Tungsten current price was transformed yearly to its constant price since 1900, which is roughly decomposed into four components as trend, cycle, impact and random. The core prices, consisting of the trend and the cyc...Tungsten current price was transformed yearly to its constant price since 1900, which is roughly decomposed into four components as trend, cycle, impact and random. The core prices, consisting of the trend and the cycle, present regularities that a long-run cycle is embedded within two major cycles, and major cycle is composed of low-price period and high-price period, along with the rapid rise into a tower, and along with deep down into next trough; three sharply upward shocks occur by the events in a tower. Fluctuations in prices trend to slow cycles and expand the bands. It can be expected that tungsten price will highly stand over 17 a, and is is a advice that reducing production and restricting export maybe maintain a high price level.展开更多
A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tung...A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tungsten by solvent extraction and reusing leaching agent.In the leaching process,affecting factors,such as temperature,leaching time,nitric acid and dosage of phosphoric acid,were examined on recovery of tungsten.Results show that more than 97%of tungsten could be extracted under conditions of leaching temperature of 80-90°C,HNO3 concentration of 3.0-4.0 mol/L,liquild-to-soild ratio of 10:1,H3PO4 dosage of 3 stoichiometric ratio and leaching time of 3 h.Solvent extraction was then employed for the W recovery from the leachate with a organic system of 40%(v/v)N235,30%(v/v)TBP,and 30%sulfonated kerosene.Approximately 99.93%of W was extracted and ammonium tungstate solution containing 193 g/L W was obtained with a stripping rate of 98.10%under the optimized conditions.展开更多
基金Project(2013ZK2001)supported by the Major Soft Science Program of Hunan Provice,ChinaProjects(1382ZD024,13BGL105)supported by the National Social Science Foundation of China
文摘Tungsten current price was transformed yearly to its constant price since 1900, which is roughly decomposed into four components as trend, cycle, impact and random. The core prices, consisting of the trend and the cycle, present regularities that a long-run cycle is embedded within two major cycles, and major cycle is composed of low-price period and high-price period, along with the rapid rise into a tower, and along with deep down into next trough; three sharply upward shocks occur by the events in a tower. Fluctuations in prices trend to slow cycles and expand the bands. It can be expected that tungsten price will highly stand over 17 a, and is is a advice that reducing production and restricting export maybe maintain a high price level.
基金Project(51334008) supported by the National Natural Science Foundation of China
文摘A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tungsten by solvent extraction and reusing leaching agent.In the leaching process,affecting factors,such as temperature,leaching time,nitric acid and dosage of phosphoric acid,were examined on recovery of tungsten.Results show that more than 97%of tungsten could be extracted under conditions of leaching temperature of 80-90°C,HNO3 concentration of 3.0-4.0 mol/L,liquild-to-soild ratio of 10:1,H3PO4 dosage of 3 stoichiometric ratio and leaching time of 3 h.Solvent extraction was then employed for the W recovery from the leachate with a organic system of 40%(v/v)N235,30%(v/v)TBP,and 30%sulfonated kerosene.Approximately 99.93%of W was extracted and ammonium tungstate solution containing 193 g/L W was obtained with a stripping rate of 98.10%under the optimized conditions.
