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4,4’-二吡啶及N,N’-取代衍生物在超分子装置中的应用进展
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作者 王亚琴 《安徽建筑工业学院学报(自然科学版)》 2007年第6期73-76,84,共5页
4,4’-二吡啶及N,N’——取代衍生物具有对称的结构和良好的性能,在配位化学,晶体工程,功能材料等领域已经显示出独特的优势。本文主要从分子梭,索烷,(类)轮烷/(类)聚轮烷等超分子装置方面介绍了4,4’-二吡啶及N,N’——取代衍生物的研... 4,4’-二吡啶及N,N’——取代衍生物具有对称的结构和良好的性能,在配位化学,晶体工程,功能材料等领域已经显示出独特的优势。本文主要从分子梭,索烷,(类)轮烷/(类)聚轮烷等超分子装置方面介绍了4,4’-二吡啶及N,N’——取代衍生物的研究现状,并对其应用和发展前景作出了展望。 展开更多
关键词 4 4’-二吡啶及其衍生物 分子梭 索烷 (类)轮烷/(类)聚轮烷 超分子装置
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Atmospheric Methane over the Past 2000 Years from a Sub-tropical Ice Core, Central Himalayas
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作者 LI Jiule XU Baiqing +2 位作者 YAO Tandong WANG Ninglian Ken MacClune 《Journal of Mountain Science》 SCIE CSCD 2010年第1期1-14,共14页
A high-resolution 2ooo-year methane record has been constructed from an ice core recovered at 7200 m a.s.1, on the Dasuopu Glacier in the central Himalayas. This sub-tropical methane record reveals an increasing trend... A high-resolution 2ooo-year methane record has been constructed from an ice core recovered at 7200 m a.s.1, on the Dasuopu Glacier in the central Himalayas. This sub-tropical methane record reveals an increasing trend in the concentration of methane during the industrial era that is similar to observations from polar regions. However, we also observed the differences in the atmospheric methane mixing ratio between this monsoon record and those from polar regions during pre-industrial times. In the time interval o N 1850 A.D., the average methane concentration in the Dasuopu ice core was 782±40 ppbv and the maximum temporal variation exceeded 200 ppbv. The difference gradient of methane concentration in Dasuopu ice core with Greenland and Antarctica cores are 66±40 ppbv and 107±40 ppbv, respectively. This suggests that the tropical latitudes might have acted as a major global methane source in preindustrial times. In addition, the temporal fluctuation of the pre-industrial methane records suggests that monsoon evolution incorporated with high methane emission from south Asia might be responsible for the relatively high methane concentration observed in the Dasuopu ice core around A.D. 800 and A.D. 1600. These results provide a rough understanding of the contribution of tropical methane source to the global methane budget and also the relationship betweenatmospheric methane and climate change. 展开更多
关键词 climate change ice core air bubble atmospheric methane Dasuopu Glacier centralHimalayas
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