A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust c...A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust containing arsenic and antimony and satisfactory results were obtained. Over 99% of arsenic and antimony were recovered, and high purity As2O3 and SbCl3 were produced. A metallic alcoholate technique was developed and proved to be of significant to the utilization of antimony resources. Using this technique, a number of antimony oxide powders were prepared, such as high purity and ultrafine Sb2O3, ultrafine Sb2O3-Sb2O5 and Sb2O3-SnO2 composite powders.展开更多
To reduce the difficulty of material filling into the top region of tooth in hot precision forging of gears using the alternative die designs, relief-cavity designs in different sizes were performed on the top of die ...To reduce the difficulty of material filling into the top region of tooth in hot precision forging of gears using the alternative die designs, relief-cavity designs in different sizes were performed on the top of die tooth. The influences of the conventional process and relief-cavity designs on corner filling, workpiece stress, die stress, forming load and material utilization were examined. Finite element simulation for tooth forming, die stress and forming load using the four designs was performed. The material utilization was further considered, and the optimal design was determined. The tooth form and forming load in forging trials ensured the validity of FE simulation. Tooth accuracy was inspected by video measuring machine(VMM), which shows the hot forged accuracy achieves the level of rough machining of gear teeth. The effects of friction on mode of metal flow and strain distribution were also discussed.展开更多
Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical et...Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical etching, or electrochemical machining on the fifth generation TFT LCDs. The selective removal of microstructure layers from the color filter surface of an optoelectronic flat panel display, as well as complete removal of the ITO thin-films, RGB layer, or resin black matrix (BM) layer from the substrate is possible. Individual defective film layers can be removed, or all films down to the Cr layer or bare glass can be completely eliminated. Experimental results demonstrate that defective ITO thin-films, RGB layers, or the resin BM layer can now be recycled with a great precision. When the ITO or RGB layer proves difficult to remove, excimer light can be used to help with removal. During this recycling process, the use of 225 nm excimer irradiation before chemical etching, or electrochemical machining, makes removal of stubborn film residues easy, effectively improving the quality of recycled color filters and reducing fabrication cost.展开更多
Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispe...Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispersed Au_1 catalyst is synthesized and applied in electrochemical synthesis of ammonia under ambient conditions. A high NH＋4 Faradaic efficiency of 11.1 % achieved by our Au_1 catalyst surpasses most of reported catalysts under comparable conditions. Benefiting from efficient atom utilization, an NH＋4 yield rate of 1,305 μg h-1 mg-1Au has been reached, which is roughly 22.5 times as high as that by sup- ported Au nanoparticles. We also demonstrate that by employing our Au_1 catalyst, NH＋4 can be electro- chemically produced directly from N_2 and H_2 with an energy utilization rate of 4.02 mmol kJ-1. Our study provides a possibility of replacing the Haber-Bosch process with environmentally benign and energy-efficient electrochemical strategies.展开更多
A technically transparent and freely available reference sample set for validation of global land cover mapping was recently established to assess the accuracies of land cover maps with multiple resolutions.This sampl...A technically transparent and freely available reference sample set for validation of global land cover mapping was recently established to assess the accuracies of land cover maps with multiple resolutions.This sample set can be used to estimate areas because of its equal-area hexagon-based sampling design.The capabilities of these sample set-based area estimates for cropland were investigated in this paper.A 30-m cropland map for China was consolidated using three thematic maps(cropland,forest and wetland maps)to reduce confusion between cropland and forest/wetland.We compared three area estimation methods using the sample set and the 30 m cropland map.The methods investigated were:(1)pixel counting from a complete coverage map,(2)direct estimation from reference samples,and(3)model-assisted estimation combining the map with samples.Our results indicated that all three methods produced generally consistent estimates which agreed with cropland area measured from an independent national land use dataset.Areas estimated from the reference sample set were less biased by comparing with a National Land Use Dataset of China(NLUD-C).This study indicates that the reference sample set can be used as an alternative source to estimate areas over large regions.展开更多
