Clay minerals of surface sediments in the South China Sea (SCS) are analyzed with X-ray diffraction, and their transport is explored with a grain size trend analysis (GSTA) model. Results show that clay mineral ty...Clay minerals of surface sediments in the South China Sea (SCS) are analyzed with X-ray diffraction, and their transport is explored with a grain size trend analysis (GSTA) model. Results show that clay mineral types in various sedimentary environments have different sediment sources and transport routes. Sediments in the northern SCS (north of 20°N) between the southwest of Taiwan Island and the outer mouth of the Pearl River have high contents of illite and chlorite, which are derived mainly from sediments on Taiwan Island and/or the Yangtze River. Sediments from the Pearl River are characterized by high kaolinite and low smectite content, and most are distributed in the area between the mouth of the Pearl River and northeast of Hainan Island and transported vertically from the continental shelf to the slope. Characterized by high illite content, sediments from Kalimantan Island are transported toward the Nansha Trough. Sediments from Luzon Island are related with volcanic materials, and are transported westwards according to smectite distribution. On the Sunda Shelf, sediments from the Mekong River are transported southeast in the north while sediments from the Indonesian islands are transported northward in the south. Ascertaining surface sediment sources and their transport routes will not only improve understanding of modem transportation and depositional processes, but also aid paleoenvironmental and paleoclimatic analysis of the SCS.展开更多
We studied the geochemical characteristics of illite clay rocks and their importance from the 5hihezi Formation of Late Permian in the Hanxing mining area by means of ICP-M5 and sequential X-ray fluorescence spectrome...We studied the geochemical characteristics of illite clay rocks and their importance from the 5hihezi Formation of Late Permian in the Hanxing mining area by means of ICP-M5 and sequential X-ray fluorescence spectrometry. The results show that the amount of SiO2 is between 53.37% and 61.58% (by weight) and that of Al2O3 22.40% and 31.31% (by weight). The ratio of SiO2/Al2O3 lies between 1.71 and 2.75. The amount of K2O ranges from 1.11% to 2.56% (by weight). The amounts of Fe and Ti are higher than the theoretical values in illite clay rock would indicate. The amounts of some trace elements, such as Ga, As, Ba, Cu, Th and U are higher than their Clark values, while that of another 23 trace elements are found to be dose to their Clark values. The amounts of REE range from 22.59 to 570.54 μg/g, with an average of 163.23μg/g. The ratios of LREE/HREE range from 5.41 to 21.82, with an average of 8.87. These characteristics show that LREE are much richer in content than HREE. The REE distribution patterns of our samples were characterized by clearly negative Ce and Eu anomalies. We analyzed the sedimentary environment of the Hanxing mining area in Late Permian by the characteristic element ratio method. The ratios of Mn/Fe range from 0 to 0.0168, which are lower than those in a marine sedimentary environment. The ratios of Sr/Ba (0.20-0.41) are less than 1. These are all indications that the sediments of the Hanxing mining area in Late Permian form largely a continental sedimentary environment. The sedimentary water is freshwater, a conclusion reached on the basis of the ratios of Th/U (2.66-6.62) and of Ca/(Ca + Fe) (0.01-0.059); the average ratio of Fe2+/Fe3+ is 4.8. The sedimentary water condition is weakly acidic and weakly oxidative-weakly reductive, a conclusion reached on the basis of ratios of Fe2+/Fe3+ (4.8) and of Ceanom (-0.08).展开更多
A laboratory study was conducted in order to explain successive extractions of reserved potassium by using concentrated HCI under reflux for 13 surface and sub-surface soil samples representing three chosen pedons of ...A laboratory study was conducted in order to explain successive extractions of reserved potassium by using concentrated HCI under reflux for 13 surface and sub-surface soil samples representing three chosen pedons of soil series (472 ECC Bashika, 463 EKC Rabeaa and 461 ECC Talafar) locations of Nineveh Province in Northern of Iraq. The aim is to investigate role of clay minerals on release of reserved potassium from soils. Results showed that dominated clay minerals were (smectite 〉 illite 〉 kaolinite 〉 chlorite) for both 472 ECC and 461 ECC soil series and were (illite 〉 smectite 〉 kaolinite 〉 chlorite) for 463 EKC soil series. Also results appeared that exchangeable K+ released values were 2,483-4,575 mg/kg at 461 ECC and 463 EKC soil series, respectively; non-exchangeable phase ranged from 752-1,390 mg/kg at 461 ECC and 472 ECC soil series, respectively. Soil fertility was evaluated according to its K+ mica release referring for high K+ release content with range between 3,324-5,516 mg/kg at 461 ECC and 463 EKC soil series, but rate ofK~ released was very law according to parabolic diffusion me,del with range from 195-359 mg/kg at latter soil series respectively. Results reflect effect of clay minerals on potassium release as amount and rates in arid and semi-arid regions. It can be concluded the study soils have a high amount of potassium content with low rate release of it, in turn these soil need particular management.展开更多
