气泡—絮粒的粘附

气泡与絮粒的粘附是气浮净水中至关重要的一个阶段。本文从“分离压”的基本原理出发,通过气泡-絮拉间残留水化层性能的测定计算,探讨了气泡与絮粒粘附时液膜薄化的物理因素和化学因素。借助高速摄影,结合统计分析,研究了气泡-絮粒粘附过程的机理,得出了几点有关信息。

谈谈DAF法中絮粒的最佳尺寸

本文通过对 DAF 法中带气絮粒的受力分析,找出了影响其上浮速度U_p 的因素。然后进一步通过对气浮池中气泡容积浓度_b 的计算,并结合 Edzwald 等的试验结果认为:进入气浮池的絮粒尺寸不必过大,最佳范同为10—30μm。溶气气浮法(DAF 法)的出现虽然只有二十几年,但其发展的速度却是迅速的。目前,DAF 装置已广泛应用于炼油、造纸、印染、电镀、化纤、食品、浴室等领域的废水处理,在给水处理中的应用也在增多。仅我国近十年来就已拥有十余座各类气浮净水装置,新编给水排水设计手册中也已增加了这方面的内容。总的说来,我国在 DAF 法净水技术的基本理论研究与生产实践上都已达到国际水平。然而在全面应用过程中也发现了不少问题。如果以系统在运行时发现絮粒与气泡的粘附性很差,在设计和选用设备时主观随意性很大等。本文讨论的是 DAF 法中絮粒的最佳尺寸问题。絮粒尺寸不仅对 DAF 法的净水效果影响很大,而且对反应池容积,反应运行过程中的动力消耗、混凝剂投量等经济因素的确定有很大的参考价值,因此能够确定絮粒的最佳尺寸是有一定意义的。

QF160气浮机在染色废水处理中的应用

叙述了QF160气浮机的工作原理、气固比计算、气泡与絮粒的粘附及气浮净水的最佳pH值。

Floc flotation of marmatite fines in aqueous suspensions induced by butyl xanthate and ammonium dibutyl dithiophosphate

The hydrophobic flocculation of marmatite fines in aqueous suspensions induced by butyl xanthate （KBX） and ammonium dibutyl dithiophosphate （ADD） was investigated using laser particle size analysis, microscopy analysis, electrophoretic light scattering, contact angle measurement and infrared spectroscopy. The studies were performed on single minerals with size 〈20 μm by varying several parameters, including pH, collector concentration and kerosene addition. The results show that the floc fotation closely correlated with the size of flocs and the particle hydrophobicity, but was not lowered with increasing the particle surface charges due to collector adsorption. Under good operating conditions, the floc flotation of marmatite fines as a function of KBX and ADD can all reach floatability over 90%, in comparison with conventional flotation obtaining floatability of about 60%. It also has been found that a small addition of kerosene greatly improved the floc flotation because of the formation of oil films on marmatite particles. The results of FTIR spectra indicate that adsorption of the two collectors onto marmatite were chemical adsorption.

The Short-term Effects of Temperature and Free Ammonia on Ammonium Oxidization in Granular and Floccular Nitrifying System

The short-term effects of temperature and free ammonia (FA) on ammonium oxidization were investigated in this study by operating several batch tests with two different partial nitrification aggregates, formed as either granules or flocs. The results showed that the rate of ammonium oxidation in both cultures increased significantly as temperature increased from 10 to 30 °C. The specific ammonium oxidation rate with the granules was 2-3 times higher than that with flocs at the same temperature. Nitrification at various FA concentrations and temperatures combination exhibited obvious inhibition in ammonium oxidation rate when FA was 90 mg·L 1 and tempera- ture dropped to 10 °C in the two systems. However, the increase in substrate oxidation rate of ammonia at 30 °C was observed. The results suggested that higher reaction temperature was helpful to reduce the toxicity of FA. Granules appeared to be more tolerant to FA attributed to the much fraction of ammonia oxidizing bacteria (AOB) and higher resistance to the transfer of ammonia into the bacterial aggregates, whereas in the floc system, the bacteria distributed throughout the entire aggregate. These results may contribute to the applicability of the nitrifying granules in wastewater treatment operated at high ammonium concentration.

Hydrophobic flocculation flotation of rutile fines in presence of styryl phosphonic acid

The hydrophobic flocculation flotation of rutile fines in the presence of styryl phosphonic acid（SPA） was investigated by flotation tests, zeta-potential measurement, optical microscope observation, laser-based particle size analysis, adsorption measurements and DLVO theory. The flotation tests indicated that rutile fines could be flocculated by SPA, and pH, shear force（stirring speed） and stirring time played significant roles in flocculation. The isoelectric point（IEP） and zeta-potential in whole range all moved to negative values as SPA was added according to the results from zeta-potential measurement. It was demonstrated that the primary reason for above was chemical adsorption. The laser-based particle size results showed the particle size at a stirring speed of 1800 r/min and 1000 mg/L SPA was the largest in all experiments. Furthermore, using the optical microscope observation and flotation tests, it was important for flotation of rutile fines to produce the flocculant. In the light of above-mentioned facts, floc flotation of rutile fines could be induced in the form of chemical adsorption by SPA to increase particle size. The data calculated from DLVO theory also indicated that chemical adsorption was the main reason for the formation of flocculant.