Besides grid-to-vehicle(G2 V) and vehicle-to-grid(V2 G) functions, the battery of an electric vehicle(EV) also has the specific feature of mobility. This means that EVs not only have the potential to utilize the stora...Besides grid-to-vehicle(G2 V) and vehicle-to-grid(V2 G) functions, the battery of an electric vehicle(EV) also has the specific feature of mobility. This means that EVs not only have the potential to utilize the storage of cheap electricity for use in high energy price periods, but can also transfer energy from one place to another place. Based on these special features of an EV battery, a new EV energy scheduling method has been developed and is described in this article. The approach is aimed at optimizing the utilization EV energy for EVs that are regularly used in multiple places. The objective is to minimize electricity costs from multiple meter points. This work applies real data in order to analyze the effectiveness of the method. The results show that by applying the control strategy presented in this paper at locations where the EVs are parked, the electricity cost can be reduced without shifting the demand and lowering customer's satisfaction. The effects of PV size and number of EVs on our model are also analyzed in this paper. This model has the potential to be used by energy system designers as a new perspective to determine optimal sizes of generators or storage devices in energy systems.展开更多
To understand historical human-induced land use/cover change （LUCC） and its climatic effects, it is essential to reconstruct historical land use/cover changes with explicit spatial information. In this study, based ...To understand historical human-induced land use/cover change （LUCC） and its climatic effects, it is essential to reconstruct historical land use/cover changes with explicit spatial information. In this study, based on the historically documented cropland area at county level, we reconstructed the spatially explicit cropland distribution at a cell size of 1 km × 1 km for the Songnen Plain in the late Qing Dynasty （1908 AD）. The reconstructions were carried out using two methods. One method （hereafter, referred to as method 1） allocated the cropland to cells ordered from a high agricultural suitability index （ASI） to a low ASI, but they were all within the domain of potential cropland area. The potential cropland area was created by excluding natural woodland, swamp, water bodies, and mountains from the study area. The other method （hereafter, method II） allocated the cropland to cells in the order from high ASI to low ASI within the domain of cropland area in 1959. This method was based on the hypothesis that the cropland area domain in 1959 resulted from enlargement of the cropland area domain in 1908. We then compared these two reconstructions. We found that the crop- land distributions reconstructed by the two methods exhibit a similar spatial distribution pat- tern. Both reconstructions show that the cropland was mostly found in the southern and eastern parts of the Songnen Plain. The two reconstructions matched each other for about 68% of the total cropland area. By spatially comparing the unmatched cropland cells of the two reconstructions with the settlements for each county, we found that unmatched cropland cells from method I are closer to settlements than those from method I1. This finding suggests that reconstruction using method I may have less bias than reconstruction with method I1.展开更多
文摘A new hydrometallurgical process of chlorination-distillation at low temperatures about 100 °C was developed for recovery of valuable metal and environmental protection. This process was used to treat flue dust containing arsenic and antimony and satisfactory results were obtained. Over 99% of arsenic and antimony were recovered, and high purity As2O3 and SbCl3 were produced. A metallic alcoholate technique was developed and proved to be of significant to the utilization of antimony resources. Using this technique, a number of antimony oxide powders were prepared, such as high purity and ultrafine Sb2O3, ultrafine Sb2O3-Sb2O5 and Sb2O3-SnO2 composite powders.
基金Project(51375042)supported by the National Natural Science Foundation of ChinaProject supported by Beijing Laboratory of Modern Transport Metal Materials and Processing Technology,China
文摘To reduce the difficulty of material filling into the top region of tooth in hot precision forging of gears using the alternative die designs, relief-cavity designs in different sizes were performed on the top of die tooth. The influences of the conventional process and relief-cavity designs on corner filling, workpiece stress, die stress, forming load and material utilization were examined. Finite element simulation for tooth forming, die stress and forming load using the four designs was performed. The material utilization was further considered, and the optimal design was determined. The tooth form and forming load in forging trials ensured the validity of FE simulation. Tooth accuracy was inspected by video measuring machine(VMM), which shows the hot forged accuracy achieves the level of rough machining of gear teeth. The effects of friction on mode of metal flow and strain distribution were also discussed.
基金supported by the BEN TEN CO., and National Science Council contracts 98-2221-E-152-001 and 99-2221-E-152-001
文摘Color filters are produced using semiconductor production techniques although problems with low yield remain to be addressed. This study presents a new means of selective removal using excimer irradiation, chemical etching, or electrochemical machining on the fifth generation TFT LCDs. The selective removal of microstructure layers from the color filter surface of an optoelectronic flat panel display, as well as complete removal of the ITO thin-films, RGB layer, or resin black matrix (BM) layer from the substrate is possible. Individual defective film layers can be removed, or all films down to the Cr layer or bare glass can be completely eliminated. Experimental results demonstrate that defective ITO thin-films, RGB layers, or the resin BM layer can now be recycled with a great precision. When the ITO or RGB layer proves difficult to remove, excimer light can be used to help with removal. During this recycling process, the use of 225 nm excimer irradiation before chemical etching, or electrochemical machining, makes removal of stubborn film residues easy, effectively improving the quality of recycled color filters and reducing fabrication cost.
