The barium titanate nanowires of complex oxide were fabricated in porous anodic aluminum oxide(AAO)using sol-gel process.The morphology,structure and phase composition of AAO and BaTiO3 nanowires were characterized by...The barium titanate nanowires of complex oxide were fabricated in porous anodic aluminum oxide(AAO)using sol-gel process.The morphology,structure and phase composition of AAO and BaTiO3 nanowires were characterized by Scanning electron microscope(SEM),Transmission electron microscope(TEM),X-ray diffraction(XRD),and other means.Through the analysis of degradation for Rhodamine B,its photocatalytic properties could be researched,and compared with barium titanate powder,the results show that the barium titanate nanowires have good photocatalytic activity.展开更多
文摘采用静电纺丝法制备了平均直径分别为180 nm和220 nm的BaTiO3(BTO)和Ni0.4Co0.2Zn0.4Fe2O4(NCZFO)纳米纤维,使用X射线衍射(XRD)、场发射扫描电镜(FESEM)和矢量网络分析仪(VNA)对纤维的物相结构、表面形貌和微波电磁参数进行了表征,并根据传输线理论分析评估了以BTO和NCZFO纳米纤维为吸收剂的硅橡胶基单层和双层结构吸波涂层在2~18 GHz范围内的微波吸收性能。结果显示,由于BTO纳米纤维的介电损耗与NCZFO纳米纤维的磁损耗的有机结合和阻抗匹配特性的改善,以NCZFO纳米纤维/硅橡胶复合体(S1)为匹配层、BTO纳米纤维/硅橡胶复合体(S2)为吸收层的双层吸波涂层比相应单层吸波涂层表现出更为优异的吸收性能。通过调节匹配层与吸收层的厚度,在4.9~18 GHz范围内反射损耗可达–20 d B以下;当吸收层和匹配层的厚度分别为2.3 mm和0.5 mm时,最小反射损耗位于9.5 GHz达–87.8 d B,低于–20 d B的吸收带宽为5 GHz。优化设计的NCZFO/BTO纳米纤维双层吸波涂层有望发展成为一种新型的宽频带强吸收吸波材料。
文摘The barium titanate nanowires of complex oxide were fabricated in porous anodic aluminum oxide(AAO)using sol-gel process.The morphology,structure and phase composition of AAO and BaTiO3 nanowires were characterized by Scanning electron microscope(SEM),Transmission electron microscope(TEM),X-ray diffraction(XRD),and other means.Through the analysis of degradation for Rhodamine B,its photocatalytic properties could be researched,and compared with barium titanate powder,the results show that the barium titanate nanowires have good photocatalytic activity.