite element analysis, verified against experimental data, are used to study the effect of the pile＇s inclination angle, and its interaction with the geometrical properties of the pile and the geotechnical characteristics of the surrounding soil on the behavior of the inclined piles supporting the jacket platforms. Results show that the inclination angle is one of the main parameters affecting the behavior of an offshore pile. We investigated the effect of the inclination angle on the maximum von Mises stress, maximum von Mises elastic strain, maximum displacement vector sum, maximum displacement in the horizontal direction, and maximum displacement in the vertical direction. Results indicate that the pile＇s operationally optimal degree of inclination is approximately 5°. By exceeding this value, the instability in the surrounding soil under applied loads grows extensively in all the geotechnical properties considered. Cohesive soils tend to display poorer results compared to grained soils.

Consolidation Properties of Highly Plastic Clay During Osmotic Pressure Consolidation Test

For the very soft clay with high water content, its void ratio, compressibility coefficient and permeability varied with stress during consolidation. It is necessary to use large strain consolidation based on the permeability-void ratio relationship and effective stress-void ratio relationship to analyze these properties. To overcome the disadvantages of conventional oedometer test, and determine the effective stress-void relations of this kind of soil, osmotic pressure consolidation test for highly plastic clay study and the expression of permeability-void ratio are performed. Therefore, the decided properties will be reasonably used for solving the large strain consolidation equation.

Key Variables Explaining Soil Organic Carbon Content Variations in Croplands and Non-Croplands in Chinese Provinces

Soil organic carbon (SOC) plays an important role in global carbon cycles.Large spatial variations in SOC contents result in uncertain estimates of the SOC pool and its changes.In the present study,the key variables explaining the SOC contents of croplands (CPs) and non-croplands (NCPs) in Chinese provinces were investigated.Data on SOC and other soil properties (obtained from the Second National Soil Survey conducted in the late 1970s to the early 1990s),climate parameters,as well as the proportion of the CP to the total land area (Pcp) were used.SOC content variations within a province were larger than those among provinces.Soil clay and total phosphorus content,ratio of annual precipitation to mean temperature,as well as Pcp were able to explain 75% of the SOC content variations in whole soil samples.Soil pH,mean temperature during the growing season from May to October,and mean annual wind velocity were able to explain 63% of the SOC content variations in NCP soils.Compared with NCP soils,CP soils had lower SOC contents,with smaller variations within and among provinces and lower C/N ratios.Stepwise regression showed that the soil clay content was a unique factor significantly correlated with the SOC content of CP soils.However,this factor only explained 24% of the variations.This result suggested that variables related to human activities had greater effects on SOC content variations in CP soils than soil properties and climate parameters.Based on SOC contents directly averaged from soil samples and estimated by regression equations,the total SOC pool in the topsoil (0-20 cm) of China was estimated at 60.02 Pg and 57.6 Pg.Thousands of years of intensive cultivation in China resulted in CP topsoil SOC loss of 4.34-4.98 Pg.

Effect of Alkali-NaOH Solution on the Nature of Synthesized Zeolite from 2：1 Tunisian Clays： XRD and MAS-NMR Investigation

This work focuses the effect of alkali-NaOH solution on the nature of synthesized zeolite from 2：1 Tunisian clays. This study was achieved using correlation between results obtained from X-ray diffraction （XRD） and MAS-NMR analysis. Preliminary treatment was adopted to prepare the starting sample that is placed in contact with NaOH solution at variable concentration. A specific hydrothermal reactor, allowing the control ofpH 〉 9, temperature and a continuous stirring of the sample in the NaOH solution; was used to achieve these syntheses. The obtained results showed that, for concentration value ~IN, the final complex presented characteristic XRD and MAS-NMR line of zeolite P. For 3N solution concentration we obtained zeolite HS. All synthesize process are controlled by XRD and MAS-NMR investigation.

