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Polyetherketoneketone/carbon fiber composites with an amorphous interface prepared by solution impregnation
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作者 ZHANG Feng LI Bo-lan +5 位作者 JIAO Meng-xiao LI Yan-bo WANG Xin YANG Yu YANG Yu-qiu ZHANG Xiao-hua 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第4期692-702,共11页
Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their composites.It is therefore of great importance to impregnate the CF bundle... Interfacial adhesion between carbon fibers(CF)and polyetherketoneketone(PEKK)is a key factor that affects the mechanical performances of their composites.It is therefore of great importance to impregnate the CF bundles with PEKK as effi-ciently as possible.We report that PEKK with a good dispersion in a mixed solution of 4-chlorophenol and 1,2-dichloroethane can be introduced onto CF surfaces by solution impregnation and curing at 280,320,340 and 360℃.The excellent wettability or infiltra-tion of the PEKK solution guarantees a full covering and its tight binding to CFs,making it possible to evaluate the interfacial shear strength(IFSS)with the microdroplet method.The interior of the CF bundles is completely and uniformly filled with PEKK by solu-tion impregnation,leading to a high interlaminar shear strength(ILSS).The maximum IFSS and ILSS reached 107.8 and 99.3 MPa,respectively.Such superior shear properties are ascribed to the formation of amorphous PEKK in the small spaces between CFs. 展开更多
关键词 Polyetherketoneketone Carbon fiber WETTABILITY Amorphous adhesion Interfacial strength
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含儿茶酚基团的湿态组织粘附水凝胶 被引量:3
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作者 陈一明 李慧颖 +3 位作者 倪鹏 方燕 刘海清 翁云翔 《化学进展》 SCIE CAS CSCD 北大核心 2023年第4期560-576,共17页
湿态粘附作用对于生命的孕育和发展具有重要意义。水凝胶是一类兼具固液特性的智能材料,组织粘附水凝胶因多功能性和生物相容性而被广泛应用于伤口闭合和修复、细胞工程、组织工程等领域。然而,湿态组织表面的水合层阻碍了组织粘附水凝... 湿态粘附作用对于生命的孕育和发展具有重要意义。水凝胶是一类兼具固液特性的智能材料,组织粘附水凝胶因多功能性和生物相容性而被广泛应用于伤口闭合和修复、细胞工程、组织工程等领域。然而,湿态组织表面的水合层阻碍了组织粘附水凝胶与组织表面形成界面粘附键。面对这一挑战,受海洋贻贝足丝蛋白中DOPA的儿茶酚基团是水下粘附的关键结构的启发,含儿茶酚基团的湿态组织粘附水凝胶的研究引起了广泛关注。本综述介绍了贻贝足丝蛋白(Mfps)的结构及湿态粘附机理,并将儿茶酚衍生物分为天然Mfps或利用基因工程合成的Mfps、含儿茶酚基团的小分子化合物、儿茶酚基团改性的天然高分子以及含儿茶酚基团的合成功能高分子;随后,概述近十年含儿茶酚基团的湿态组织粘附水凝胶在组织创口修复材料、生物涂层材料、靶向型药物输送材料、生物电子设备材料的研究进展;文末,展望了此类水凝胶材料未来发展面临的机遇和挑战。 展开更多
关键词 贻贝足丝蛋白 粘附机理 儿茶酚衍生物 湿组织粘附 水凝胶
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高分子医用组织胶粘剂的应用与研究进展 被引量:10
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作者 孙文 闫秋艳 +2 位作者 苏超 栾世方 殷敬华 《材料导报》 EI CAS CSCD 北大核心 2022年第3期1-17,共17页
高分子医用组织胶粘剂由于具有优异的性能,受到医疗领域的广泛关注,适用于轻微至危及生命的各种组织损伤的闭合与再生。与传统的伤口缝合方法(缝合线和缝合钉)相比,胶粘剂使用方便、闭合伤口速度快、对组织的损伤小。目前,高分子医用胶... 高分子医用组织胶粘剂由于具有优异的性能,受到医疗领域的广泛关注,适用于轻微至危及生命的各种组织损伤的闭合与再生。与传统的伤口缝合方法(缝合线和缝合钉)相比,胶粘剂使用方便、闭合伤口速度快、对组织的损伤小。目前,高分子医用胶粘剂以多种形式用于伤口处理,如止血剂、粘合剂和密封剂。尽管组织胶粘剂目前应用广泛,但仍面临一些限制和未解决的挑战(例如较弱的湿态粘附强度和缺乏生物功能等),这限制了它们的使用,为未来的改进留下了充足的空间。基于组织胶粘剂界面的化学和物理特性、组织粘连的基本机制以及特定临床应用的要求,本文总结了组织胶粘剂的基本设计原则及湿态粘附机制,基于组织特异性的考虑,介绍了该领域的最新研究进展,并展望了未来组织胶粘剂的潜在功能和临床需求。 展开更多
关键词 组织胶粘剂 粘附机制 湿粘附 组织修复
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Nonclasssical Properties in Two-Mode Fields Resonantly Interacting with a Three-Level -Type Atom 被引量:6
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作者 SU Wan-Jun ZENG Xiao-Meng ZHONG Zhi-Rong 《Communications in Theoretical Physics》 SCIE CAS CSCD 2007年第4X期721-724,共4页
Some noclassical properties in electromagnetic field are investigated for the interaction of two-modes initially taken in coherent-state representation with the three-level -type atom, such as squeezing properties an... Some noclassical properties in electromagnetic field are investigated for the interaction of two-modes initially taken in coherent-state representation with the three-level -type atom, such as squeezing properties and violation of the Cauchy-Schwartz inequality. The enhancement of field squeezing is found by selective atomic measurement. The Cauchy-Schwartz inequality is violated by the application of the classical field followed by detection in excited state. 展开更多
