Nanometer materials include roughly nanoparticle,nanotube, nanowire, nanofiber, nanofilm and nanoblock, among which nanofiber is defined as material with nanometer-sized diameter and longer than 1 micron in length. Th...Nanometer materials include roughly nanoparticle,nanotube, nanowire, nanofiber, nanofilm and nanoblock, among which nanofiber is defined as material with nanometer-sized diameter and longer than 1 micron in length. The research development of polymer nanofibers, including manufacture methods and properties of some polymer nanofibers as well as their potential applications is reviewed.展开更多
The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. ...The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. Lee,F. Low, and D. Pines, Phys. Rev. B90 (1953) 297] technique to construct an effective Hamiltonian and then use a variational solution to deal with the exciton-phonon system. The interactions of exciton with the longitudinal-optical phonon and the surface-optical phonon have been taken into consideration. The numerical calculations for GaAs show that the influences of phonon modes on the exciton in a quasi-one-dimensional quantum wire are considerable and should not be neglected. Moreover the numerical results for heavy- and light-hole exciton are obtained, which show that the polaronic effects on two types of excitons are very different but both depend heavily on the sizes of the wire.展开更多
The single crystal bismuth nanowire arrays grown along [0112] with the diameter of 30 nm was synthesized in the pore of anodic aluminum oxide templates through electrodeposi- tion process. The temperature dependent el...The single crystal bismuth nanowire arrays grown along [0112] with the diameter of 30 nm was synthesized in the pore of anodic aluminum oxide templates through electrodeposi- tion process. The temperature dependent electric conductance of Bi nanowire arrays was measured from 78 K to 320 K. We found that the semimetal-to-semiconductor transition happened around 230 K for 30 nm Bi nanowires oriented along [0112] and the electric con- ductance of the nanowires had a strong temperature dependence.展开更多
The large refractive index difference between Si and SiO2 makes it possible to realize ultrasmall photonic integrated circuits. A 5×5 ultracompact arrayed waveguide grating multiplexer based on 500×250 nm Si...The large refractive index difference between Si and SiO2 makes it possible to realize ultrasmall photonic integrated circuits. A 5×5 ultracompact arrayed waveguide grating multiplexer based on 500×250 nm Si nanowire waveguides is designed and fabricated by using the technologies of E-beam writing and amorphous-Si deposition. The mea- sured channel spacing is about 1.5 nm (close to the design value) and the channel crosstalk is about –8 dB.展开更多
The unique properties of semiconductor nanowires are introduced,and recent research progresses in application,self-assembly synthesis methods and mechanisms are summarized.
We have developed a simple, productive, and ettectlve poly(cllmetnysltoxane) rranu fer method to fabricate highly conductive Pd nanowires following DNA scaffolds on various substrates, based on ethanolreduction at l...We have developed a simple, productive, and ettectlve poly(cllmetnysltoxane) rranu fer method to fabricate highly conductive Pd nanowires following DNA scaffolds on various substrates, based on ethanolreduction at low temperature. Pd nanoparticles were selectively deposited and confined onto the DNA templates on a PDMS sheet to form Pd nanowires and then the nanowires were transferred to other various substrates with a low occurrence of par asitic nanoparticles. The structure, morphology and the conductance of Pd nanowires were characterized with transmission electron microscopy, field emission scanning electron mi croscopy, and electrical transport measurement, respectively. Moreover, the growth process of the Pd nanowires was investigated by varying the incubation time and reaction temper ature. The present strategy provides a new method to fabricate extremely dense, highly conductive, and well aligned Pd nanowires on various substrates, which make it promising for building nanosensors and nanoelectronic devices.展开更多
We consider a simple approach of standard Ginzburg-Landan free-energy functional for a wire to study the properties of superconducting nanowires, and analyze the problem of quantum and thermally activated phase slips....We consider a simple approach of standard Ginzburg-Landan free-energy functional for a wire to study the properties of superconducting nanowires, and analyze the problem of quantum and thermally activated phase slips. In such systems one can consider a possibility for phase slips to be created not only due to thermal but also due to quantum fluctuations of a superconducting order parameter. We obtain some expressions of the free energy, the entropy, the specific heat and the bias current, respectively. The bias current I is a function of the temperature and the length of superconducting nanowires, and has a quantum phase slip. We obtain the stochastic dynamics of superconductiveresistive switching in hysteretic current-biased superconducting nanowires undergoing phase-slip fluctuations, and obtain the distribution of switching currents. Our results can be verified in modern experiments with superconducting nanowires.展开更多
