提出了激光-数字化精确控制短路过渡电弧复合热源焊接新方法。以CMT(Cold Metal Transfer)电弧焊和激光-CMT复合热源焊接为例,利用304不锈钢平板堆焊,对比分析了CMT电弧焊及激光-CMT电弧复合热源的焊缝成形特点,研究了在采用纯Ar保护气...提出了激光-数字化精确控制短路过渡电弧复合热源焊接新方法。以CMT(Cold Metal Transfer)电弧焊和激光-CMT复合热源焊接为例,利用304不锈钢平板堆焊,对比分析了CMT电弧焊及激光-CMT电弧复合热源的焊缝成形特点,研究了在采用纯Ar保护气体焊接304不锈钢时的激光-CMT电弧复合热源焊接过程稳定性、飞溅、焊缝成形特征、焊接效率及焊接接头的力学性能,并将试验结果与304不锈钢TIG填丝焊进行对比。分析结果表明,纯Ar保护激光-CMT复合热源焊接接头的综合力学性能与TIG填丝焊接头的综合力学性能相当,但焊接效率可以提高5倍,因此在不锈钢和镍基合金等高性能金属材料的焊接中,用纯Ar保护的激光-CMT电弧复合热源焊接取代TIG填丝焊具有可行性。展开更多
利用光学显微镜、X射线衍射(XRD)和扫描电子显微镜的电子背散射衍射花样(electronic backscatter ring diffraction,EBSD),对用化学气相沉积制备的高纯钨进行了微观结构和晶面取向分析;利用霍普金森压杆系统和电子万能试验机测试了高纯...利用光学显微镜、X射线衍射(XRD)和扫描电子显微镜的电子背散射衍射花样(electronic backscatter ring diffraction,EBSD),对用化学气相沉积制备的高纯钨进行了微观结构和晶面取向分析;利用霍普金森压杆系统和电子万能试验机测试了高纯钨的动态和准静态力学性能。研究表明:化学气相沉积高纯钨具有柱状晶组织,并且具有明显的(100)择优取向;动态屈服强度达到2000MPa以上,静态屈服强度约为1350MPa,具有应变速率敏感性。展开更多
Oxidation characteristics of Alloy 617 and Haynes 230 at 900 oC in simulated helium environment,hot steam environment containing H2 as well as in air and pure helium conditions were investigated.Compared to air condit...Oxidation characteristics of Alloy 617 and Haynes 230 at 900 oC in simulated helium environment,hot steam environment containing H2 as well as in air and pure helium conditions were investigated.Compared to air condition,the oxidation rate of Alloy 617 was not significantly affected in helium and hot steam environments,while Haynes 230 showed lower oxidation rate in helium environment.On the other hand,the oxide morphology and structure of Alloy 617 were strongly affected by the environments,but those of Haynes 230 were less dependent on the environments.For Haynes 230,a Cr2O3 inner layer and a protective MnCr2O4 outer layer were formed in all environments,which contributed to the better oxidation resistance.As the mechanical properties,such as creep and tensile properties,were significantly affected by the oxidation behaviors,surface treatment methods to enhance oxidation resistance of these alloys should be developed.展开更多
In the hydrogen network with the minimum hydrogen utility flow rate,the pinch appears at the point with zero hydrogen surplus,while the hydrogen surpluses of all the other points are positive.In the hydrogen purity pr...In the hydrogen network with the minimum hydrogen utility flow rate,the pinch appears at the point with zero hydrogen surplus,while the hydrogen surpluses of all the other points are positive.In the hydrogen purity profiles,the pinch can only lie at the sink-tie-line intersecting the source purity profile.According to the alternative distribution of the negative and positive regions,the effect of the purification to the hydrogen surplus is analyzed.The results show that when the purification is applied,the pinch point will appear neither above the purification feed nor between the initial pinch point and the purification feed,no matter the purification feed lies above or below the initial pinch point.This is validated by two case studies.展开更多
The permselectivity of H2/O2, H2/N2, H2/CO, and H2/CH4 mixtures passing a graphdiyne membrane is studied by molecular dynamics simulations. At pressure range of 0.047-4.5 GPa, H2 can pass the graphdiyen membrane quick...The permselectivity of H2/O2, H2/N2, H2/CO, and H2/CH4 mixtures passing a graphdiyne membrane is studied by molecular dynamics simulations. At pressure range of 0.047-4.5 GPa, H2 can pass the graphdiyen membrane quickly, while all the O2, N2, CO, and CH4 molecules are blocked. At pressure of 47 kPa, the hydrogen flow is 7 mol/m^2s. With increase of pressure, the hydrogen flow goes up, and reaches maximum of 6×10^5 mol/m^2s at 1.5 GPa. Compared to other known membranes, graphdiyne can be used for means of hydrogen purification with the best balance of high selectivity and high permeance.展开更多