基金Supported by the National Natural Science Foundation of China (No. 40631007)the National Basic Research Program of China (973 Program, Nos. 2007CB819505, 2009CB219502)+3 种基金the Ministry of Science and Technology of China (2006BAB19B03)the Knowledge Innovation Program of Chinese Academy of Sciences (Nos. SQ200713 and LYQY200704)the Open Fund of the Key Laboratory of Marginal Sea Geology, Chinese Academy of Sciences (No. MSGL08-16)the Open Fund of the Key Laboratory of Marine Geology and Environment, Chinese Academy of Sciences (No. MGE2008KG08)
文摘Clay minerals of surface sediments in the South China Sea (SCS) are analyzed with X-ray diffraction, and their transport is explored with a grain size trend analysis (GSTA) model. Results show that clay mineral types in various sedimentary environments have different sediment sources and transport routes. Sediments in the northern SCS (north of 20°N) between the southwest of Taiwan Island and the outer mouth of the Pearl River have high contents of illite and chlorite, which are derived mainly from sediments on Taiwan Island and/or the Yangtze River. Sediments from the Pearl River are characterized by high kaolinite and low smectite content, and most are distributed in the area between the mouth of the Pearl River and northeast of Hainan Island and transported vertically from the continental shelf to the slope. Characterized by high illite content, sediments from Kalimantan Island are transported toward the Nansha Trough. Sediments from Luzon Island are related with volcanic materials, and are transported westwards according to smectite distribution. On the Sunda Shelf, sediments from the Mekong River are transported southeast in the north while sediments from the Indonesian islands are transported northward in the south. Ascertaining surface sediment sources and their transport routes will not only improve understanding of modem transportation and depositional processes, but also aid paleoenvironmental and paleoclimatic analysis of the SCS.
基金supported by the National Nature Science Foundation of China (Nos. 41072031 and 40172119)the Natural Science Foundation of Hebei Province,China (No.D2009000833)
文摘We studied the geochemical characteristics of illite clay rocks and their importance from the 5hihezi Formation of Late Permian in the Hanxing mining area by means of ICP-M5 and sequential X-ray fluorescence spectrometry. The results show that the amount of SiO2 is between 53.37% and 61.58% (by weight) and that of Al2O3 22.40% and 31.31% (by weight). The ratio of SiO2/Al2O3 lies between 1.71 and 2.75. The amount of K2O ranges from 1.11% to 2.56% (by weight). The amounts of Fe and Ti are higher than the theoretical values in illite clay rock would indicate. The amounts of some trace elements, such as Ga, As, Ba, Cu, Th and U are higher than their Clark values, while that of another 23 trace elements are found to be dose to their Clark values. The amounts of REE range from 22.59 to 570.54 μg/g, with an average of 163.23μg/g. The ratios of LREE/HREE range from 5.41 to 21.82, with an average of 8.87. These characteristics show that LREE are much richer in content than HREE. The REE distribution patterns of our samples were characterized by clearly negative Ce and Eu anomalies. We analyzed the sedimentary environment of the Hanxing mining area in Late Permian by the characteristic element ratio method. The ratios of Mn/Fe range from 0 to 0.0168, which are lower than those in a marine sedimentary environment. The ratios of Sr/Ba (0.20-0.41) are less than 1. These are all indications that the sediments of the Hanxing mining area in Late Permian form largely a continental sedimentary environment. The sedimentary water is freshwater, a conclusion reached on the basis of the ratios of Th/U (2.66-6.62) and of Ca/(Ca + Fe) (0.01-0.059); the average ratio of Fe2+/Fe3+ is 4.8. The sedimentary water condition is weakly acidic and weakly oxidative-weakly reductive, a conclusion reached on the basis of ratios of Fe2+/Fe3+ (4.8) and of Ceanom (-0.08).
文摘A laboratory study was conducted in order to explain successive extractions of reserved potassium by using concentrated HCI under reflux for 13 surface and sub-surface soil samples representing three chosen pedons of soil series (472 ECC Bashika, 463 EKC Rabeaa and 461 ECC Talafar) locations of Nineveh Province in Northern of Iraq. The aim is to investigate role of clay minerals on release of reserved potassium from soils. Results showed that dominated clay minerals were (smectite 〉 illite 〉 kaolinite 〉 chlorite) for both 472 ECC and 461 ECC soil series and were (illite 〉 smectite 〉 kaolinite 〉 chlorite) for 463 EKC soil series. Also results appeared that exchangeable K+ released values were 2,483-4,575 mg/kg at 461 ECC and 463 EKC soil series, respectively; non-exchangeable phase ranged from 752-1,390 mg/kg at 461 ECC and 472 ECC soil series, respectively. Soil fertility was evaluated according to its K+ mica release referring for high K+ release content with range between 3,324-5,516 mg/kg at 461 ECC and 463 EKC soil series, but rate ofK~ released was very law according to parabolic diffusion me,del with range from 195-359 mg/kg at latter soil series respectively. Results reflect effect of clay minerals on potassium release as amount and rates in arid and semi-arid regions. It can be concluded the study soils have a high amount of potassium content with low rate release of it, in turn these soil need particular management.