极光卵极光强度的空间分布是太阳风-磁层-电离层能量耦合过程的重要表现,并且随着空间环境参数和地磁指数的变化而变化,是空间天气的重要指示器.建立合适的极光强度模型对亚暴的预测以及磁层动力学的研究具有重要意义.本文基于Polar卫...极光卵极光强度的空间分布是太阳风-磁层-电离层能量耦合过程的重要表现,并且随着空间环境参数和地磁指数的变化而变化,是空间天气的重要指示器.建立合适的极光强度模型对亚暴的预测以及磁层动力学的研究具有重要意义.本文基于Polar卫星的紫外极光成像仪(Ultraviolet Imager,UVI)数据,采用两种不同的极光强度表征方法,即曲线拟合方法(从UVI图像数据中提取极光强度沿磁余纬方向上的曲线特征,Curve Feature along the Magnetic Co-latitude Direction of the Auroral Intensity,CFMCD_AI)和网格化方法(从UVI图像数据中提取极光强度的网格化特征,Gridding Feature of the Auroral Intensity,GF_AI),来构造极区极光强度特征数据库.然后,利用该数据库,采用广义回归神经网络(Generalized Regression Neural Network,GRNN)构建了以行星际/太阳风参数(行星际磁场三分量、太阳风速度和密度)和地磁指数(AE指数)为输入参数的两种极光强度预测模型(GRNN_CFMCD_AI模型和GRNN_GF_AI模型).利用图像质量评价指数结构相似度(structure similarity,SSIM)作为极光强度模型预测结果和对应的UVI图像的相似性评价标准(完全相似为1,不相似为0,一般认为SSIM大于0.5是具有较好的相似性),对两种极光强度模型进行了性能评价.结果显示,GRNN_GF_AI模型预测结果对应的SSIM值范围为0.36~0.77,均值为0.54,性能优于GRNN_CFMCD_AI模型的.展开更多
The fabrication and characterization of a Schottky-emitter heterojunction-collector UV-enhanced bipolar phototransistor (SHBT) are presented. The luminescence peak of the ZnO film is observed at 371nm in the PL spec...The fabrication and characterization of a Schottky-emitter heterojunction-collector UV-enhanced bipolar phototransistor (SHBT) are presented. The luminescence peak of the ZnO film is observed at 371nm in the PL spectrum. The sensitivity of the ultraviolet response from 200 to 400nm is enhanced noticeably, and the spectrum response at wavelengths longer than 400nm is also retained, The experiments show that the Au/n-ZnO/p-Si SHBT UV enhanced phototransistor enhances the sensitivity of the ultraviolet response noticeably. The UV response sensitivity at 370nm of the phototransistor is 5-10 times that of a ZnO/Si heterojunction UV enhanced photodiode.展开更多
A different approach,using the molecular beam epitaxy (MBE)-grown ZnS-based Schottky photodiode technology,is applied to fabricate an 8×8 photodiode array.The micro-processing procedures of this photodiode array ...A different approach,using the molecular beam epitaxy (MBE)-grown ZnS-based Schottky photodiode technology,is applied to fabricate an 8×8 photodiode array.The micro-processing procedures of this photodiode array including standard photolithography,a number of metallisation,wet-chemical etching and SiO_2 deposition for insulation are developed.The detector is characterized to have a cutoff wavelength at 340 nm and the photo-responsivity measurements on the pixels result an ultraviolet (UV) response as high as 0.15 A/W,corresponding to an external quantum efficiency of 55% in the visible-blind spectral ranging from 400 down to 250nm.Imaging tests indicate that this array is able to capture the intensity profile of a given UV light source with reasonably good capability.展开更多
With rapid advances of solar blind ultraviolet LED and ultraviolet detecting technology in recent years, ultraviolet communication gradually becomes a research hotspot due to its inherent advantages: low solar backgro...With rapid advances of solar blind ultraviolet LED and ultraviolet detecting technology in recent years, ultraviolet communication gradually becomes a research hotspot due to its inherent advantages: low solar background noise, non-line-of-sight(NLOS) and good secrecy. The strong scattering characteristics in atmospheric render ultraviolet waveband the ideal choice for achieving NLOS optical communication. This paper reviews the research history and status of ultraviolet communication both in China and abroad, and especially introduces three main issues of ultraviolet communication: channel model, system analysis and design, light sources and detectors. For each aspect, current open issues and prospective research directions are analyzed.展开更多
Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the ab...Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the absence of a charge makes it di伍cult for the size selection and detection.Infrared(IR)spectroscopy based on threshold photoionization using a tunable vacuum ultraviolet free electron laser(VUV-FEL)has recently been developed in the lab.The IR-VUV depletion and IR+VUV enhancement spectroscopic techniques open new avenues for size-selected IR spectroscopies of a large variety of neutral clusters without confinement(i.e.,an ultraviolet chromophore,a messenger tag,or a host matrix).The spectroscopic principles have been demonstrated by investigations of some neutral water clusters and some metal carbonyls.Here,the spectroscopic principles and their applications for neutral clusters are reviewed.展开更多
α-pinene is the most abundant monoterpene that represents an important family of volatile organic compounds.Molecular identification of key transient compounds during theα-pinene ozonolysis has been proven to be a c...α-pinene is the most abundant monoterpene that represents an important family of volatile organic compounds.Molecular identification of key transient compounds during theα-pinene ozonolysis has been proven to be a challenging experimental target because of a large number of intermediates and products involved.Here we exploit the recently developed hybrid instruments that integrate aerosol mass spectrometry with a vacuum ultraviolet free-electron laser to study theα-pinene ozonolysis.The experiments ofα-pinene ozonolysis are performed in an indoor smog chamber,with reactor having a volume of 2 m^(3) which is made of fluorinated ethylene propylene film.Distinct mass spectral peaks provide direct experimental signatures of previously unseen compounds produced from the reaction ofα-pinene with O_(3).With the aid of quantum chemical calculations,plausible mechanisms for the formation of these new compounds are proposed.These findings provide crucial information on fundamental understanding of the initial steps ofα-pinene oxidation and the subsequent processes of new particle formation.展开更多
The authors have prepared supramolecular systems as artificial metalloproteins composed of several chiral salen-type Mn(II) and Co(II) complexes in a HSA (human serum albumin) matrix. The docking was discussed b...The authors have prepared supramolecular systems as artificial metalloproteins composed of several chiral salen-type Mn(II) and Co(II) complexes in a HSA (human serum albumin) matrix. The docking was discussed by UV-vis spectral changes and a ligand-protein docking simulation program. After linearly polarized UV light irradiation, that anisotropy of molecular orientation of the complexes increased was confirmed by polarized IR spectra. The authors have observed that the electrochemical behavior of the aligned complexes incorporating diphenyl groups in HSA can be tuned without UV radiation damage of HSA higher structures.展开更多
Significantly improved electrostatic discharge (ESD) properties of InGaN/GaN-based UV light-emitting diode (LED) with in- serting p-GaN/p-A1GaN superlattice (p-SLs) layers (instead of p-A1GaN single layer) bet...Significantly improved electrostatic discharge (ESD) properties of InGaN/GaN-based UV light-emitting diode (LED) with in- serting p-GaN/p-A1GaN superlattice (p-SLs) layers (instead of p-A1GaN single layer) between multiple quantum wells and Mg-doped GaN layer are reported. The pass yield of the LEDs increased from 73.53% to 93.81% under negative 2000 V ESD pulses. In addition, the light output power (LOP) and efficiency droop at high injection current were also improved. The mechanism of the enhanced ESD properties was then investigated. After excluding the effect of capacitance modulation, high-resolution X-ray diffraction (XRD) and atomic force microscope (AFM) measurements demonstrated that the dominant mechanism of the enhanced ESD properties is the material quality improved by p-SLs, which indicated less leakage paths, ra- ther than the current spreading improved by p-SLs.展开更多
