超新星SN1987A包层的温度演化

本文介绍了超新星ＳＮ１９８７Ａ爆发六年来关于其包层温度演化的研究情况，温度是研究超新星的各种物理过程的一个基本参量，然而目前对温度的各种估算十分弥散，结果相当不确定。本文利用辐射转移理论的逃逸几率方法，导出Ｈａ线辐射理论光变曲线，通过与观测曲线的比较，可定量地导出超新星气壳的温度演化行为。这一模型的结果与他人的结果有较好的符合。同时，我们的结果表明，在爆发５００天以后，温度反而随年龄上升，可能的解释在于随着气壳的膨胀，电子及离子的密度迅速减小，而使得复合冷速率大为减小，而加热却继续着。

Approximate Well Width and Optical Gain Formulas of 1 .555μm In_(1-x-y )Ga_y Al_x As Compressively Strained Quantum- Well Laser

Using Harrison's model and anisotropic parabolic approximation,the band structure of In1- x- y Gay Alx As compressively strained quantum wells is calculated.To design lasers with1.55μm wavelength,it is necessary to an- alyze the well width,differential gain,transparency carrier density and the characteristic gain for an arbitrary com- position.Some useful empirical formulas are also presented.

Linearity of Removal in the Proeess of Optical Element Polishing

In the light of some assumptions that are very close to the practical working conditions,a very complicated polishing process of optical element can be simplified as a linear and shift invariant system that is relatd only to the speed,pres- sure and time of processing.In polishing,the removed material can be represented and entreated by the convolution of the removal function of polishing head and the dwell function.The properties of removal function are presented.The assumptions and methods given by the author have been shown to be correct and applicable by experiments using a ring lap to polish the optical surfac.

On the Non-linear Motion of IGS Station

With the daily SINEX files of the IGS, the time series of IGS stations are obtained using an independently developed software under generalized network adjustment models with coordinate patterns. From the time series, non-linear motions are found. With spectral analysis method, the variation frequency （annual period and semi-annual period） of the site velocity is found. Moreover, the empirical model of the velocity variation of the station has been established by regression analysis method based on the weekly solution coordinate series of the station. With respect to the velocity of the IGS tracking station, it was better to model the variation periodically or to give a velocity periodically using a piece-wise linear function rather than a linear variable to estimate its bias.

Novel measurement scheme of peak separation of side-hole fiber grating

There are two peaks of different polarizations in the reflection spectrum of the side-hole fiber grating and their separation interval has a linear variation along with the pressure changing while it is insensitive to the temperature.We have proposed a novel measurement scheme based on polarization detection.The detection of peak separation is achieved by measuring the two peaks’ center wavelengths separately with all polarization maintaining fiber system.The side-hole fiber grating pressure sensing within the range of 0～3.5 MPa is realized successfully with the new scheme.

Evolution of Surface Oxide Film of Typical Aluminum Alloy During Medium-Temperature Brazing Process

The evolution of the surface oxide film along the depth direction of typical aluminum alloy under mediumtemperature brazing was investigated by means of X-ray photoelectron spectroscopy(XPS). For the alloy with Mg content below 2.0wt%, whether under cold rolling condition or during medium-temperature brazing process, the enrichment of Mg element on the surface was not detected and the oxide film was pure Al2O3. However, the oxide film grew obviously during medium-temperature brazing process, and the thickness was about 80 nm. For the alloy with Mg content above 2.0wt%, under cold rolling condition, the original surface oxide film was pure Al2O3. However, the Mg element was significantly enriched on the outermost surface during medium-temperature brazing process, and MgO-based oxide film mixed with small amount of MgAl2O4 was formed with a thickness of about 130 nm. The alloying elements of Mn and Si were not enriched on the surface neither under cold rolling condition nor during mediumtemperature brazing process for all the selected aluminum alloy, and the surface oxide film was similar to that of pure aluminum, which was almost entire Al2O3.

Mechanism of the genetic mutagenesis effects of far infrared ray laser

We have analyzed the order-disordering variance due to resonance effect and the nonlinear behavior of far infrared ray laser (FIRL)-biological system interaction.The analytic results show that the interaction between the living biological system and FIRL can produce resonance excitation effect,and so the original high ordered state of the system can be destroyed and thus the conformation variation in the system can be produced under further action of the laser.In addition,we have analyzed the nonlinear properties of the FIRL bio-molecule interaction and explained the mutagenesis effects of FIRL.The theoretic analysis is consistent with the results of FIRL mutagenesis breeding test.

