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基于SAXS的不同变质程度煤纳米级孔隙结构特征研究 被引量:1
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作者 张钰 李勇 +3 位作者 王延斌 王壮森 赵石虎 韩文龙 《煤田地质与勘探》 CAS CSCD 北大核心 2021年第6期142-150,共9页
为揭示不同变质程度煤岩纳米级孔隙特征,运用小角X射线散射方法(SAXS),采集镜质体反射率R_(max)在0.31%~6.24%的15个样品,基于散射数据获取的煤岩孔隙率、孔径分布、比表面积和分形维数,讨论了煤化过程对煤岩纳米孔隙(0.3~100nm)结构的... 为揭示不同变质程度煤岩纳米级孔隙特征,运用小角X射线散射方法(SAXS),采集镜质体反射率R_(max)在0.31%~6.24%的15个样品,基于散射数据获取的煤岩孔隙率、孔径分布、比表面积和分形维数,讨论了煤化过程对煤岩纳米孔隙(0.3~100nm)结构的影响,并用低温CO_(2)和N_(2)吸附DFT模型结果对孔径分布进行了验证。结果表明:在R_(max)<0.5%时,煤岩孔隙率和比表面积随着变质程度的增加而增加,微孔(<2nm)含量增长较少,介孔(2~50nm)和大孔(50~100nm)含量大幅增加,煤岩表面逐渐光滑;在R_(max)=0.5%~1.4%时,孔隙率和比表面积减小,各类孔隙含量均减少,煤岩表面逐渐光滑;在R_(max)=1.4%~4.0%时,煤岩孔隙率和比表面积增大,微孔含量大幅增加,介孔和大孔含量近乎稳定,煤岩表面逐渐粗糙;在R_(max)>4.0%后,煤岩孔隙率和比表面积缓慢增加,微孔增长幅度变缓,煤岩表面逐渐光滑。SAXS在0.3~100nm孔径分布(本次实验范围)中用球形形状因子与低温CO_(2)和N_(2)吸附结果契合度较高,煤中纳米级孔隙率及比表面积主要由微孔贡献。 展开更多
关键词 变质程度 小角X射线散射 纳米孔隙特征 分形特征 煤化作用
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Atomic force microscopy study on microstructure of various ranks of coals
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作者 Jie-Nan PAN Hai-Tao ZHU He-Ling BAI Yan-Qing ZHAO Hai-Chao WANG Li-Ping YAO 《Journal of Coal Science & Engineering(China)》 2013年第3期309-315,共7页
As a new technology, Atomil Force Microscopy (AFM) is being used in the research of microscopic structure on coal surface in recent years. By this technology, we can observe the nanoscale pore and crack shape of coa... As a new technology, Atomil Force Microscopy (AFM) is being used in the research of microscopic structure on coal surface in recent years. By this technology, we can observe the nanoscale pore and crack shape of coal surface, and measure some structural parameters. Different metamorphic grades produce different feature of surface microscopic structure of coal. This paper analyzes the surface microscopic structure of different metamorphic grade coal by AFM. The results show that the coal surface microstructure has a trend from rough to smooth with the increasing of metamorphic grade. The low rank coals contain large or medium pores and the high rank coals contain micro pores. The values of surface morphology characteristic parameters (Sq and Sa) nonlinearly decrease with the increasing coal rank. That is, the coal surface becomes smoother during coalification. 展开更多
关键词 atomic force microscopy (AFM) metamorphic degree MICRO-STRUCTURE nanoscale pore
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