A series of novel red tungsto-molybdate phosphors, LiEul-xSmx(WO4)0.5(MoO4)1.5 (x = 0, 0.25%, 0.50%, 0.75%, 1.00%, 2.00% 4.00%, 6.00%, 8.00% and 10.00%), were synthesized using conventional solid state reaction ...A series of novel red tungsto-molybdate phosphors, LiEul-xSmx(WO4)0.5(MoO4)1.5 (x = 0, 0.25%, 0.50%, 0.75%, 1.00%, 2.00% 4.00%, 6.00%, 8.00% and 10.00%), were synthesized using conventional solid state reaction methods. The experimental re- sults indicate that the introduction of Sm^3+ changes neither the crystal structure nor the shape and position of the emission spectra. However, it extends the excitation region at 400 nm and enhances the emission at 615 nm. The reason for the im- provement of red emission of Eu^3+ by the introduction of Sm^3+ and the energy transfer mechanism from Sm^3+ to Eu^3+ was in- vestigated in detail.展开更多
A high performance heterojunction organic ultraviolet photodetector based on NPB and Bphen has been fabricated. A trans- parent conducting polymer PEDOT:PSS coated quartz substrate instead of ITO coated glass substra...A high performance heterojunction organic ultraviolet photodetector based on NPB and Bphen has been fabricated. A trans- parent conducting polymer PEDOT:PSS coated quartz substrate instead of ITO coated glass substrate as anode is propitious to detect shorter wavelength ultraviolet light. As a result, the device shows a low dark current density, a high responsivity of 502 mA/W and a detectivity of 2.67x1012 cm Hz1/Zfw which is illuminated by a 220 nm ultraviolet light with an intensity of 1.6 mW/cm2. Moreover, the performance of the PEDOT:PSS transparent electrode device is better than the semi-transparent A1 electrode device electrode because of the higher transmittance and electrode properties.展开更多
Two silicon-based ultraviolet (UV) and blue-extended photodiodes are presented, which were fabricated for light detection in the ultraviolet/blue spectral range. Stripe-shaped and octagon-ring-shaped structures were...Two silicon-based ultraviolet (UV) and blue-extended photodiodes are presented, which were fabricated for light detection in the ultraviolet/blue spectral range. Stripe-shaped and octagon-ring-shaped structures were designed to verify parameters of the UV-responsivity, UV-selectivity, breakdown voltage, and response time. The ultra-shallow lateral pn junction had been successfully realized in a standard 0.5-μm complementary metal oxide semiconductor (CMOS) process to enlarge the pn junction area, enhance the absorption of UV light, and improve the responsivity and quantum efficiency. The test results illustrated that the stripe-shaped structure has the lower breakdown voltage, higher UV-responsicity, and higher UV-selectivity. But the octagon-ring-shaped structure has the lower dark current. The response time of both structures was almost the same.展开更多
An accurate measurement of the refractive index is necessary for the optical design of both deep ultraviolet laser diodes and light-emitting diodes. Generally, the refractive indices along different crystallographic a...An accurate measurement of the refractive index is necessary for the optical design of both deep ultraviolet laser diodes and light-emitting diodes. Generally, the refractive indices along different crystallographic axes of anisotropic thin films are measured using variable angle spectroscopic ellipsometry.However, there are still some limitations concerning this method. Here