The 2-dimensional unsteady aerodynamic forces,in the context of both a thin airfoil where theory of potential flow is always applicable and a bluff bridge-deck section where separated flow is typically induced,are inv...The 2-dimensional unsteady aerodynamic forces,in the context of both a thin airfoil where theory of potential flow is always applicable and a bluff bridge-deck section where separated flow is typically induced,are investigated from a point of view of whether or not they conform to the principle of linear superposition in situations of various structural motions and wind gusts.It is shown that some basic preconditions that lead to the linear superposability of the unsteady aerodynamic forces in cases of thin airfoil sections are no longer valid for a bluff section.Theoretical models of bridge aerodynamics such as the one related to flutter-buffeting analysis and those concerning aerodynamic admittance(AA)functions,however,necessitate implicitly this superposability.The contradiction revealed in this work may throw light on the perplexing problem of AA functions pertaining to the description of buffeting loads of bridge decks.Some existing theoretical AA models derived from flutter derivatives according to interrelations valid only for thin airfoil theories,which have been employed rather extensively in bridge aerodynamics,are demonstrated to be illogical.Finally,with full understanding of the preconditions of the applicability of linear superposability of the unsteady aerodynamic forces,suggestions in regard to experiment-based AA functions are presented.展开更多
A resistor-capacitor(RC)circuit model is proposed to study the effect of nanosecond pulsed electricfield on cells according to the structure and electrical parameters of cells.After a nanosecond step fieldhas been app...A resistor-capacitor(RC)circuit model is proposed to study the effect of nanosecond pulsed electricfield on cells according to the structure and electrical parameters of cells.After a nanosecond step fieldhas been applied,the variation of voltages across cytomembrane and mitochondria membrane both in nor-mal and in malignant cells are studied with this model.The time for selectively targeting the mitochondriamembrane and malignant cell can be evaluated much easily with curves that show the variation of voltageacross each membrane with time.Ramp field is the typical field applied in electrobiology.The voltagesacross each membrane induced by ramp field are analyzed with this model.To selectively target the mito-chondria membrane,proper range of ramp slope is needed.It is relatively difficult to decide the range ofa slope to selectively affect the malignant cell.Under some conditions,such a range even does not exist.展开更多
In this study, we combined silver nanowires with cupro fabrics using a dipping- drying method to prepare electrically conductive fabrics. The silver nanowires were first adhered to and then absorbed by microfibers to ...In this study, we combined silver nanowires with cupro fabrics using a dipping- drying method to prepare electrically conductive fabrics. The silver nanowires were first adhered to and then absorbed by microfibers to form electrically conductive fibers. They also filled the gaps and spaces between the microfibers, and were stacked or piled together to form networks with high electrical conductivity. The electrically conductive fabric had low resistance and good stretchability, e.g., 0.0047-0.0091 Ωin the strain range of 0-190%. They also exhibited stable electrical conductivity, as well as excellent flexibility, which remained even when the fabric was stretched, shrunk, or bent. The results show that the electrically conductive fabric can be used as a smart textile, especially in fields associated with weaving, clothing, food products, lifestyle products, medicine, biology, electronics, aviation, and military equipment and accessories.展开更多
Gated transport measurements are the backbone of electrical characterization of nanoscale electronic devices. Scanning gate microscopy (SGM) is one such gating technique that adds crucial spatial information, access...Gated transport measurements are the backbone of electrical characterization of nanoscale electronic devices. Scanning gate microscopy (SGM) is one such gating technique that adds crucial spatial information, accessing the localized properties of semiconductor devices. Nanowires represent a central device concept due to the potential to combine very different materials. However, SGM on semiconductor nanowires has been limited to a resolution in the 50-100 nm range. Here, we present a study by SGM of newly developed III-V semiconductor nanowire InAs/GaSb heterojunction Esaki tunnel diode devices under ultra-high vacuum. Sub-5 nm resolution is demonstrated at room temperature via use of quartz resonator atomic force microscopy sensors, with the capability to resolve InAs nanowire facets, the InAs/GaSb tunnel diode transition and nanoscale defects on the device. We demonstrate that such measurements can rapidly give important insight into the device properties via use of a simplified physical model, without the requirement for extensive calculation of the electrostatics of the system. Interestingly, by precise spatial correlation of the device electrical transport properties and surface structure we show the position and existence of a very abrupt (〈10 nm) electrical transition across the InAs/GaSb junction despite the change in material composition occurring only over 30-50 nm. The direct and simultaneous link between nanostructure composition and electrical properties helps set important limits for the precision in structural control needed to achieve desired device performance.展开更多