B→ρ(ω,φ)η(′)Decays and NLO Contributions in pQCD Approach

By employing the perturbative QCD （pQCD） factorization approach, we calculate some important next- to-leading-order （NLO） contributions to the two-body charmless hadronic decays B^＋ →ρ^＋η（＇） and B^0 → ρ^0（ω, φ）η（＇）, induced by the vertex QCD corrections, the quark-loops as well as the chromo-magnetic penguins. From the numerical results and phenomenological analysis we find that （a） for B^± → ρ^±η（＇） （B^0 → ρ^0（ω, φ）η（＇）decays, the partial NLO contributions to branching ratios are small （large） in magnitude; and （b） the pQCD predictions for ACP^dir（B^± → ρ^±η（＇）） are consistent with the data, while the predicted .ACP（B^0 → ρ^0（ω）η（＇）） are generally large in magnitude and could be tested by the forthcoming LHCb experiments.

Measurement and analysis of soil nitrogen and organic matter content using near-infrared spectroscopy techniques

Near infrared reflectance （N1R） spectroscopy is as a rapid, convenient and simple nondestructive technique useful for quantifying several soil properties. This method was used to estimate nitrogen （N） and organic matter （OM） content in a soil of Zhejiang Province, Hangzhou County. A total of 125 soil samples were taken from the field. Ninety-five samples spectra were used during the calibration and cross validation stage. Thirty samples spectra were used to predict N and OM concentration. NIR spectra of these samples were correlated using partial least square regression. The regression coefficients between measured and predicted values of N and OM was 0.92 and 0.93, and SEP （standard error of prediction） were 3.28 and 0.06, respectively, which showed that NIR method had potential to accurately predict these constituents in this soil. The results showed that NIR spectroscopy could be a good tool for precision farming application.

Envelope Periodic Solutions to Bose-Einstein Condensation in Linear Magnetic Field and Time-Dependent Laser Field

In this paper, by applying the extended 3acobi elliptic function expansion method, the envelope periodic solutions and corresponding dark soliton solution, bright soliton solution to Bose-Einstein condensation in linear magnetic field and time-dependent laser field are obtained.

Characterization of Pyrolytic Lignin Extracted from Bio-oil

Bio-oil is a new liquid fuel produced by fast pyrolysis,which is a promising technology to convert bio-mass into liquid. Pyrolytic lignin extracted from bio-oil,a fine powder,contributes to the instability of bio-oil. The paper presents the structural features of three kinds of pyrolytic lignin extracted from bio-oil with different methods(WIF,HMM,and LMM) . The pyrolytic lignin samples are characterized by Fourier transform infrared spectrometer(FTIR) and X-ray photoelectron spectroscopy(XPS) . FTIR data indicate that the three pyrolytic lignin samples have similar functional groups,while the absorption intensity is different,and show characteristic vibra-tions of typical lignocellulosic material groups O H(3340-3380 cm-1) ,C H(2912-2929 cm-1) and C O(1652-1725 cm-1) . Comparison in the region(3340-3380 cm-1) indicates that WIF has more O H stretch groups than HMM and LMM. The carbon spectra are fitted to four peaks:C1,C C or C H,BE 283.5 eV;C2,C OR or C OH,BE 284.5-285.8 eV;C3,C O or HO C OR,BE 286.10-287.10 eV;C4,O C O,BE 287.5-287.7 eV. The absence of C1,C C or C H indicates the dominant polymerization structure of aro-matic carbon in pyrolytic lignin samples. For HMM and WIF,C2a and C2b can not be separated,so there is no free hydroxyl group in the samples. The oxygen peaks are also fitted to four peaks:O1,OH,BE = 530.3 eV;O2,RC O,BE 531.45-531.72 eV;O3,O C O,BE = 532.73-533.74 eV;O4,H2O,BE 535 eV. The absence of O1 and O4 indicates that little hydroxyl groups and adsorbed water are present in the samples.

OPTIMIZATION OF WDM OPTICAL PACKET SWITCHES WITH SPARSE WAVELENGTH CONVERTERS AND NON-DEGENERATE FIBER DELAY-LINES

This paper investigates the untraditional approach of contention resolution in Wavelength Division Multiplexing (WDM) Optical Packet Switching (OPS). The most striking characteristics of the developed switch architecture are: (1) Contention resolution is achieved by a combined sharing of Fiber Delay-Lines (FDLs) and Tunable Optical Wavelength Converters (TOWCs); (2) FDLs are arranged in non-degenerate form, i.e., non-uniform distribution of the delay lines; (3) TOWCs just can perform wavelength conversion in partial continuous wavelength channels, i.e., sparse wavelength conversion. The concrete configurations of FDLs and TOWCs are described and analyzed under non-bursty and bursty traffic scenarios. Simulation results demonstrate that for a prefixed packet loss probability constraint, e.g., 10-6, the developed architecture provides a different point of view in OPS design. That is, combined sharing of FDLs and TOWCs can, effectively, obtain a good tradeoff between the switch size and the cost, and TOWCs which are achieved in sparse form can also decrease the implementing complexity.