基金supported by the National Key R&D Program of China (2017YFA0208300)the National Natural Science Foundation of China (21522107, 21671180, 21521091, 21390393, U1463202, and 21522305)
文摘Tremendous efforts have been devoted to explore energy-efficient strategies of ammonia synthesis to replace Haber-Bosch process which accounts for 1.4% of the annual energy consumption. In this study, atomically dispersed Au_1 catalyst is synthesized and applied in electrochemical synthesis of ammonia under ambient conditions. A high NH＋4 Faradaic efficiency of 11.1 % achieved by our Au_1 catalyst surpasses most of reported catalysts under comparable conditions. Benefiting from efficient atom utilization, an NH＋4 yield rate of 1,305 μg h-1 mg-1Au has been reached, which is roughly 22.5 times as high as that by sup- ported Au nanoparticles. We also demonstrate that by employing our Au_1 catalyst, NH＋4 can be electro- chemically produced directly from N_2 and H_2 with an energy utilization rate of 4.02 mmol kJ-1. Our study provides a possibility of replacing the Haber-Bosch process with environmentally benign and energy-efficient electrochemical strategies.
基金supported by the National Natural Science Foundation of China(Grant No.41301445)a research grant from Tsinghua University(Grant No.20151080351)
文摘A technically transparent and freely available reference sample set for validation of global land cover mapping was recently established to assess the accuracies of land cover maps with multiple resolutions.This sample set can be used to estimate areas because of its equal-area hexagon-based sampling design.The capabilities of these sample set-based area estimates for cropland were investigated in this paper.A 30-m cropland map for China was consolidated using three thematic maps(cropland,forest and wetland maps)to reduce confusion between cropland and forest/wetland.We compared three area estimation methods using the sample set and the 30 m cropland map.The methods investigated were:(1)pixel counting from a complete coverage map,(2)direct estimation from reference samples,and(3)model-assisted estimation combining the map with samples.Our results indicated that all three methods produced generally consistent estimates which agreed with cropland area measured from an independent national land use dataset.Areas estimated from the reference sample set were less biased by comparing with a National Land Use Dataset of China(NLUD-C).This study indicates that the reference sample set can be used as an alternative source to estimate areas over large regions.
基金supported by the China Scholarship Council and Donghua University Graduate Student Degree Thesis Innovation Fund Project (Grant No. CUSF-DH-D-2013059)
文摘Besides grid-to-vehicle(G2 V) and vehicle-to-grid(V2 G) functions, the battery of an electric vehicle(EV) also has the specific feature of mobility. This means that EVs not only have the potential to utilize the storage of cheap electricity for use in high energy price periods, but can also transfer energy from one place to another place. Based on these special features of an EV battery, a new EV energy scheduling method has been developed and is described in this article. The approach is aimed at optimizing the utilization EV energy for EVs that are regularly used in multiple places. The objective is to minimize electricity costs from multiple meter points. This work applies real data in order to analyze the effectiveness of the method. The results show that by applying the control strategy presented in this paper at locations where the EVs are parked, the electricity cost can be reduced without shifting the demand and lowering customer's satisfaction. The effects of PV size and number of EVs on our model are also analyzed in this paper. This model has the potential to be used by energy system designers as a new perspective to determine optimal sizes of generators or storage devices in energy systems.
基金National Natural Science Foundation of ChinaNo.42171217,No.41471171+1 种基金Doctorial Innovation Fund,No.HSDBSCX 2015-12Natural Science of Foundation of Heilongjiang Province,No.ZD201308
文摘To understand historical human-induced land use/cover change （LUCC） and its climatic effects, it is essential to reconstruct historical land use/cover changes with explicit spatial information. In this study, based on the historically documented cropland area at county level, we reconstructed the spatially explicit cropland distribution at a cell size of 1 km × 1 km for the Songnen Plain in the late Qing Dynasty （1908 AD）. The reconstructions were carried out using two methods. One method （hereafter, referred to as method 1） allocated the cropland to cells ordered from a high agricultural suitability index （ASI） to a low ASI, but they were all within the domain of potential cropland area. The potential cropland area was created by excluding natural woodland, swamp, water bodies, and mountains from the study area. The other method （hereafter, method II） allocated the cropland to cells in the order from high ASI to low ASI within the domain of cropland area in 1959. This method was based on the hypothesis that the cropland area domain in 1959 resulted from enlargement of the cropland area domain in 1908. We then compared these two reconstructions. We found that the crop- land distributions reconstructed by the two methods exhibit a similar spatial distribution pat- tern. Both reconstructions show that the cropland was mostly found in the southern and eastern parts of the Songnen Plain. The two reconstructions matched each other for about 68% of the total cropland area. By spatially comparing the unmatched cropland cells of the two reconstructions with the settlements for each county, we found that unmatched cropland cells from method I are closer to settlements than those from method I1. This finding suggests that reconstruction using method I may have less bias than reconstruction with method I1.
