The spheric La2O3∶Eu nanocrystals were prepared using NH3·H2O-NH4HCO3 mixture as precipitant. The material was characterized by FTIR, XRD and TEM techniques. The luminescence properties of Eu3+ in spheric La2O3 ...The spheric La2O3∶Eu nanocrystals were prepared using NH3·H2O-NH4HCO3 mixture as precipitant. The material was characterized by FTIR, XRD and TEM techniques. The luminescence properties of Eu3+ in spheric La2O3 were measured by three dimension spectra, emission and excitation spectra. The results indicate that the La2O3∶Eu nanocrystals are in hexagonal phase by annealing at 800 ℃, the crystal size is about 30 nm. The maximum emission and excitation wavelength were determined by three dimensional spectroscopy to be at 591 nm and 394 nm, respectively. In emission spectrum the band at 591 nm and 612 nm are corresponding to 5D0-7F1 and 5D0-7F2 transition of Eu3+ ions. With increasing in annealing temperature the differences of intensity of the two transitions are increased. This phenomenon shows that the luminescence intensity of La2O3∶Eu nanocrystals can be tuned by changing annealing temperature.展开更多
Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and ...Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30～300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines.展开更多
文摘The spheric La2O3∶Eu nanocrystals were prepared using NH3·H2O-NH4HCO3 mixture as precipitant. The material was characterized by FTIR, XRD and TEM techniques. The luminescence properties of Eu3+ in spheric La2O3 were measured by three dimension spectra, emission and excitation spectra. The results indicate that the La2O3∶Eu nanocrystals are in hexagonal phase by annealing at 800 ℃, the crystal size is about 30 nm. The maximum emission and excitation wavelength were determined by three dimensional spectroscopy to be at 591 nm and 394 nm, respectively. In emission spectrum the band at 591 nm and 612 nm are corresponding to 5D0-7F1 and 5D0-7F2 transition of Eu3+ ions. With increasing in annealing temperature the differences of intensity of the two transitions are increased. This phenomenon shows that the luminescence intensity of La2O3∶Eu nanocrystals can be tuned by changing annealing temperature.
文摘Eu(DBM) 3·H 2O nanocrystallites were obtained by the chemical precipitation method.By the elemental analyzer,infrared spectrum,TGA-DSC and TEM,that the construction of nanocrystallines,the thermal properties and size were confirmed,in addition,fluorescence excitation and emission spectrum,ultraviolet absorption spectrums were investigation.Then the nanocrystallines were incorporated into the copolymer system of styrene and methyl acrylic acid,the fluorescence functional polymer nanometer material with high lanthanide content (50、wt%) were obtained.The experiment indicated that Eu(DBM) 3·H 2O nanocrystallines particle sizes were in 30～300、nm,it exhibited europium ion charlatanistic luminescence.The optical resins could provide a relatively stable environment for Eu(DBM) 3·H 2O nanocrystallines.
