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不同纳米结构SiC的光催化性能研究
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作者 欧阳海波 畅丽媛 +4 位作者 李翠艳 黄剑锋 曹丽云 费杰 孔新刚 《陕西科技大学学报(自然科学版)》 2015年第4期45-50,共6页
以生物质碳为碳源,以SiO2和Si混合粉体为硅源,通过控制碳热还原合成的工艺条件分别合成了SiC微球、SiC/SiO2纳米串珠和SiC纳米线等.借助XRD、SEM及TEM等测试手段分析了三种纳米结构SiC材料的相组成及微观结构,并采用可见光催化分解亚甲... 以生物质碳为碳源,以SiO2和Si混合粉体为硅源,通过控制碳热还原合成的工艺条件分别合成了SiC微球、SiC/SiO2纳米串珠和SiC纳米线等.借助XRD、SEM及TEM等测试手段分析了三种纳米结构SiC材料的相组成及微观结构,并采用可见光催化分解亚甲基蓝溶液评估了三种纳米结构SiC材料的光催化性能.研究结果表明:SiC微球由SiC纳米颗粒组成、SiC/SiO2纳米串珠由SiC纳米线作为芯轴,非晶SiO2包覆在SiC纳米线外形成周期性的串珠结构;三种纳米结构SiC材料在300~800nm的可见光范围内均有较强的吸收能力.SiC/SiO2纳米串珠的表层SiO2可以有效分离光生电子-空穴,且SiO2层表面富集的羟基自由基更有利于光催化降解有机物的发生,提高了其催化效率,故SiC/SiO2纳米串珠较SiC微球和SiC纳米线具有更好的可见光催化能力. 展开更多
关键词 纳米结构sic 微观结构 光催化性能
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Microstructure and properties of alumina-silicon carbide nanocomposites fabricated by pressureless sintering and post hot-isostatic pressing 被引量:4
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作者 Young-Keun JEONG Koichi NIIHARA 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第A01期1-6,共6页
A1203/5%SIC nanocomposites were fabricated by pressureless sintering using MgO as a sintering aid and then post hot-isostatic pressed (HIP), which can subsequently break through the disadvantage of hot-pressing proc... A1203/5%SIC nanocomposites were fabricated by pressureless sintering using MgO as a sintering aid and then post hot-isostatic pressed (HIP), which can subsequently break through the disadvantage of hot-pressing process. The MgO additive was able to promote the densification of the composites, but could not induce the grain growth of A1203 matrix due to the grain growth inhibition by nano-sized SiC particles. After HIP treatment, A12OJSiC nanocomposites achieved full densification and homogeneous distribution of nano-sized SiC particles. Moreover, the fracture morphology of HIP treated specimens was identical with that of the hot-pressed A1203/SiC nanocomposites showing complete transgranular fracture. Consequently, high fracture strength of 1 GPa was achieved for the A1203/5%SIC nanocomposites by pressureless sintering and post HIP process. 展开更多
关键词 NANOCOMPOSITE pressureless sintering fracture strength
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