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高温气相反应合成金红石型纳米TiO_2颗粒的研究 被引量:12
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作者 施利毅 李春忠 +3 位作者 古宏晨 房鼎业 朱以华 陈爱平 《金属学报》 SCIE EI CAS CSCD 北大核心 2000年第3期295-299,共5页
在高温气相反应器中,利用掺 AlCl3的 TiCl4氧化反应制备金红石型纳米 TiO2颗粒研究了氧气预热温度、反应器尾部氮气流量、反应温度、停留时间等对 TiO2颗粒大小的影响结果表明:提高氧气预热温度和加大反应器尾部氮... 在高温气相反应器中,利用掺 AlCl3的 TiCl4氧化反应制备金红石型纳米 TiO2颗粒研究了氧气预热温度、反应器尾部氮气流量、反应温度、停留时间等对 TiO2颗粒大小的影响结果表明:提高氧气预热温度和加大反应器尾部氮气流量对控制产物粒径有利, TiO2粒径随反应温度升高和停留时间延长而增大当反应温度为1373K, AICl3与TiCl4摩尔比为 0.25、停留时间为1.73s时,纯金红石相纳米TiO2颗粒的粒径分布为 30-50nm. 展开更多
关键词 纳米颗业 二氧化钛 气相氧化 钛白粉
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Review on the nanoparticle fluidization science and technology 被引量:12
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作者 Xiaolin Zhu Qiang Zhang +1 位作者 Yao Wang Fei Wei 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2016年第1期9-22,共14页
Gas fluidization has an ability to turn static particles to fluid-like dense flow, which allows greatly improved heat transfer among porous powders and highly efficient solid processing to become reality. As the risin... Gas fluidization has an ability to turn static particles to fluid-like dense flow, which allows greatly improved heat transfer among porous powders and highly efficient solid processing to become reality. As the rising star of current scientific research, some nanoparticles can also be fluidized in the form of agglomerates, with sizes ranging from tens to hundreds of microns. Herein, we have reviewed the recent progress on nanomaterial agglomeration and their fluidization behavior, the assisted techniques to enhance the fluidization of nanomaterials,including some mechanical measures, external fields and improved gas injections, as well as their effects on solid fluidization and mixing behaviors. Most of these techniques are effective in breaking large agglomerates and promoting particulate fluidization, meanwhile, the solid mixing is intensified under assisted fluidization. The applications of nanofluidization in nanostructured material production and sustainable chemical industry are further presented. In summary, the fluidization science of multidimensional, multicomponent and multifunctional particles, their multi-phase characterization, and the guideline of fluidized bed coupled process are prerequisites for the sustainable development of fluidized bed based materials, energy and chemical industry. 展开更多
关键词 Nanomaterial Nanoparticle Fluidization Agglomerate Assisted technique Solid mixing Application
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