A Cu nanowire (NW)/cuprous oxide (Cu2O)-based semiconductor-liquid junction solar cell with a greatly enhanced efficiency and reduced cost was assembled. The Cu NWs function as a transparent electrode as well as p...A Cu nanowire (NW)/cuprous oxide (Cu2O)-based semiconductor-liquid junction solar cell with a greatly enhanced efficiency and reduced cost was assembled. The Cu NWs function as a transparent electrode as well as part of the Cu NWs/ Cu2O coaxial structures, which remarkably benefit the charge separation. The best solar cell reached a conversion efficiency as high as 1.92% under a simulated AM1.5G illumination, which is 106 times higher than that of cells based on fluorine-doped tin oxide and Cu2O.展开更多
A wavelength splitter with ultra-compact and simple structure is proposed and analyzed by using both plane wave expansion (PWE) method and finite difference time domain (FDTD) method. The device is based on direct...A wavelength splitter with ultra-compact and simple structure is proposed and analyzed by using both plane wave expansion (PWE) method and finite difference time domain (FDTD) method. The device is based on directional coupling between two parallel lithium niobate (LiNbO3, LN) nanowire optical waveguides. The wavelength splitter with a coupling region length of 5 um can separate 1.3 um and 1.55 um wavelengths for corresponding outputs with transmittance higher than 97%.展开更多
Integration of molybdenum disulfide (MoS2) onto high surface area photocathod is highly desired to minimize the overpotential for the solar-powered hydrogen evolution reaction (HER). Semiconductor nanowires (NWs...Integration of molybdenum disulfide (MoS2) onto high surface area photocathod is highly desired to minimize the overpotential for the solar-powered hydrogen evolution reaction (HER). Semiconductor nanowires (NWs) are beneficial use in photoelectrochemistry because of their large electrochemically availab surface area and inherent ability to decouple light absorption and the transpo of minority carriers. Here, silicon (Si) NW arrays were employed as a mod photocathode system for MoS2 wrapping, and their solar-driven HER activil was evaluated. The photocathode is made up of a well-defined MoSJTiO2/Si coaxial NW heterostructure, which yielded photocurrent density up to 15 mA/cm2 (at 0 V vs. the reversible hydrogen electrode (RHE)) with goo stability under the operating conditions employed. This work reveals the earth-abundant electrocatalysts coupled with high surface area NW electrod~ can provide performance comparable to noble metal catalysts for photocathod hydrogen evolution.展开更多
Semiconductor nanowires (NW) possess several beneficial properties for efficient conversion of solar energy into electricity and chemical energy. Due to their efficient absorption of light, short distances for minor...Semiconductor nanowires (NW) possess several beneficial properties for efficient conversion of solar energy into electricity and chemical energy. Due to their efficient absorption of light, short distances for minority carriers to travel, high surface-to-volume ratios, and the availability of scalable synthesis methods, they provide a pathway to address the low cost-to-power requirements for widescale adaptation of solar energy conversion technologies. Here we highlight recent progress in our group towards implementation of NW components as photovoltaic and photoelectrochemical energy conversion devices. An emphasis is placed on the unique properties of these one-dimensional (1D) structures, which enable the use of abundant, low-cost materials and improved energy conversion efficiency compared to bulk devices.展开更多
文摘Nanometer materials include roughly nanoparticle,nanotube, nanowire, nanofiber, nanofilm and nanoblock, among which nanofiber is defined as material with nanometer-sized diameter and longer than 1 micron in length. The research development of polymer nanofibers, including manufacture methods and properties of some polymer nanofibers as well as their potential applications is reviewed.
文摘The effects of exciton-optical phonon interaction on the binding energy and the total and reduced effective masses of an exciton in a cylindrical quantum wire have been investigated. We adopt a perturbative-PLL [T.D. Lee,F. Low, and D. Pines, Phys. Rev. B90 (1953) 297] technique to construct an effective Hamiltonian and then use a variational solution to deal with the exciton-phonon system. The interactions of exciton with the longitudinal-optical phonon and the surface-optical phonon have been taken into consideration. The numerical calculations for GaAs show that the influences of phonon modes on the exciton in a quasi-one-dimensional quantum wire are considerable and should not be neglected. Moreover the numerical results for heavy- and light-hole exciton are obtained, which show that the polaronic effects on two types of excitons are very different but both depend heavily on the sizes of the wire.
文摘The single crystal bismuth nanowire arrays grown along [0112] with the diameter of 30 nm was synthesized in the pore of anodic aluminum oxide templates through electrodeposi- tion process. The temperature dependent electric conductance of Bi nanowire arrays was measured from 78 K to 320 K. We found that the semimetal-to-semiconductor transition happened around 230 K for 30 nm Bi nanowires oriented along [0112] and the electric con- ductance of the nanowires had a strong temperature dependence.