关键词 nonclassical properties two-mode coherent states resonant interaction selective atomic measurement
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Review of copper and copper alloys as immune and antibacterial element 被引量:2
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作者 Yang-gang WANG Hao-yang LI +3 位作者 Xiao-yan YUAN Yan-bin JIANG Zi-an XIAO Zhou LI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第10期3163-3181,共19页
This review discussed the relationship among copper,human,and bacteria.Copper plays an important role in human immunity.Copper can boost human immune defense reactions at recommended intake level.The content mainly fo... This review discussed the relationship among copper,human,and bacteria.Copper plays an important role in human immunity.Copper can boost human immune defense reactions at recommended intake level.The content mainly focused on copper antibacterial activity and copper antibacterial mechanisms.Conclusions stated that copper antibacterial activity is affected by copper homeostasis mechanisms in bacteria,adhesion,humidity,strain specificity,and manufacturing methods of antibacterial agents.For the preparation of particle antibacterial agents and surface antibacterial agents,this review discussed several manufacturing methods,such as sol−gel,cold spray,and biosynthesis belonging to chemical synthesis,physical synthesis,and biological synthesis,respectively.Sol−gel method contributes to the preparation of particle agents and surface agents.Cold spray technique is utilized in synthesis of surface copper agent.Biosynthesis is a novel technology which can be applied in nanoparticle agent preparation. 展开更多
关键词 IMMUNITY TOXICITY antibacterial activity copper homeostasis adhesion humidity strain specificity antibacterial agents mechanisms
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Semi-liquid metal and adhesion-selection enabled rolling and transfer(SMART) printing:A general method towards fast fabrication of flexible electronics 被引量:8
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作者 Rui Guo Siyuan Yao +1 位作者 Xuyang Sun Jing Liu 《Science China Materials》 SCIE EI CSCD 2019年第7期982-994,共13页
Recent breakthrough in eutectic gallium-indium alloy has revealed its great potential in modern electronic engineering. Here, we established a general method towards super-fast fabrication of flexible electronics via ... Recent breakthrough in eutectic gallium-indium alloy has revealed its great potential in modern electronic engineering. Here, we established a general method towards super-fast fabrication of flexible electronics via semi-liquid metal and adhesion-selection enabled rolling and transfer (SMART) printing on various substrates. Based on the semiliquid metal and its adhesion-difference on specifically designed target materials, we demonstrated that the rolling and transfer printing method could serve to rapidly manufacture a wide variety of complicated patterns with high resolution and large size. The process is much faster than most of the currently existing electronic fabrication strategies including liquid metal printing ever developed, and the cost either in time or consumption rate is rather low. As illustrated, a series of functional flexible and stretchable electronics such as multiple layer and large area circuits were fabricated to show their superior merit in combination with electrical conductivity and deformability. In addition, it was also demonstrated that the electronics fabricated in this way exhibited good repeatablity. A most noteworthy advantage is that all the fabrication processes could be highly automatic in the sense that user-friendly machines can thus be developed. This method paves a practical way for super-fast soft electronics manufacture and is expected to play an important role in the coming industry and consumer electronics. 展开更多
关键词 Ni-EGaln semi-liquid metal fast fabrication adhesion difference flexible electronics
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