we proposed a potential method to measure the band edge refractive index of wide bandgap semiconductor. An aperiodic oscillation emission phenomenon due to the Fabry-Perot effect was observed in the fluorescence spectrum of an AlN film with a thickness of 1500 nm. Based on the characteristics of the fluorescence spectrum and the definition of Fabry-Perot effect, we obtained the ordinary refractive index of the AlN thin film near the band edge directly. This refractive index measurement method is a supplement to the variable angle ellipsometry,and it is a more direct and effective method for transferred film and thinner samples to measure the fluorescence spectrum.展开更多
文摘极光卵极光强度的空间分布是太阳风-磁层-电离层能量耦合过程的重要表现,并且随着空间环境参数和地磁指数的变化而变化,是空间天气的重要指示器.建立合适的极光强度模型对亚暴的预测以及磁层动力学的研究具有重要意义.本文基于Polar卫星的紫外极光成像仪(Ultraviolet Imager,UVI)数据,采用两种不同的极光强度表征方法,即曲线拟合方法(从UVI图像数据中提取极光强度沿磁余纬方向上的曲线特征,Curve Feature along the Magnetic Co-latitude Direction of the Auroral Intensity,CFMCD_AI)和网格化方法(从UVI图像数据中提取极光强度的网格化特征,Gridding Feature of the Auroral Intensity,GF_AI),来构造极区极光强度特征数据库.然后,利用该数据库,采用广义回归神经网络(Generalized Regression Neural Network,GRNN)构建了以行星际/太阳风参数(行星际磁场三分量、太阳风速度和密度)和地磁指数(AE指数)为输入参数的两种极光强度预测模型(GRNN_CFMCD_AI模型和GRNN_GF_AI模型).利用图像质量评价指数结构相似度(structure similarity,SSIM)作为极光强度模型预测结果和对应的UVI图像的相似性评价标准(完全相似为1,不相似为0,一般认为SSIM大于0.5是具有较好的相似性),对两种极光强度模型进行了性能评价.结果显示,GRNN_GF_AI模型预测结果对应的SSIM值范围为0.36~0.77,均值为0.54,性能优于GRNN_CFMCD_AI模型的.
文摘The fabrication and characterization of a Schottky-emitter heterojunction-collector UV-enhanced bipolar phototransistor (SHBT) are presented. The luminescence peak of the ZnO film is observed at 371nm in the PL spectrum. The sensitivity of the ultraviolet response from 200 to 400nm is enhanced noticeably, and the spectrum response at wavelengths longer than 400nm is also retained, The experiments show that the Au/n-ZnO/p-Si SHBT UV enhanced phototransistor enhances the sensitivity of the ultraviolet response noticeably. The UV response sensitivity at 370nm of the phototransistor is 5-10 times that of a ZnO/Si heterojunction UV enhanced photodiode.
文摘A different approach,using the molecular beam epitaxy (MBE)-grown ZnS-based Schottky photodiode technology,is applied to fabricate an 8×8 photodiode array.The micro-processing procedures of this photodiode array including standard photolithography,a number of metallisation,wet-chemical etching and SiO_2 deposition for insulation are developed.The detector is characterized to have a cutoff wavelength at 340 nm and the photo-responsivity measurements on the pixels result an ultraviolet (UV) response as high as 0.15 A/W,corresponding to an external quantum efficiency of 55% in the visible-blind spectral ranging from 400 down to 250nm.Imaging tests indicate that this array is able to capture the intensity profile of a given UV light source with reasonably good capability.
基金supported by the National High-tech R&D Program of China grant 2015AA043302the Basic research project of Shenzhen grant JCYJ20140417115840236
文摘With rapid advances of solar blind ultraviolet LED and ultraviolet detecting technology in recent years, ultraviolet communication gradually becomes a research hotspot due to its inherent advantages: low solar background noise, non-line-of-sight(NLOS) and good secrecy. The strong scattering characteristics in atmospheric render ultraviolet waveband the ideal choice for achieving NLOS optical communication. This paper reviews the research history and status of ultraviolet communication both in China and abroad, and especially introduces three main issues of ultraviolet communication: channel model, system analysis and design, light sources and detectors. For each aspect, current open issues and prospective research directions are analyzed.