文摘The large refractive index difference between Si and SiO2 makes it possible to realize ultrasmall photonic integrated circuits. A 5×5 ultracompact arrayed waveguide grating multiplexer based on 500×250 nm Si nanowire waveguides is designed and fabricated by using the technologies of E-beam writing and amorphous-Si deposition. The mea- sured channel spacing is about 1.5 nm (close to the design value) and the channel crosstalk is about –8 dB.
文摘The unique properties of semiconductor nanowires are introduced,and recent research progresses in application,self-assembly synthesis methods and mechanisms are summarized.
文摘We have developed a simple, productive, and ettectlve poly(cllmetnysltoxane) rranu fer method to fabricate highly conductive Pd nanowires following DNA scaffolds on various substrates, based on ethanolreduction at low temperature. Pd nanoparticles were selectively deposited and confined onto the DNA templates on a PDMS sheet to form Pd nanowires and then the nanowires were transferred to other various substrates with a low occurrence of par asitic nanoparticles. The structure, morphology and the conductance of Pd nanowires were characterized with transmission electron microscopy, field emission scanning electron mi croscopy, and electrical transport measurement, respectively. Moreover, the growth process of the Pd nanowires was investigated by varying the incubation time and reaction temper ature. The present strategy provides a new method to fabricate extremely dense, highly conductive, and well aligned Pd nanowires on various substrates, which make it promising for building nanosensors and nanoelectronic devices.
基金Supported by the National Natural Science Foundation of China under Grant No. 10974167
文摘We consider a simple approach of standard Ginzburg-Landan free-energy functional for a wire to study the properties of superconducting nanowires, and analyze the problem of quantum and thermally activated phase slips. In such systems one can consider a possibility for phase slips to be created not only due to thermal but also due to quantum fluctuations of a superconducting order parameter. We obtain some expressions of the free energy, the entropy, the specific heat and the bias current, respectively. The bias current I is a function of the temperature and the length of superconducting nanowires, and has a quantum phase slip. We obtain the stochastic dynamics of superconductiveresistive switching in hysteretic current-biased superconducting nanowires undergoing phase-slip fluctuations, and obtain the distribution of switching currents. Our results can be verified in modern experiments with superconducting nanowires.
基金Projects(51178182,90915002)supported by the National Natural Science Foundation of ChinaProject(SLDRCE10-MB-03)supported by the Open Project of the State Key Laboratory of Disaster Reduction in Civil Engineering,China
文摘The 2-dimensional unsteady aerodynamic forces,in the context of both a thin airfoil where theory of potential flow is always applicable and a bluff bridge-deck section where separated flow is typically induced,are investigated from a point of view of whether or not they conform to the principle of linear superposition in situations of various structural motions and wind gusts.It is shown that some basic preconditions that lead to the linear superposability of the unsteady aerodynamic forces in cases of thin airfoil sections are no longer valid for a bluff section.Theoretical models of bridge aerodynamics such as the one related to flutter-buffeting analysis and those concerning aerodynamic admittance(AA)functions,however,necessitate implicitly this superposability.The contradiction revealed in this work may throw light on the perplexing problem of AA functions pertaining to the description of buffeting loads of bridge decks.Some existing theoretical AA models derived from flutter derivatives according to interrelations valid only for thin airfoil theories,which have been employed rather extensively in bridge aerodynamics,are demonstrated to be illogical.Finally,with full understanding of the preconditions of the applicability of linear superposability of the unsteady aerodynamic forces,suggestions in regard to experiment-based AA functions are presented.
基金Supported by National Natural Science Foundation of China (50477007)
文摘A resistor-capacitor(RC)circuit model is proposed to study the effect of nanosecond pulsed electricfield on cells according to the structure and electrical parameters of cells.After a nanosecond step fieldhas been applied,the variation of voltages across cytomembrane and mitochondria membrane both in nor-mal and in malignant cells are studied with this model.The time for selectively targeting the mitochondriamembrane and malignant cell can be evaluated much easily with curves that show the variation of voltageacross each membrane with time.Ramp field is the typical field applied in electrobiology.The voltagesacross each membrane induced by ramp field are analyzed with this model.To selectively target the mito-chondria membrane,proper range of ramp slope is needed.It is relatively difficult to decide the range ofa slope to selectively affect the malignant cell.Under some conditions,such a range even does not exist.