A theoretical analysis of vertical dynamic response of large-diameter pipe piles in layered soil

Considering the viscous damping of the soil and soil-pile vertical coupled vibration,a computational model of large-diameter pipe pile in layered soil was established.The analytical solution in frequency domain was derived by Laplace transformation method.The responses in time domain were obtained by inverse Fourier transformation.The results of the analytical solution proposed agree well with the solutions in homogenous soil.The effects of the shear modulus and damping coefficients of the soil at both outer and inner sides of the pipe pile were researched.The results indicate that the shear modulus of the outer soil has more influence on velocity admittance than the inner soil.The smaller the shear modulus,the larger the amplitude of velocity admittance.The velocity admittance weakened by the damping of the outer soil is more obvious than that weakened by the damping of the inner soil.The displacements of the piles with the same damping coefficients of the outer soil have less difference.Moreover,the effects of the distribution of soil layers are analyzed.The results indicate that the effect of the upper soil layer on dynamic response of the pipe pile is more obvious than that of the bottom soil layer.A larger damping coefficient of the upper layer results in a smaller velocity admittance.The dynamic response of the pipe pile in layered soil is close to that of the pipe pile in homogenous soil when the properties of the upper soil layer are the same.

Characteristics of Oxides in Argillic Soils of Warm Tem-perate Zone in China

Studies of seven typical soil profiles showed that in the argillic soils derived from loess in the warmtemperate zone of China all the oxides of Fe, Mn, Al and Si were enriched with the accumulation of clayfraction in the profiles. But owing to the influence of oxidation-reduction process the migration velocity ofFe and Mn was faster than that of clay. The free degrees of those metals were in the sequence Mn>Fe>Al,which reflected their different chemical activities in soil. In soils at the same level of development, the freedegree of iron and its activity, the free degree of Al, Alo/Alt× 100, SiO_2/R_2O_3, Sio/Sit× 100, and themagnetic susceptibility were relatively close to each other respectively. It might be considered that both thefres degrees of Fe and Al and Alo/Alt× 100 could serve as the distinctive indexes for argillic soils in warmtemperate zone. The paleoclimate corresponding to the fifth layer of paleosol (s_5) in Lnochuan, Shaanxiwas warmer and more humid than the present, and the paleoecological landscape approximated to today'sbioclimatic belt between the temperate deciduous broadleaved forest and the semiarid forest types.The Mossbouer spectra of the colloidal fraction (<1um) in the clayified horizon of argillic dark loessialsoil, cinnamon soil, brown earth and (s_5) paleosol indicated the superparamagnetic state at room temperature.The magnetic splitting six line spectra were observed clearly at 80 K. The results fitted with a computershowed that hematite and goethite were predominant in iron oxides and commonly existed as fine particles.The proportion of hematite and goethite in soil colloids varied considerably with different climates. Thehigher the temperature, the larger the proportion of hematite.

Effect of Clay Minerals on the Chemical Characteristics of Soil Humus

Chemical characteristics of humic substances in soils with different mineralogical characteristics and under different utilization patterns in Zhangpu, Fujian Province,together with two pairs of cultiwted soils in North China Plain were studied by chemical analysis,visible and IR spectroscopy and 13C NMR spectrometry.For soils in Zhangpu the HA/FA ratio and both the aromaticity and the degree of hundfication of HA were higher in soils with montmorillonite as the predominant clay mineral than in thO6e with kaolinite as the predominant clay mineral, provided these soils were under the same utilisstion pattern. While for eaCh pair of soils with similar mineralogical characteristics the HA/FA ratio was higher and the C/H ratio and the content of carboxyl group of HA were lower in paddy soil than in upland soil.Among the upland soils(or paddy soils) studied the HA/FA ratio of soil in Zhangpu with kaollnite as the predominant clay mineral was the lowest,and that of soil in Zhangpu with montmorillonite aa the predominant clay mineral was the highest.It was concluded that the presence of moatmorillonite favored the formation and maturation of humic acid.

Geomechanical and water vapor absorption characteristics of clay-bearing soft rocks at great depth

The geological and physico-mechanical properties characterization of deep soft rocks is one of the critical scientific issues for deep soft rock engineering. In the present study, X-ray diffraction(XRD) analysis,scanning electron microscope(SEM), and mercury intrusion porosimetry experiments were carried out to investigate the mineral compositions, microstructure and porosity characteristics of the 13 claybearing soft rock samples collected from a deep coal mine in China. Water vapor absorption and uniaxial compressive experiments were also performed to examine water absorption characteristics and waterinduced strength degradation effect of the investigated deep soft rock samples. The results show that the dominant mineral components in mudstone, coarse sandstone and fine sandstone samples were calcite, quartz and clay respectively. The contents of clay minerals in all samples were relatively high and ranged from 12.3%(N-4) to 56.5%(XS-1). Water vapor absorption processes of all the soft rock samples follow an exponential law which is very similar to the water vapor absorption behavior of conglomerate samples reported in our earlier study. Correlation analyses also suggested that there were good positive correlation relationships between water absorptivity and clay minerals for both mudstone and sandstone samples. Furthermore, it was found that vapor absorption was not correlated with the porosity for mudstone, however, positive correlation relationship was found between them for sandstone. Correlation analysis between UCS, modulus of elasticity and water content demonstrated that both of them tend to decrease with the increase of their water content due to water absorption.