Techniques for DFB Fiber Laser Based Accelerometer

A distributed feedback fiber laser based Bragg grating vibration sensor system is proposed.Demodulated by using an unbalanced M-Z interferometer,experiment demonstrates that the system runs at a sensing sensitivity of about 257.2 rad·s2/m and a resolution of 4.2×10-5 m/s2 for monitoring acceleration.Experimental results show that the phase-shift changes with the acceleration linearly.

Preparation,Characterization of Dawson-type Heteropoly Acid Cerium（Ⅲ） Salt and Its Catalytic Performance on the Synthesis of n-Butyl Acetate

A novel cerium(Ⅲ) salt of Dawson type tungstophosphoric acid(Ce2P2W18O62·16H2O) was prepared by doping cerous nitrate in H6P2W18O62·13H2O powder and characterized by thermogravimetry and differential thermal analyses(TG/DTA),Fourier transform infrared spectroscopy(FT-IR),X-ray powder diffraction(XRD),pyridine infrared spectroscopy(Py-IR) and scanning electron microscopy(SEM).Its catalytic activity was evaluated by the probe reaction of synthesis of n-butyl acetate with acetic acid and n-butanol.The effects of various parameters such as molar ratio of n-butanol to acetic acid,reaction temperature,reaction time,and catalyst amount have been studied by single factor experiment.The results show that Ce2P2W18O62·16H2O behaved as an excellent heterogeneous catalyst in the synthesis of n-butyl acetate.The optimum synthetic conditions were determined as follows︰molar ratio of n-butanol to acetic acid at 2.0︰1.0,mass of the catalyst being 1.44% of the total reaction mixture,reaction temperature of 120 ℃ and reaction time of 150 min.Under above conditions,the conversion of acetic acid was above 97.8%.The selectivity of n-butyl acetate based on acetic acid was,in all cases,nearly 100%.The catalysts could be recycled and still exhibited high catalytic activity with 90.4% conversion after five cycles of reaction.It was found by means of TG-DTA and Py-IR that the catalyst deactivation was due to the adsorption of a complex of by-product on the active sites on catalysts surface or the catalyst loss in its separation from the products.Compared with using sulfuric acid as catalyst,the present procedure with Ce2P2W18O62·16H2O is a green productive technology due to simple process,higher yield,catalyst recycling and no corrosion for the production facilities.

Tracing overlapping biological signals in mid-infrared using colonic tissues as a model system

AIMTo understand the interference of carbohydrates absorbance in nucleic acids signals during diagnosis of malignancy using Fourier transform infrared (FTIR) spectroscopy.METHODSWe used formalin fixed paraffin embedded colonic tissues to obtain infrared (IR) spectra in the mid IR region using a bruker II IR microscope with a facility for varying the measurement area by varying the aperture available. Following this procedure we could measure different regions of the crypt circles containing different biochemicals. Crypts from 18 patients were measured. Circular crypts with a maximum diameter of 120 μm and a lumen of about 30 μm were selected for uniformity. The spectral data was analyzed using conventional and advanced computational methods.RESULTSAmong the various components that are observed to contribute to the diagnostic capabilities of FTIR, the carbohydrates and nucleic acids are prominent. However there are intrinsic difficulties in the diagnostic capabilities due to the overlap of major absorbance bands of nucleic acids, carbohydrates and phospholipids in the mid-IR region. The result demonstrates colonic tissues as a biological system suitable for studying interference of carbohydrates and nucleic acids under ex vivo conditions. Among the diagnostic parameters that are affected by the absorbance from nucleic acids is the RNA/DNA ratio, dependent on absorbance at 1121 cm-1 and 1020 cm-1 that is used to classify the normal and cancerous tissues especially during FTIR based diagnosis of colonic malignancies. The signals of the nucleic acids and the ratio (RNA/DNA) are likely increased due to disappearance of interfering components like carbohydrates and phosphates along with an increase in amount of RNA.CONCLUSIONThe present work, proposes one mechanism for the observed changes in the nucleic acid absorbance in mid-IR during disease progression (carcinogenesis).