文摘In this study, we combined silver nanowires with cupro fabrics using a dipping- drying method to prepare electrically conductive fabrics. The silver nanowires were first adhered to and then absorbed by microfibers to form electrically conductive fibers. They also filled the gaps and spaces between the microfibers, and were stacked or piled together to form networks with high electrical conductivity. The electrically conductive fabric had low resistance and good stretchability, e.g., 0.0047-0.0091 Ωin the strain range of 0-190%. They also exhibited stable electrical conductivity, as well as excellent flexibility, which remained even when the fabric was stretched, shrunk, or bent. The results show that the electrically conductive fabric can be used as a smart textile, especially in fields associated with weaving, clothing, food products, lifestyle products, medicine, biology, electronics, aviation, and military equipment and accessories.
文摘Gated transport measurements are the backbone of electrical characterization of nanoscale electronic devices. Scanning gate microscopy (SGM) is one such gating technique that adds crucial spatial information, accessing the localized properties of semiconductor devices. Nanowires represent a central device concept due to the potential to combine very different materials. However, SGM on semiconductor nanowires has been limited to a resolution in the 50-100 nm range. Here, we present a study by SGM of newly developed III-V semiconductor nanowire InAs/GaSb heterojunction Esaki tunnel diode devices under ultra-high vacuum. Sub-5 nm resolution is demonstrated at room temperature via use of quartz resonator atomic force microscopy sensors, with the capability to resolve InAs nanowire facets, the InAs/GaSb tunnel diode transition and nanoscale defects on the device. We demonstrate that such measurements can rapidly give important insight into the device properties via use of a simplified physical model, without the requirement for extensive calculation of the electrostatics of the system. Interestingly, by precise spatial correlation of the device electrical transport properties and surface structure we show the position and existence of a very abrupt (〈10 nm) electrical transition across the InAs/GaSb junction despite the change in material composition occurring only over 30-50 nm. The direct and simultaneous link between nanostructure composition and electrical properties helps set important limits for the precision in structural control needed to achieve desired device performance.
基金Acknowledgements This work was financially supported by the National Basic Research Program of China (No. 2012CB932303), the National Natural Science Foundation of China (No. 61301036), Shanghai Municipal Natural Science Foundation (Nos. 13ZR1463600 and 13XD1403900) and the Innovation Project of Shanghai Institute of Ceramics.
文摘A Cu nanowire (NW)/cuprous oxide (Cu2O)-based semiconductor-liquid junction solar cell with a greatly enhanced efficiency and reduced cost was assembled. The Cu NWs function as a transparent electrode as well as part of the Cu NWs/ Cu2O coaxial structures, which remarkably benefit the charge separation. The best solar cell reached a conversion efficiency as high as 1.92% under a simulated AM1.5G illumination, which is 106 times higher than that of cells based on fluorine-doped tin oxide and Cu2O.
基金supported by the National Natural Science Foundation of China(No.61040064)
文摘A wavelength splitter with ultra-compact and simple structure is proposed and analyzed by using both plane wave expansion (PWE) method and finite difference time domain (FDTD) method. The device is based on directional coupling between two parallel lithium niobate (LiNbO3, LN) nanowire optical waveguides. The wavelength splitter with a coupling region length of 5 um can separate 1.3 um and 1.55 um wavelengths for corresponding outputs with transmittance higher than 97%.
文摘Integration of molybdenum disulfide (MoS2) onto high surface area photocathod is highly desired to minimize the overpotential for the solar-powered hydrogen evolution reaction (HER). Semiconductor nanowires (NWs) are beneficial use in photoelectrochemistry because of their large electrochemically availab surface area and inherent ability to decouple light absorption and the transpo of minority carriers. Here, silicon (Si) NW arrays were employed as a mod photocathode system for MoS2 wrapping, and their solar-driven HER activil was evaluated. The photocathode is made up of a well-defined MoSJTiO2/Si coaxial NW heterostructure, which yielded photocurrent density up to 15 mA/cm2 (at 0 V vs. the reversible hydrogen electrode (RHE)) with goo stability under the operating conditions employed. This work reveals the earth-abundant electrocatalysts coupled with high surface area NW electrod~ can provide performance comparable to noble metal catalysts for photocathod hydrogen evolution.
文摘Semiconductor nanowires (NW) possess several beneficial properties for efficient conversion of solar energy into electricity and chemical energy. Due to their efficient absorption of light, short distances for minority carriers to travel, high surface-to-volume ratios, and the availability of scalable synthesis methods, they provide a pathway to address the low cost-to-power requirements for widescale adaptation of solar energy conversion technologies. Here we highlight recent progress in our group towards implementation of NW components as photovoltaic and photoelectrochemical energy conversion devices. An emphasis is placed on the unique properties of these one-dimensional (1D) structures, which enable the use of abundant, low-cost materials and improved energy conversion efficiency compared to bulk devices.