The precursore Zn（en）2S （en=ethylenediamine） were prepared via a solvothermal process from elemental sulfur and zinc using ethylenediamine as a solvent. Detailed characterizations of the infrared （IR） absorption...The precursore Zn（en）2S （en=ethylenediamine） were prepared via a solvothermal process from elemental sulfur and zinc using ethylenediamine as a solvent. Detailed characterizations of the infrared （IR） absorption spectrum, powder X-ray diffraction （XRD） and thermogravimetric analysis （TG） confirmed two en coordinated with Zn2+ to form a complex cation. The morphological property was also characterized by transmission electron microscopy （TEM ） and electron diffraction analysis （ED）. Phase-pure hexagonal wurtzite ZnS products were obtained by annealing the precursor in nitrogen stream at about 900 ℃. Zn（en）2S showed a nanosize of about 30 nm, and ZnS of about 60 nm. The fluorescence spectra were also studied. PL results showed that Zn（en）2S excited a fluorescence at 452 nm.展开更多
文摘The precursore Zn（en）2S （en=ethylenediamine） were prepared via a solvothermal process from elemental sulfur and zinc using ethylenediamine as a solvent. Detailed characterizations of the infrared （IR） absorption spectrum, powder X-ray diffraction （XRD） and thermogravimetric analysis （TG） confirmed two en coordinated with Zn2+ to form a complex cation. The morphological property was also characterized by transmission electron microscopy （TEM ） and electron diffraction analysis （ED）. Phase-pure hexagonal wurtzite ZnS products were obtained by annealing the precursor in nitrogen stream at about 900 ℃. Zn（en）2S showed a nanosize of about 30 nm, and ZnS of about 60 nm. The fluorescence spectra were also studied. PL results showed that Zn（en）2S excited a fluorescence at 452 nm.
