The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conj...The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.展开更多
A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of sim...A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of simulation, which include substructure model, beam element model and solid element model. The comparison results show that the substructure model has a satisfying capability, calculation efficiency and accuracy to predict the concerned joints as well as the overall framework. Based on the substructure model and a kind of semi-rigid connection for concretefilled square hollow section steel column proposed in this paper, the nonlinear dynamic analyses are conducted by the alternate path method. It is found that the removal of the ground inner column brings high-level joint moments and comparatively low-level axial tension forces. The initial stiffness and transmitted ultimate moment of the semi-rigid connection are the main factors that influence the frame behavior, and their lower limit should be guaranteed to resist collapse. Reduced ultimate moment results in drastic displacement and axial force development, which may bring progressive collapse. The higher initial stiffness ensures that the structure has a stronger capacity to resist progressive collapse.展开更多
Often many variables have to be analyzed for their importance in terms of significant contribution and predictability in medical research. One of the possible analytical tools may be the Multiple Linear Regression Ana...Often many variables have to be analyzed for their importance in terms of significant contribution and predictability in medical research. One of the possible analytical tools may be the Multiple Linear Regression Analysis. However, research papers usually report both univariate and multivariate regression analyses of the data. The biostatistician sometimes faces practical difficulties while selecting the independent variables for logical inclusion in the multivariate analysis. The selection criteria for inclusion of a variable in the multivariate regression is that the variable at the univariate level should have a regression coefficient with p 〈 0.20. However, there is a chance that an independent variable with p 〉 0.20 at univariate regression may become significant in the multivariate regression analysis and vice versa, provided the above criteria is not strictly adhered to. We undertook both univariate and multivariate linear regression analyses on data from two multi-centric clinical trials. We recommend that there is no need to restrict the p value of 〈= 0.20. Because of high speed computer and availability of statistical software, the desired results could be achieved by considering all relevant independent variables in multivariate regression analysis.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China. (No.21103161. No.11274142, No.11304058, No.11274034. and No.11004080) and the China Postdoctoral Science Foundation (No.2011MS00927 and No.2013T60319).
文摘The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.
基金Supported by National Natural Science Foundation of China (No.50878066)Natural Science Foundation of Heilongjiang Province (No.ZJG0701)Heilongjiang Postdoctoral Science Foundation
文摘A 9-story concrete-filled steel tubular frame model is used to analyze the response of joints due to sudden column loss. Three different models are developed and compared to study the efficiency and feasibility of simulation, which include substructure model, beam element model and solid element model. The comparison results show that the substructure model has a satisfying capability, calculation efficiency and accuracy to predict the concerned joints as well as the overall framework. Based on the substructure model and a kind of semi-rigid connection for concretefilled square hollow section steel column proposed in this paper, the nonlinear dynamic analyses are conducted by the alternate path method. It is found that the removal of the ground inner column brings high-level joint moments and comparatively low-level axial tension forces. The initial stiffness and transmitted ultimate moment of the semi-rigid connection are the main factors that influence the frame behavior, and their lower limit should be guaranteed to resist collapse. Reduced ultimate moment results in drastic displacement and axial force development, which may bring progressive collapse. The higher initial stiffness ensures that the structure has a stronger capacity to resist progressive collapse.
文摘Often many variables have to be analyzed for their importance in terms of significant contribution and predictability in medical research. One of the possible analytical tools may be the Multiple Linear Regression Analysis. However, research papers usually report both univariate and multivariate regression analyses of the data. The biostatistician sometimes faces practical difficulties while selecting the independent variables for logical inclusion in the multivariate analysis. The selection criteria for inclusion of a variable in the multivariate regression is that the variable at the univariate level should have a regression coefficient with p 〈 0.20. However, there is a chance that an independent variable with p 〉 0.20 at univariate regression may become significant in the multivariate regression analysis and vice versa, provided the above criteria is not strictly adhered to. We undertook both univariate and multivariate linear regression analyses on data from two multi-centric clinical trials. We recommend that there is no need to restrict the p value of 〈= 0.20. Because of high speed computer and availability of statistical software, the desired results could be achieved by considering all relevant independent variables in multivariate regression analysis.