Analysis on effective stress formula and consolidation of gassy muddy clay

In order to found an applicable equation of consolidation for gassy muddy clay, an effective stress formula of gas-charged nearly-saturated soils was introduced. And then, a consolidation equation was derived. Subsequently, supposing soils were under tangential loading, the expressions of pore water pressure were presented. The analytic solution of pore water pressure was attempted to be validated by the measured values in a real embankment. The parameters in the expressions of pore water pressure were gotten by the method of trial. The result shows that the consolidation model is rational and the analytic solution of pore water pressure is correct. The following conclusions can be made: 1) the influence of bubbles on the compressibility of pore fluid should be considered; 2) the effective stress would be influenced by bubbles, and the consolidation would depend on the compressibility of soil skeleton: the softer the soils are, the more distinct the influence of bubbles is; for normal clay, the influence of bubbles on the effective stress may be commonly neglected.

Research on Dynamic Parameters of Soil Sites in the Dalian Area

In this paper, dynamic soil parameters derived from Dalian area seismic risk assessment reports are collected. In this study, the measurement data is divided into 7 types, i.e. silty clay, muddy silty clay, clay, medium sand, rock fragments, backfill soil and fully-weathered slate. Statistics of the dynamic parameters of these soils are carried out to obtain the mean values of dynamic shear modulus ratio and damping ratio. Typical drill holes are selected to establish dynamic soil models to investigate the seismic response for various cases. The dynamic parameters of the models are taken from the statistical values of this study, the standard values of code 94 (i.e. the dynamic soil parameters for Dalian seismic microzonation), and the recommended values by Yuan Xiaoming et al. (2000) respectively. The calculated results of peak ground acceleration are compared with the response spectral characteristics. The results show that the statistical values are approximate to the values recommended by Yuan Xiaoming, et al. (2000), but different greatly with the standard values in code 94.

Pore Size Distribution of Clayey Soils and Its Correlation with Soil Organic Matter

Soil pore size distribution(PSD) directly influences soil physical,chemical,and biological properties,and further knowledge of soil PSD is very helpful for understanding soil functions and processes.In this study,PSD of three clayey soils collected from the topsoil(0-20 cm) of Vertisols in Northern China was analyzed using the N_2 adsorption(NA) and mercury intrusion porosimetry(MIP) methods.The effect of soil organic matter(SOM) on the PSD of clayey soils was also evaluated.The differential curves of pore volume of clayey soils by the NA method exhibited that the pores with diameter < 0.01 μm accounted for more than 50%in the pore size range of 0.001 to 0.1 μm.The differential pore curves of clayey soils by the MIP method exhibited three distinct peaks in pore size range of 60 to 100,0.3 to 0.4 and 0.009 to 0.012 μm,respectively.In the three clayey soils,the ultramicropores(5-0.1μm) were determined to be the main pore class(on average 35.5%),followed by macropores(> 75 μm,31.4%),cryptopores(0.1-0.007μm,16.0%),micropores(30-5 μm,9.7%) and mesopores(75-30 μm,7.3%).The SOM greatly affected the pore structure and PSD of aggregates in clayey soils.In particular,SOM removal reduced the volume and porosity of 5-100 μm pores while increased those of <5 μm pores in the 5-2 and 2-0.25 mm aggregates of clayey soils.The increase in the volume and porosity of < 5 μm pores may be attributed to the disaggregation and partial emptying of small pores caused by the destruction of SOM.

