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纳米磁性炭对氨氮吸附特性的影响研究 被引量:7
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作者 邸璐 王芳 +4 位作者 王霞 易维明 张德俐 陈晓云 李永军 《可再生能源》 CAS CSCD 北大核心 2021年第11期1421-1427,共7页
氨氮在水体中大量存在会使水质发生变化,引发藻华等水体危害。生物炭对氨氮废水具有较好的吸附效果,但普通生物炭完成吸附后无法回收,容易造成二次污染与资源浪费。文章在玉米秸秆生物炭的基础上制备了纳米磁性炭,通过元素分析,SEM,XRD,... 氨氮在水体中大量存在会使水质发生变化,引发藻华等水体危害。生物炭对氨氮废水具有较好的吸附效果,但普通生物炭完成吸附后无法回收,容易造成二次污染与资源浪费。文章在玉米秸秆生物炭的基础上制备了纳米磁性炭,通过元素分析,SEM,XRD,FTIR和BET等一系列表征分析,结合批式吸附试验,探究了纳米磁性炭对氨氮吸附特性的影响。结果表明:经过溶剂热法还原之后,Fe_(3)O_(4)纳米颗粒能够成功负载到生物炭上,整体形貌上保持玉米秸秆网状多孔的结构,具有良好的磁分离能力;与原生物炭相比,纳米磁性炭表面羟基数量增多,为氨氮吸附提供了更多的吸附位点;在25℃下,纳米磁性炭最高氨氮吸附量为19.2 mg/g,其吸附过程符合Freundlich吸附模型。该研究可为生物炭在氨氮废水处理方面与资源化利用提供理论基础。 展开更多
关键词 纳米磁性炭 理化结构 氨氮吸附 吸附动力学 等温吸附
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纳米零价铁磁性生物炭对水中2,4,6-三氯酚吸附机理及动力学研究 被引量:3
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作者 韦学玉 刘志刚 徐晓平 《河南城建学院学报》 CAS 2016年第5期73-77,共5页
利用黄豆壳合成纳米零价铁磁性生物炭(n ZVI-MBC)材料,运用X射线衍射(XRD)和透射电子显微镜(TEM)对其理化性质进行表征,探讨其对2,4,6-三氯苯酚(2,4,6-TCP)吸附机制,并考察溶液p H和n ZVI-MBC投加量等因素对吸附效果的影响。表... 利用黄豆壳合成纳米零价铁磁性生物炭(n ZVI-MBC)材料,运用X射线衍射(XRD)和透射电子显微镜(TEM)对其理化性质进行表征,探讨其对2,4,6-三氯苯酚(2,4,6-TCP)吸附机制,并考察溶液p H和n ZVI-MBC投加量等因素对吸附效果的影响。表征结果显示:n ZVI-MBC成功负载了α-Fe,且颗粒近似球形,呈团聚状。实验结果表明:n ZVI-MBC在p H为5~8出现阶段性吸附,吸附效果较好。n ZVI-MBC对2,4,6-TCP的吸附与二级动力学模型拟合度较好,且符合Langmuir吸附等温线方程,吸附过程主要受快速反应控制,降低反应温度有利于生物炭对水中2,4,6-TCP的吸附。 展开更多
关键词 纳米零价铁磁性生物 黄豆壳 2 4 6-三氯酚 吸附
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Effects of Enriched Biochars Containing Magnetic Iron Nanoparticles on Mycorrhizal Colonisation,Plant Growth,Nutrient Uptake and Soil Quality Improvement 被引量:8
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作者 Stephen JOSEPH Hossain M.ANAWAR +8 位作者 Paul STORER Paul BLACKWELL Chee CHIA Yun LIN Paul MUNROE Scott DONNE Josip HORVAT Jianli WANG Zakaria M.SOLAIMAN 《Pedosphere》 SCIE CAS CSCD 2015年第5期749-760,共12页
At present, there is little commercial sale of biochar, since farmers find they can not gain a return on their investment in this amendment in the first few years after its application, because of the high cost associ... At present, there is little commercial sale of biochar, since farmers find they can not gain a return on their investment in this amendment in the first few years after its application, because of the high cost associated with large application rates. To overcome this constraint, development of artificially aged enriched biochar-mineral complexes(BMCs), having a higher mineral content, surface functionality, exchangeable cations, high concentration of magnetic iron(Fe) nanoparticles, and higher water-extractable organic compounds has been undertaken by a combined team of researchers and a commercial company. Two biochars produced under different pyrolysis conditions were activated with a phosphoric acid treatment. A mixture of clay, chicken litter, and minerals were added to the biochar, and then this composite was torrefied at either 180 or 220?C. In this study a pot experiment was carried out in glasshouse conditions to determine the effects of four different BMCs, with different formulations applied at rates of 100 and 200 kg ha-1, on the mycorrhizal colonisation, wheat growth and nutrient uptake, and soil quality improvement. It was found that the phosphorus(P) and nitrogen uptake in wheat shoots were significantly greater for a low application rate of BMCs(100 kg ha-1). The present formulation of BMC was effective in enhancing growth of wheat at low application rate(100 kg ha-1). The increase in growth appeared due to an increase in P uptake in the plants that could be partly attributed to an increase in mycorrhizal colonisation and partly due to the properties of the BMC. 展开更多
关键词 biochar-mineral complexes Fe nanoparticles P uptake redox reactions
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