TC6 titanium alloy samples are processed by laser shock peening （LSP）. Then, some samples are vacu- um annealed at 623 K for 10 h for the study on the thermost.ablity of the nanostructure produced by LSP. The charac...TC6 titanium alloy samples are processed by laser shock peening （LSP）. Then, some samples are vacu- um annealed at 623 K for 10 h for the study on the thermost.ablity of the nanostructure produced by LSP. The characteristics of the strengthened layer and nanostructure are studied by atomic force microscopy（AFM）, scan- ning electron microscope （SEM）, electron backscatter diffraction（EBSD）, X-ray diffraction（XRD）, and transmis- sion electron microscopy（TEM） appliances, meanwhile the enhanced microhardness is tested at cross section. AFM of the processed surface indicates that the deformation is approximately uniform, and LSP slightly increases the roughness. SEM and EBSD of the strengthened cross section show that a phases are compressed to strip- shaped, a proportion of a and ~ phases is shattered to smaller phases from surface to 200 ttm in depth. The sur- face XRD shows that although there is no new produced phase during LSP, the grain size refinement and the in- troduction of lattice micro-strains lead to the broadened peak. The TEM photographs and diffraction patterns in- dicate that the shock wave provides high strain rate deformation and leads to the formation of nanocrystal. Com- pared with the samples before annealing, the dislocation density is lower and the grain-boundary is more distinct in the annealed samples, but the nanocrystal size does not grow bigger after annealing. The microhardness measurement indicates that LSP improves the microhardness of TC6 for about 12.2% on the surface, and the layer affected by LSP is about 500/~m in depth. The microhardness after annealing is 10 HVo.5 lower, but the affected depth does not change. The thermostable study shows that the strengthened layer of TC6 processed by LSP is stable at 623 K. The strengthened thermostable layer can significantly improve the fatigue resistance, wear resis- tance and stress corrosion resistance of the titanium alloy. The study results break the USA standard AMS2546 that titanium parts after LSP are subjected in subsequent processing within 589 K.展开更多
Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe...Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe alloy in physiological environment. The surface nanostructure was characterized by TEM, and the electrochemical behaviors of the samples with nanocrystalline layer and coarse grain were comparatively investigated in 0.9% NaCl and 0.2% NaF solutions, respectively. The results indicate that nanocrystallines with the size of 10-30 nm are formed within the surface layer of 30 μm in depth. The nanocrystallized surface behaves higher impedance, more positive corrosion potential and lower corrosion current density in 0.9%NaCl and 0.2%NaF solutions as compared with the coarse grain surface. The improvement of the corrosion resistance is attributed to the rapid formation of stable and dense passive film on the nanocrystallized surface of TiNbZrFe alloy.展开更多
Nanoindentation and high resolution electron backscatter diffraction（EBSD） were combined to examine the elastic modulus and hardness of α and β phases,anisotropy in residual elastic stress strain fields and distri...Nanoindentation and high resolution electron backscatter diffraction（EBSD） were combined to examine the elastic modulus and hardness of α and β phases,anisotropy in residual elastic stress strain fields and distributions of geometrically necessary dislocation（GND） density around the indentations within TA15 titanium alloy.The nano-indention tests were conducted on α and β phases,respectively.The residual stress strain fields surrounding the indentation were calculated through crosscorrelation method from recorded patterns.The GND density distribution around the indentation was calculated based on the strain gradient theories to reveal the micro-mechanism of plastic deformation.The results indicate that the elastic modulus and hardness for α p hase are 129.05 GPas and 6.44 GPa,while for β phase,their values are 109.80 GPa and 4.29 GPa,respectively.The residual Mises stress distribution around the indentation is relatively heterogeneous and significantly influenced by neighboring soft β phase.The region with low residual stress around the indentation is accompanied with markedly high a type and prismatic-GND density.展开更多
Different mass fractions （0, 5%, 10%, and 15%） of the synthesized nano SiC particles reinforced Ti-6Al-4V （Ti64） alloy metal matrix composites （MMCs） were successfully fabricated by the powder metallurgy method....Different mass fractions （0, 5%, 10%, and 15%） of the synthesized nano SiC particles reinforced Ti-6Al-4V （Ti64） alloy metal matrix composites （MMCs） were successfully fabricated by the powder metallurgy method. The effects of addition of SiC particle on the mechanical properties of the composites such as hardness and compressive strength were investigated. The optimum density （93.33%） was obtained at the compaction pressure of 6.035 MPa. Scanning electron microscopic （SEM） observations of the microstructures revealed that the wettability and the bonding force were improved in Ti64 alloy/5% nano SiCp composites. The effect of nano SiCp content in Ti64 alloy/SiCp matrix composite on phase formation was investigated by X-ray diffraction. The correlation between mechanical parameter and phase formation was analyzed. The new phase of brittle interfaced reaction formed in the 10% and 15% SiCp composite specimens and resulted in no beneficial effect on the strength and hardness. The compressive strength and hardness of Ti64 alloy/5% nano SiCp MMCs showed higher values. Hence, 5% SiCp can be considered to be the optimal replacement content for the composite.展开更多