基金This work was supported by the National Natural Science Foundation of China(No.92061203 and No.21688102)the Strategic Priority Research Program of Chinese Academy of Sciences(XDB17000000)+3 种基金International Partnership Program of Chinese Academy of Sciences(121421KYSB20170012)Chinese Academy of Sciences(GJJSTD20190002)K.C.Wong Education Foundation(GJTD-2018-06)Dalian Institute of Chemical Physics(DICP DCLS201702).
文摘Spectroscopic characterization of clusters is crucial to understanding the structures and reaction mechanisms at the microscopic level,but it has been proven to be a grand challenge for neutral clusters because the absence of a charge makes it di伍cult for the size selection and detection.Infrared(IR)spectroscopy based on threshold photoionization using a tunable vacuum ultraviolet free electron laser(VUV-FEL)has recently been developed in the lab.The IR-VUV depletion and IR+VUV enhancement spectroscopic techniques open new avenues for size-selected IR spectroscopies of a large variety of neutral clusters without confinement(i.e.,an ultraviolet chromophore,a messenger tag,or a host matrix).The spectroscopic principles have been demonstrated by investigations of some neutral water clusters and some metal carbonyls.Here,the spectroscopic principles and their applications for neutral clusters are reviewed.
基金financially supported by the National Natural Science Foundation of China(No.22125303,No.92061203,and No.21688102)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB17000000)+2 种基金Dalian Institute of Chemical Physics(DICP DCLS201701)Chinese Academy of Sciences(No.GJJSTD20190002)K.C.Wong Education Foundation(No.GJTD-2018-06)。
文摘α-pinene is the most abundant monoterpene that represents an important family of volatile organic compounds.Molecular identification of key transient compounds during theα-pinene ozonolysis has been proven to be a challenging experimental target because of a large number of intermediates and products involved.Here we exploit the recently developed hybrid instruments that integrate aerosol mass spectrometry with a vacuum ultraviolet free-electron laser to study theα-pinene ozonolysis.The experiments ofα-pinene ozonolysis are performed in an indoor smog chamber,with reactor having a volume of 2 m^(3) which is made of fluorinated ethylene propylene film.Distinct mass spectral peaks provide direct experimental signatures of previously unseen compounds produced from the reaction ofα-pinene with O_(3).With the aid of quantum chemical calculations,plausible mechanisms for the formation of these new compounds are proposed.These findings provide crucial information on fundamental understanding of the initial steps ofα-pinene oxidation and the subsequent processes of new particle formation.
文摘The authors have prepared supramolecular systems as artificial metalloproteins composed of several chiral salen-type Mn(II) and Co(II) complexes in a HSA (human serum albumin) matrix. The docking was discussed by UV-vis spectral changes and a ligand-protein docking simulation program. After linearly polarized UV light irradiation, that anisotropy of molecular orientation of the complexes increased was confirmed by polarized IR spectra. The authors have observed that the electrochemical behavior of the aligned complexes incorporating diphenyl groups in HSA can be tuned without UV radiation damage of HSA higher structures.
基金supported by the National Natural Science Foundation of China(Grant No.61204006)the Fundamental Research Funds for the Central Universities(Grant No.K50511250002)the National Key Science&Technology Special Project(Grant No.2008ZX01002-002)
文摘Significantly improved electrostatic discharge (ESD) properties of InGaN/GaN-based UV light-emitting diode (LED) with in- serting p-GaN/p-A1GaN superlattice (p-SLs) layers (instead of p-A1GaN single layer) between multiple quantum wells and Mg-doped GaN layer are reported. The pass yield of the LEDs increased from 73.53% to 93.81% under negative 2000 V ESD pulses. In addition, the light output power (LOP) and efficiency droop at high injection current were also improved. The mechanism of the enhanced ESD properties was then investigated. After excluding the effect of capacitance modulation, high-resolution X-ray diffraction (XRD) and atomic force microscope (AFM) measurements demonstrated that the dominant mechanism of the enhanced ESD properties is the material quality improved by p-SLs, which indicated less leakage paths, ra- ther than the current spreading improved by p-SLs.