Adsorption of cadmium ions from aqueous solutions by activated carbon with oxygen-containing functional groups

The adsorption of aqueous cadmium ions(Cd(Ⅱ)) have been investigated for modified activated carbon(AC-T)with oxygen-containing functional groups.The oxygen-containing groups of AC-T play an important role in Cd(Ⅱ) ion adsorption onto AC-T.The modified activated carbon is characterized by scanning electron microscopy,Fourier transform infrared spectroscopy(FT-IR) and X-ray photoelectron spectroscopy(XPS).The results of batch experiments indicate that the maximal adsorption could be achieved over the broad pH range of 4.5 to 6.5.Adsorption isotherms and kinetic study suggest that the sorption of Cd(Ⅱ) onto AC-T produces monolayer coverage and that adsorption is controlled by chemical adsorption.And the adsorbent has a good reusability.According to the FT-IR and XPS analyses,electrostatic attraction and cation exchange between Cd(Ⅱ) and oxygen-containing functional groups on AC-T are dominant mechanisms for Cd(Ⅱ) adsorption.

Continuous Flow Reactor for Hydroxylation of Benzene to Phenol by Hydrogen Peroxide

The direct hydroxylation of benzene to phenol catalyzed by activated carbon-supported Fe （Fe/AC） in acetonitrile using H2O2 as the oxidant was studied in a continuous flow reactor. Results showed that the continuous operation could obtain high phenol yield of 28.1%, coupled with the turnover frequency of 3 h^-1, and high selectivity of 98% under mild condition. The catalyst was characterized by N2 adsorption/desorption, Boehm titration, X-ray photoelectron spectra, and Fourier transform infrared spectroscopy. It was observed that iron may interact with the carboxyl group forming iron-carboxylate like species, which act as the active phase. The apparent activation energy obtained by fitting an Arrhenius model to the experimental data was 13.4 kJ/mol. The reaction order was calculated to be about i, 0.2 for benzene and 0.7 for H202.

Construction of a macromolecular structural model of Chinese lignite and analysis of its low-temperature oxidation behavior

The aim of this paper is to analyze the change in the active structure of lignite during the process of lowtemperature oxidation by constructing a molecular structure model for lignite. Using quantum computation combined with experimental results of proximate analysis, ultimate analysis, Fourier transform infrared spectroscopy(FTIR) and X-ray photoelectron spectroscopy(XPS), a structural model for the large molecular structure was constructed. By analyzing the bond lengths in the model molecule, the evolution law for the active structure of lignite was predicted for the process of low-temperature oxidation. In low-temperature oxidation,alkanes and hydroxyls are the primary active structures observed in lignite, though ether may also react. These active functional groups react with oxygen to release heat, thereby speeding up the reaction between coal and oxygen. Finally, the content of various functional groups in the process of lignite low-temperature oxidation was analyzed by infrared analysis, and the accuracy of the model was verified.

Synthesis of Macro-Mesostructured γ-Al_2O_3 with Large Pore Volume and High Surface Area by a Facile Secondary Reforming Method

Through improving the aging process during synthesis of the support, γ-Al2O3 with large pore volume and high surface area was synthesized by a facile secondary reforming method. The synthesis parameters, such as the reaction temperature, the first aging temperature and the second aging temperature, were investigated. The textural properties of γ-Al2O3 were characterized by means of N2 adsorption-desorption isotherms, X-ray powder diffractometry （XRD）, scanning electron microscopy （SEM）, Fourier transform infrared （FTIR） spectroscopy and thermogravimetry （TG）. The experimental results indicated that AACH and amorphous A1OOH were the precursors of alumina, which were formed via precipitation from solutions after reaction of aluminum sulphate with ammonium hydrogen carbonate. The precursor nanocrystallites grew and re-assembled during the secondary reforming process, which resulted in an increased pore size and pore volume and a decreased bulk density. The as-synthesized γ-Al2O3 materials featured meso/macroporosity, large pore volume （2.175 cm^3/g）, high surface area （237.8 m^2/g）, and low bulk density （0.284 g/mL）.

Assessment of Sericin Biosorbent for Selective Dye Removal

The silk sericin is the main residue in silk production and it is found to be a low cost and efficient bio-sorbent. In this study, sericin was characterized with various techniques including SEM （scanning electron micro- scope）, XRD, N2 physisorption, FTIR （Fourier transformed infrared spectroscopy） and XPS （X-ray photoelectron spectroscopy）. The nitrogen content of sericin was ca. 8.5 mmol.g-1 according to elemental analysis. Dye adsorption by sericin biosorbent was investigated with the acid yellow （AY）, methylene blue （MB） and copper （II） phthalocyanine-3,4＇4＂4＇＂-tetrasulfonic acid （CuPc） dyes from water. Sericin displayed large capacity for AY andCuPc adsorption with adsorption capacities of respectively 3.1 and 0.35 mmol.g-1, but it did not adsorbed methyl- ene blue dye. This selectivity is due to the basicity of amide groups in seriein biosorbents.