We report recent advances in the experimental and theoretical study of grain size(GS)effects on the thermal and mechanical properties of nanostructured NiTi polycrystalline shape memory alloy(SMA).It is shown that whe...We report recent advances in the experimental and theoretical study of grain size(GS)effects on the thermal and mechanical properties of nanostructured NiTi polycrystalline shape memory alloy(SMA).It is shown that when GS<60 nm,the superelastic stress-strain hysteresis loop area(H)of the polycrystal decreases rapidly with GS and tends to vanish as GS approaches 10 nanometers.At the same time,the temperature dependence of the transition stress also decreases with GS and eventually approaches zero,leading to a wide superelastic temperature window and breakdown of the Clausius-Claperyon relationship.Rate dependence of the stress-strain responses is significantly reduced and the cyclic stability of the material is improved by the nanocrystallization.It is proposed that the emergence of such significant changes in the behavior of the material with GS reduction originate from the large increase in the area-to-volume ratios of the nanometer-thick interfaces(grain boundary and Austenite-Martensite(A-M)interface)in the polycrystal.In particular,with GS reduction,interfacial energy terms will gradually become dominant over the bulk energy of the crystallite,eventually bring fundamental changes in the phase transition responses of the material.Modelling strategy leading to the establishment of quantitative relationships among GS,grain boundary,A-M interfaces and the macroscopic responses of the material are outlined.展开更多
In this paper, for improving the photocatalytic efficiency of titania(TiO2) nanoparticles(NPs), Ag Au alloy-TiO2 core-shell NPs are fabricated via a sol-gel(SG) process in the presence of Ag Au alloy NPs with block co...In this paper, for improving the photocatalytic efficiency of titania(TiO2) nanoparticles(NPs), Ag Au alloy-TiO2 core-shell NPs are fabricated via a sol-gel(SG) process in the presence of Ag Au alloy NPs with block copolymer shells as templates. The photocatalytic activities of the Ag Au-TiO2 NPs on the photodecomposition of methylene blue(MB) are investigated. The Ag Au-TiO2 composite NPs coated with 5.0% titania related to block copolymers show higher photocatalytic activity than the other samples in which the titania contents are larger than 5.0%. The results indicate that the increase of the thickness of the TiO2 shell leads to the decrease of the photocatalytic activity.展开更多
基金the National Natural Science Foundation of China,No.81671811the National Natural Science Foundation of China(Youth Foundation),No.81501857(to ZHZ)+2 种基金Liaoning Provincial Reform Project for Key Clinical Diagnosis and Treatment,No.LNCCC-A03-2014the Natural Science Foundation of Liaoning Province,No.LK201642Special Science and Technology Research Project for Population and Health in Shenyang,No.F15-139-9-23~~
文摘TC6 titanium alloy samples are processed by laser shock peening （LSP）. Then, some samples are vacu- um annealed at 623 K for 10 h for the study on the thermost.ablity of the nanostructure produced by LSP. The characteristics of the strengthened layer and nanostructure are studied by atomic force microscopy（AFM）, scan- ning electron microscope （SEM）, electron backscatter diffraction（EBSD）, X-ray diffraction（XRD）, and transmis- sion electron microscopy（TEM） appliances, meanwhile the enhanced microhardness is tested at cross section. AFM of the processed surface indicates that the deformation is approximately uniform, and LSP slightly increases the roughness. SEM and EBSD of the strengthened cross section show that a phases are compressed to strip- shaped, a proportion of a and ~ phases is shattered to smaller phases from surface to 200 ttm in depth. The sur- face XRD shows that although there is no new produced phase during LSP, the grain size refinement and the in- troduction of lattice micro-strains lead to the broadened peak. The TEM photographs and diffraction patterns in- dicate that the shock wave provides high strain rate deformation and leads to the formation of nanocrystal. Com- pared with the samples before annealing, the dislocation density is lower and the grain-boundary is more distinct in the annealed samples, but the nanocrystal size does not grow bigger after annealing. The microhardness measurement indicates that LSP improves the microhardness of TC6 for about 12.2% on the surface, and the layer affected by LSP is about 500/~m in depth. The microhardness after annealing is 10 HVo.5 lower, but the affected depth does not change. The thermostable study shows that the strengthened layer of TC6 processed by LSP is stable at 623 K. The strengthened thermostable layer can significantly improve the fatigue resistance, wear resis- tance and stress corrosion resistance of the titanium alloy. The study results break the USA standard AMS2546 that titanium parts after LSP are subjected in subsequent processing within 589 K.