Sorption of Water-Extractable Organic Carbon in Various Clay Subsoils: Effects of Soil Properties

Clay-rich subsoils are added to sandy soils to improve crop yield and increase organic carbon （C） sequestration; however, little is known about the influence of clay subsoil properties on organic C sorption and desorption. Batch sorption experiments were conducted with nine clay subsoils with a range of properties. The clay subsoils were shaken for 16 h at 4 ℃with water-extractable organic C （WEOC, 1 224 g C L-1） from mature wheat residue at a soil to extract ratio of 1：10. After removal of the supernatant, the residual pellet was shaken with deionised water to determine organic C desorption. The WEOC sorption was positively correlated with smectite and illite contents, cation exchange capacity （CEC） and total organic C, but negatively correlated with kaolinite content. Desorption of WEOC expressed as a percentage of WEOC sorbed was negatively correlated with smectite and illite contents, CEC, total and exchangeable calcium （Ca） concentrations and clay content, but positively correlated with kaolinite content. The relative importance of these properties varied among soil types. The soils with a high WEOC sorption capacity had medium CEC and their dominant clay minerals were smectite and illite. In contrast, kaolinite was the dominant clay mineral in the soils with a low WEOC sorption capacity and low-to-medium CEC. However, most soils had properties which could increase WEOC sorption as well as those that could decrease WEOC sorption. The relative importance of properties increasing or decreasing WEOC sorption varied with soils. The soils with high desorption had a low total Ca concentration, low-to-medium CEC and low clay content, whereas the soils with low desorption were characterised by medium-to-high CEC and smectite and illite were the dominant clay minerals. We conclude that WEOC sorption and desorption depend not on a single property but rather a combination of several properties of the subsoils in this study.

Clay Addition to Sandy Soil Influence of Clay Type and Size on Nutrient Availability in Sandy Soils Amended with Residues Differing in C/N ratio

Addition of clay-rich subsoil to sandy soil results in heterogeneous soil with clay peds （2-mm） or finely ground （〈 2 mm） clay soil （FG）, which may affect the nutrient availability. The aim of this study was to assess the effect of clay soil particle size （FG or peds） and properties on nutrient availability and organic C binding in sandy soil after addition of residues with low （young kikuyu grass, KG） or high （faba bean, FB） C/N ratio. Two clay soils with high and low smectite percentage, clay and exchangeable Fe and A1 were added to a sandy soil at a rate of 20% （weight/weight） either as FG or peds. Over 45 d, available N and P as well as microbial biomass N and P concentrations and cumulative respiration were greater in soils with residues of KG than FB. For soils with KG residues, clay addition increased available N and initial microbial biomass C and N concentrations, but decreased cumulative respiration and P availability compared to sandy soil without clay. Differences in measured parameters between clay type and size were inconsistent and varied with time except the increase in total organic C in the 〈 53 μm fraction during the experiment, which was greater for soils with FG than with peds. We concluded that the high exchangeable Fe and A1 concentrations in the low-smectite clay soil can compensate a lower clay concentration and proportion of smectite with respect to binding of organic matter and nutrients.

Joint Multifractal Analysis of Scaling Relationships Between Soil Water-Retention Parameters and Soil Texture

Soil water-retention characteristics at measurement scales are generally different from those at application scales, and there is scale disparity between them and soil physical properties. The relationships between two water-retention parameters, the scaling parameter related to the inverse of the air-entry pressure （avG, cm- 1） and the curve shape factor related to soil pore-size distribution （n） of the van Genuchten water-retention equation, and soil texture （sand, silt, and clay contents） were examined at multiple scales. One hundred twenty-eight undisturbed soil samples were collected from a 640-m transect located in Fuxin, China. Soil water-retention curves were measured and the van Genuchten parameters were obtained by curve fitting. The relationships between the two parameters and soil texture at the observed scale and at multiple scales were evaluated using Pearson correlation and joint multifractal analyses, respectively. The results of Pearson correlation analysis showed that the parameter c^vG was significantly correlated with sand, silt, and clay contents at the observed scale. Joint multifractal analyses, however, indicated that the parameter ~vG was not correlated with silt and sand contents at multiple scales. The parameter n was positively correlated with clay content at multiple scales. Sand content was significantly correlated with the parameter n at the observed scale but not at multiple scales. Clay contents were strongly correlated to both water-retention parameters because clay content was relatively low in the soil studied, indicating that water retention was dominated by clay content in the field of this study at all scales. These suggested that multiple-scale analyses were necessary to fully grasp the spatial variability of soil water-retention characteristics.