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高分辨率精确质谱非靶标分析塑料食品接触材料迁移化合物综述
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作者 李洁君 张丽媛 王永香 《上海包装》 2021年第2期45-52,共8页
对食品接触材料迁移化合物进行定性和定量分析是个挑战,缺少分析标准以及许多迁移化合物未包含在化学和光谱数据库中。将气相色谱和液相色谱结合各种精确的高分辨率的质量分析器上用于分析塑料食品接触材料中迁移化合物。综述了目前高... 对食品接触材料迁移化合物进行定性和定量分析是个挑战,缺少分析标准以及许多迁移化合物未包含在化学和光谱数据库中。将气相色谱和液相色谱结合各种精确的高分辨率的质量分析器上用于分析塑料食品接触材料中迁移化合物。综述了目前高分辨率精确质谱非靶标分析方法,特别是分析塑料食品接触材料的未知迁移化合物数据采集的软件工具。总结了使用高分辨率精确质谱分析出塑料食品接触材料中各种有意添加物质和非故意添加物质。最后,还讨论了塑料食品包装材料的安全性评估,以期对相关课题的研究具有一定的参考价值。 展开更多
关键词 塑料食品接触材料 分辨精确质谱 非靶标分析法 安全性评估
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量子操作的分辨
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作者 张成 任林源 张璟 《计算机工程与应用》 CSCD 北大核心 2009年第8期9-12,共4页
利用量子操作的无错分辨来考虑量子操作的精确分辨,得到了量子操作精确分辨的充要条件;其次,将量子态的集合分辨推广到量子操作的集合分辨,同时得到了两个充要条件;最后考虑了量子操作无错分辨的失败概率的下界。
关键词 量子操作 精确分辨 无错分辨 下界
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Accuracy Comparison of Gridded Historical Cultivated Land Data in Jiangsu and Anhui Provinces 被引量:5
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作者 YUAN Cun YE Yu +1 位作者 TANG Chanchan FANG Xiuqi 《Chinese Geographical Science》 SCIE CSCD 2017年第2期273-285,共13页
The spatial resolution of source data, the impact factor selection on the grid model and the size of the grid might be the main limitations of global land datasets applied on a regional scale. Quantitative studies of ... The spatial resolution of source data, the impact factor selection on the grid model and the size of the grid might be the main limitations of global land datasets applied on a regional scale. Quantitative studies of the impacts of rasterization on data accuracy can help improve data resolution and regional data accuracy. Through a case study of cropland data for Jiangsu and Anhui provinces in China, this research compared data accuracy with different data sources, rasterization methods, and grid sizes. First, we investigated the influence of different data sources on gridded data accuracy. The temporal trends of the History Database of the Global Environment (HYDE), Chinese Historical Cropland Data (CHCD), and Suwan Cropland Data (SWCD) datasets were more similar. However, differ- ent spatial resolutions of cropland source data in the CHCD and SWCD datasets revealed an average difference of 16.61% when provin- cial and county data were downscaled to a 10 x 10 km2 grid for comparison. Second, the influence of selection of the potential arable land reclamation rate and temperature factors, as well as the different processing methods for water factors, on accuracy of gridded datasets was investigated. Applying the reclamation rate of potential cropland to grid-processing increased the diversity of spatial distri- bution but resulted in only a slightly greater standard deviation, which increased by 4.05. Temperature factors only produced relative disparities within 10% and absolute disparities within 2 km2 over more than 90% of grid cells. For the different processing methods for water factors, the HYDE dataset distributed 70% more cropland in grid cells along riverbanks, at the abandoned Yellow River Estuary (located in Binhai County, Yancheng City, Jiangsu Province), and around Hongze Lake, than did the SWCD dataset. Finally, we ex- plored the influence of different grid sizes. Absolute accuracy disparities by unit area for the year 2000 were within 0.1 km2 at a 1 km2 grid size, a 25% improvement over the 10 km2 grid size. Compared to the outcomes of other similar studies, this demonstrates that some model hypotheses and grid-processing methods in international land datasets are truly incongruent with actual land reclamation proc- esses, at least in China. Combining the model-based methods with historical empirical data may be a better way to improve the accuracy of regional scale datasets. Exploring methods for the above aspects improved the accuracy of historical crop/and gridded datasets for finer regional scales. 展开更多
关键词 accuracy evaluation spatial resolution grid-processing method grid size historical period
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Less than 6 GHz resolution THz spectroscopy of water vapor 被引量:10
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作者 ZHAN HongLei SUN ShiNing +4 位作者 ZHAO Kun LENG WenXiu BAO RiMa XIAO LiZhi ZHANG ZhenWei 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2015年第12期2104-2109,共6页
The application of terahertz(THz) technique in many fields like petroleum industry requires the high resolution and multifunction to realize the precise detection of different materials. In this study water vapor in... The application of terahertz(THz) technique in many fields like petroleum industry requires the high resolution and multifunction to realize the precise detection of different materials. In this study water vapor in atmosphere was scanned with shortand long-path THz spectrometers with different scan ranges. The full width at half maximum of the THz characteristic lines in long-path system reached less than 7 GHz and that in short achieved -5.5 GHz, indicating that the THz spectroscopy of water vapor can be used to calibrate THz devices. THz systems with right scan ranges could be a promising selection for the identification of solid, liquid and gaseous materials with very similar structures due to the high resolution. The research demonstrates that the multifunctional THz test can be realized through the balance of resolution and sampling space in many fields, such as oil-gas industry. 展开更多
关键词 TERAHERTZ water vapor RESOLUTION full width at half maximum
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