Natural amber, copal resin and colophony are have investigated by UV-VIS, infrared and Raman spectrum. In order to distin- guish the natural amber, copal resin and colophony, we have successfully used the nondestructi...Natural amber, copal resin and colophony are have investigated by UV-VIS, infrared and Raman spectrum. In order to distin- guish the natural amber, copal resin and colophony, we have successfully used the nondestructive examination (NDE) technology. The results show that UV-VIS could not distinguish these compositions. The infrared spectra can distinguish them, but the technology may destroy the specimen. The Raman spectra show three characteristic peaks of vibration near position 932 cmq and position 1179 cmq of copal resin, which confirm the existence of terpenes compounds in it. In the Raman spectra of colophony, the vibration characteristic peak at position 1589 cmq, caused by the conjugate double bond of internal unsaturated resin acid, is the basis of the characteristic difference between colophony and natural amber. The advantages of the distin- guished technology by Raman spectroscopy are convenient and nondestructive examination for natural amber, copal resin and colophony.展开更多
基金the National Natural Science Foundation of China (Grant No. 51261011)the Science and Technology Program of Yunnan (Grant No. 2010DH025)
文摘Natural amber, copal resin and colophony are have investigated by UV-VIS, infrared and Raman spectrum. In order to distin- guish the natural amber, copal resin and colophony, we have successfully used the nondestructive examination (NDE) technology. The results show that UV-VIS could not distinguish these compositions. The infrared spectra can distinguish them, but the technology may destroy the specimen. The Raman spectra show three characteristic peaks of vibration near position 932 cmq and position 1179 cmq of copal resin, which confirm the existence of terpenes compounds in it. In the Raman spectra of colophony, the vibration characteristic peak at position 1589 cmq, caused by the conjugate double bond of internal unsaturated resin acid, is the basis of the characteristic difference between colophony and natural amber. The advantages of the distin- guished technology by Raman spectroscopy are convenient and nondestructive examination for natural amber, copal resin and colophony.