基金supported by the Natural Science Foundation of Fujian Province (Grant No. 2011J05142)the Ministry of Education in China Project of Humanities and Social Sciences (Grant No. 11YJC820135)
文摘A series of novel red tungsto-molybdate phosphors, LiEul-xSmx(WO4)0.5(MoO4)1.5 (x = 0, 0.25%, 0.50%, 0.75%, 1.00%, 2.00% 4.00%, 6.00%, 8.00% and 10.00%), were synthesized using conventional solid state reaction methods. The experimental re- sults indicate that the introduction of Sm^3+ changes neither the crystal structure nor the shape and position of the emission spectra. However, it extends the excitation region at 400 nm and enhances the emission at 615 nm. The reason for the im- provement of red emission of Eu^3+ by the introduction of Sm^3+ and the energy transfer mechanism from Sm^3+ to Eu^3+ was in- vestigated in detail.
基金supported by the National Natural Science Foundation of China (Grant No. 50972007)the Beijing Municipal Natural Science Foundation (Grant No. 4092035)+3 种基金the National Basic Research Program of China (973 Program) of the Ministry of Science and Technology of China(Grant No. 2011CB932703)the National Science Fund for Distinguished Young Scholars (Grant No. 60825407)the Special Items Fund of the Beijing Municipal Commission of Educationthe Opened Fund of the State Key Laboratory of Integrated Optoelectronics
文摘A high performance heterojunction organic ultraviolet photodetector based on NPB and Bphen has been fabricated. A trans- parent conducting polymer PEDOT:PSS coated quartz substrate instead of ITO coated glass substrate as anode is propitious to detect shorter wavelength ultraviolet light. As a result, the device shows a low dark current density, a high responsivity of 502 mA/W and a detectivity of 2.67x1012 cm Hz1/Zfw which is illuminated by a 220 nm ultraviolet light with an intensity of 1.6 mW/cm2. Moreover, the performance of the PEDOT:PSS transparent electrode device is better than the semi-transparent A1 electrode device electrode because of the higher transmittance and electrode properties.
基金This work is supported by the State Key Program of National Natural Science of China (61233010), by the National Natural Science Foundation of China (61274043) and by the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET- 11-0975). Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
文摘Two silicon-based ultraviolet (UV) and blue-extended photodiodes are presented, which were fabricated for light detection in the ultraviolet/blue spectral range. Stripe-shaped and octagon-ring-shaped structures were designed to verify parameters of the UV-responsivity, UV-selectivity, breakdown voltage, and response time. The ultra-shallow lateral pn junction had been successfully realized in a standard 0.5-μm complementary metal oxide semiconductor (CMOS) process to enlarge the pn junction area, enhance the absorption of UV light, and improve the responsivity and quantum efficiency. The test results illustrated that the stripe-shaped structure has the lower breakdown voltage, higher UV-responsicity, and higher UV-selectivity. But the octagon-ring-shaped structure has the lower dark current. The response time of both structures was almost the same.
基金This work was financially supported by the National Natural Science Foundation of China(91333207,61427901,61604178,91833301 and U1505252).
文摘An accurate measurement of the refractive index is necessary for the optical design of both deep ultraviolet laser diodes and light-emitting diodes. Generally, the refractive indices along different crystallographic axes of anisotropic thin films are measured using variable angle spectroscopic ellipsometry.However, there are still some limitations concerning this method. Here we proposed a potential method to measure the band edge refractive index of wide bandgap semiconductor. An aperiodic oscillation emission phenomenon due to the Fabry-Perot effect was observed in the fluorescence spectrum of an AlN film with a thickness of 1500 nm. Based on the characteristics of the fluorescence spectrum and the definition of Fabry-Perot effect, we obtained the ordinary refractive index of the AlN thin film near the band edge directly. This refractive index measurement method is a supplement to the variable angle ellipsometry,and it is a more direct and effective method for transferred film and thinner samples to measure the fluorescence spectrum.