基金Projects(N100702001,N120310001)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(20131036)supported by Doctoral Fund of Liaoning Province,ChinaProject(51301037)supported by the National Natural Science Foundation of China
文摘Surface mechanical attrition treatment (SMAT) was performed on biomedicalβ-type TiNbZrFe alloy for 60 min at room temperature to study the effect of surface nanocrystallization on the corrosion resistance of TiNbZrFe alloy in physiological environment. The surface nanostructure was characterized by TEM, and the electrochemical behaviors of the samples with nanocrystalline layer and coarse grain were comparatively investigated in 0.9% NaCl and 0.2% NaF solutions, respectively. The results indicate that nanocrystallines with the size of 10-30 nm are formed within the surface layer of 30 μm in depth. The nanocrystallized surface behaves higher impedance, more positive corrosion potential and lower corrosion current density in 0.9%NaCl and 0.2%NaF solutions as compared with the coarse grain surface. The improvement of the corrosion resistance is attributed to the rapid formation of stable and dense passive film on the nanocrystallized surface of TiNbZrFe alloy.
文摘Nanoindentation and high resolution electron backscatter diffraction（EBSD） were combined to examine the elastic modulus and hardness of α and β phases,anisotropy in residual elastic stress strain fields and distributions of geometrically necessary dislocation（GND） density around the indentations within TA15 titanium alloy.The nano-indention tests were conducted on α and β phases,respectively.The residual stress strain fields surrounding the indentation were calculated through crosscorrelation method from recorded patterns.The GND density distribution around the indentation was calculated based on the strain gradient theories to reveal the micro-mechanism of plastic deformation.The results indicate that the elastic modulus and hardness for α p hase are 129.05 GPas and 6.44 GPa,while for β phase,their values are 109.80 GPa and 4.29 GPa,respectively.The residual Mises stress distribution around the indentation is relatively heterogeneous and significantly influenced by neighboring soft β phase.The region with low residual stress around the indentation is accompanied with markedly high a type and prismatic-GND density.
基金CISL,Department of Physics,Annamalai University for the support in using AFM and SEM for experimentation
文摘Different mass fractions （0, 5%, 10%, and 15%） of the synthesized nano SiC particles reinforced Ti-6Al-4V （Ti64） alloy metal matrix composites （MMCs） were successfully fabricated by the powder metallurgy method. The effects of addition of SiC particle on the mechanical properties of the composites such as hardness and compressive strength were investigated. The optimum density （93.33%） was obtained at the compaction pressure of 6.035 MPa. Scanning electron microscopic （SEM） observations of the microstructures revealed that the wettability and the bonding force were improved in Ti64 alloy/5% nano SiCp composites. The effect of nano SiCp content in Ti64 alloy/SiCp matrix composite on phase formation was investigated by X-ray diffraction. The correlation between mechanical parameter and phase formation was analyzed. The new phase of brittle interfaced reaction formed in the 10% and 15% SiCp composite specimens and resulted in no beneficial effect on the strength and hardness. The compressive strength and hardness of Ti64 alloy/5% nano SiCp MMCs showed higher values. Hence, 5% SiCp can be considered to be the optimal replacement content for the composite.
基金supported by the Hong Kong Research Grant Council(RGC)(Grant No.619113)the National Natural Science Foundation of China(Grant No.11128204)the State Key Lab of Water Resources and Hydropower Engineering of WHU,China
文摘We report recent advances in the experimental and theoretical study of grain size(GS)effects on the thermal and mechanical properties of nanostructured NiTi polycrystalline shape memory alloy(SMA).It is shown that when GS<60 nm,the superelastic stress-strain hysteresis loop area(H)of the polycrystal decreases rapidly with GS and tends to vanish as GS approaches 10 nanometers.At the same time,the temperature dependence of the transition stress also decreases with GS and eventually approaches zero,leading to a wide superelastic temperature window and breakdown of the Clausius-Claperyon relationship.Rate dependence of the stress-strain responses is significantly reduced and the cyclic stability of the material is improved by the nanocrystallization.It is proposed that the emergence of such significant changes in the behavior of the material with GS reduction originate from the large increase in the area-to-volume ratios of the nanometer-thick interfaces(grain boundary and Austenite-Martensite(A-M)interface)in the polycrystal.In particular,with GS reduction,interfacial energy terms will gradually become dominant over the bulk energy of the crystallite,eventually bring fundamental changes in the phase transition responses of the material.Modelling strategy leading to the establishment of quantitative relationships among GS,grain boundary,A-M interfaces and the macroscopic responses of the material are outlined.
基金supported by the National Natural Science Foundation of China(Nos.51173069 and 51473068)
文摘In this paper, for improving the photocatalytic efficiency of titania(TiO2) nanoparticles(NPs), Ag Au alloy-TiO2 core-shell NPs are fabricated via a sol-gel(SG) process in the presence of Ag Au alloy NPs with block copolymer shells as templates. The photocatalytic activities of the Ag Au-TiO2 NPs on the photodecomposition of methylene blue(MB) are investigated. The Ag Au-TiO2 composite NPs coated with 5.0% titania related to block copolymers show higher photocatalytic activity than the other samples in which the titania contents are larger than 5.0%. The results indicate that the increase of the thickness of the TiO2 shell leads to the decrease of the photocatalytic activity.