Effect of magnetic seeding agglomeration on flotation of fine minerals

Magnetic seeding agglomeration(MSA),i.e.,adding magnetic seeds and a low intensity pre-magnetization for fine agglomeration,was applied to the flotation of coal,pyrite and hematite ore slimes.Size analysis and flotation tests highlight that the MSA improved flotation recovery and kinetics of pyrite ore while causing some loss in selectivity,and in the presences of the polyacrylamide for coal and starch for hematite the agglomeration flotation was further strengthened due to the synergetic effect between the flocculants and magnetic seeds.Magnetism analyses and calculation confirmed the adsorption of magnetic seeds onto minerals,resulting in a decreased threshold magnetic field intensity for the MSA to happen.Then atomic force microscope(AFM)study found that there exists a long range force between magnetic seeds and minerals,which facilitates the adsorption of magnetic seeds on minerals.FTIR shows both the polyacrylamide and starch adsorbed onto minerals and magnetic seeds,thus acting as the bridging media between minerals and magnetic seeds,intensifying the agglomeration in flotation.Surface characterization of the MSA was understood by SEM imaging,and models of the MSA were proposed.

Numerical simulation of flocculation and settling behavior of whole-tailings particles in deep-cone thickener

Rapid dewatering and thickening of whole-tailings with ultrafine particles is one of the most important processes for the whole-tailings paste preparation. Deep-cone thickener, a kind of such process for the flocculation and settling of whole-tailings, is particularly necessary to study. However, there exist many problems in observing the flocculation and settling process of whole-tailings, as well as the particle size distribution(PSD) of whole-tailings floccules in deep-cone thickener. Population balance model(PBM) is applied to predict the PSD in deep-cone thickener, and LUO model and GHADIRI model are employed to study the aggregation and fragmentation mechanism of the whole-tailings particles, respectively. Through three-dimensional numerical simulation on the whole-tailings flocculation and settling in deep-cone thickener using computational fluid dynamics(CFD)-PBM, the distribution of density and turbulent kinetic energy in deep-cone thickener were obtained, at the same time the spatio-temporal changes of whole-tailings floccules particle size distribution are analyzed. Finally, the major flocculation position in deep-cone thickener is found and the flocculation settling rules of whole-tailings are achieved.

Fractal dimensions of flocs between clay particles and HAB organisms

The impact of harmful algal blooms （HABs） on public health and related economics have been increasing in many coastal regions of the world. Sedimentation of algal cells through flocculation with clay particles is a promising strategy for controlling HABs. Previous studies found that removal efficiency （RE） was influenced by many factors, including clay type and concentration, algal growth stage, and physiological aspects of HAB cells. To estimate the effect of morphological characteristics of the aggregates on HAB cell removal, fractal dimensions were measured and the RE of three species of HAB organism, Heterosigma akashiwo, Alexandrium tamarense, and Skeletonema eostatum, by original clay and modified clay, was determined. For all HAB species, the modified clay had a higher RE than original clay. For the original clay, the two-dimensional fractal dimension （D2） was 1.92 and three-dimensional ffactal dimension （D3） 2.81, while for the modified clay, D2 was 1.84 and D3 was 2.50. The addition of polyaluminum chloride （PAC1） lead to a decrease of the repulsive barrier between clay particles, and resulted in lower D2 and D3. Due to the decrease of D3, and the increase of the effective sticking coefficient, the flocculation rate between modified clay particles and HAB organisms increased, and thus resulted in a high RE. The fractal dimensions of flocs differed in HAB species with different cell morphologies. For example, Alexandrium tamarense cells are ellipsoidal, and the D3 and D2 of flocs were the highest, while for Skeletonema costatum, which has filamentous cells, the D3 and D2 of flocs were the lowest.

Characteristics of the dynamic distribution of suspended particles in the flocculation process

Polyaluminium chloride (PAC) synthetic water was selected as a coagulant and kaolin suspension particles as objects to be removed. Online instruments such as the turbidimeter and particle counter were employed to monitor the flocculation process online and collect test data. The aim of the experiments was to study the dynamic distribution characteristics of suspension particles in the flocculation process. The 3D flow field in the reacting vessel was also simulated at different slow stirring speeds. The experiments showed that particle collision and aggregation in the flocculation process is in compliance with the Sutherland cluster aggregation model. This study further indicated that under appropriate hydrodynamic conditions, the distribution of turbulent flow in the reactor could be improved to increase the odds of effective particle collision and restrain the breakup of formed flocs by vortex shearing force. A good flocculation effect could therefore be produced.