文摘提出了激光-数字化精确控制短路过渡电弧复合热源焊接新方法。以CMT(Cold Metal Transfer)电弧焊和激光-CMT复合热源焊接为例,利用304不锈钢平板堆焊,对比分析了CMT电弧焊及激光-CMT电弧复合热源的焊缝成形特点,研究了在采用纯Ar保护气体焊接304不锈钢时的激光-CMT电弧复合热源焊接过程稳定性、飞溅、焊缝成形特征、焊接效率及焊接接头的力学性能,并将试验结果与304不锈钢TIG填丝焊进行对比。分析结果表明,纯Ar保护激光-CMT复合热源焊接接头的综合力学性能与TIG填丝焊接头的综合力学性能相当,但焊接效率可以提高5倍,因此在不锈钢和镍基合金等高性能金属材料的焊接中,用纯Ar保护的激光-CMT电弧复合热源焊接取代TIG填丝焊具有可行性。
文摘利用光学显微镜、X射线衍射(XRD)和扫描电子显微镜的电子背散射衍射花样(electronic backscatter ring diffraction,EBSD),对用化学气相沉积制备的高纯钨进行了微观结构和晶面取向分析;利用霍普金森压杆系统和电子万能试验机测试了高纯钨的动态和准静态力学性能。研究表明:化学气相沉积高纯钨具有柱状晶组织,并且具有明显的(100)择优取向;动态屈服强度达到2000MPa以上,静态屈服强度约为1350MPa,具有应变速率敏感性。
基金supported by the MEST/NRF (Nuclear R&D Program,2005-2004718 and 2009 0083392) of Korea
文摘Oxidation characteristics of Alloy 617 and Haynes 230 at 900 oC in simulated helium environment,hot steam environment containing H2 as well as in air and pure helium conditions were investigated.Compared to air condition,the oxidation rate of Alloy 617 was not significantly affected in helium and hot steam environments,while Haynes 230 showed lower oxidation rate in helium environment.On the other hand,the oxide morphology and structure of Alloy 617 were strongly affected by the environments,but those of Haynes 230 were less dependent on the environments.For Haynes 230,a Cr2O3 inner layer and a protective MnCr2O4 outer layer were formed in all environments,which contributed to the better oxidation resistance.As the mechanical properties,such as creep and tensile properties,were significantly affected by the oxidation behaviors,surface treatment methods to enhance oxidation resistance of these alloys should be developed.
基金Supported by the State Key Development Program for Basic Research of China（2012CB720500） the National Natural Science Foundation of China（21276205,20936004） the State Key Laboratory of Heavy Oil Processing
文摘In the hydrogen network with the minimum hydrogen utility flow rate,the pinch appears at the point with zero hydrogen surplus,while the hydrogen surpluses of all the other points are positive.In the hydrogen purity profiles,the pinch can only lie at the sink-tie-line intersecting the source purity profile.According to the alternative distribution of the negative and positive regions,the effect of the purification to the hydrogen surplus is analyzed.The results show that when the purification is applied,the pinch point will appear neither above the purification feed nor between the initial pinch point and the purification feed,no matter the purification feed lies above or below the initial pinch point.This is validated by two case studies.
基金V. ACKNOWLEDGMENTS This work was supported by the National Natu- ral Science Foundation of China （No.20603032 and 20733004）, the National Key Basic Research Program （No.2011CB921400）, the Foundation of National Excellent Doctoral Dissertation of China （No.200736）, the Fundamental Research Funds for the Central Universities （No.WK2340000006 and No.WK2060140005）, and the Shanghai Supercomputer Center, the USTC-HP HPC Project, and the SCCAS.
文摘The permselectivity of H2/O2, H2/N2, H2/CO, and H2/CH4 mixtures passing a graphdiyne membrane is studied by molecular dynamics simulations. At pressure range of 0.047-4.5 GPa, H2 can pass the graphdiyen membrane quickly, while all the O2, N2, CO, and CH4 molecules are blocked. At pressure of 47 kPa, the hydrogen flow is 7 mol/m^2s. With increase of pressure, the hydrogen flow goes up, and reaches maximum of 6×10^5 mol/m^2s at 1.5 GPa. Compared to other known membranes, graphdiyne can be used for means of hydrogen purification with the best balance of high selectivity and high permeance.
