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线性反应器中[Cu(IDAc)(H_2O)_2]_∞一维纳米晶体自组装
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作者 郑雪琳 翁家宝 +2 位作者 刘成峰 孙萃玉 曹胜光 《应用化学》 CAS CSCD 北大核心 2004年第6期571-575,共5页
采用聚乙二醇 (PEG) 水体系构建一维开放的“线性反应器”。该体系中 ,由Cu(Ⅱ )和亚氨基二乙酸配体自组装合成不同尺寸 (D为 2 0~ 6 0nm ,长度为 2 0 0nm~ 2 2 μm)的一维线状纳米晶体 ,通过改变PEG和水的配比 ,可实现线状纳米晶... 采用聚乙二醇 (PEG) 水体系构建一维开放的“线性反应器”。该体系中 ,由Cu(Ⅱ )和亚氨基二乙酸配体自组装合成不同尺寸 (D为 2 0~ 6 0nm ,长度为 2 0 0nm~ 2 2 μm)的一维线状纳米晶体 ,通过改变PEG和水的配比 ,可实现线状纳米晶体尺寸的调控。该反应器中形成的纳米晶体的结构与水溶液中自组装形成的[Cu(IDAc) (H2 O) 2 ]∞ 单晶相同。X射线单晶衍射表明 ,Cu(Ⅱ )的配位环境为四方锥形 ,平面配位键上的4个配位原子分别是配体的氮原子和 2个羧基氧原子及配位水分子 ,另一配位水分子处于四方锥形的轴向配位键上。相邻的结构单元通过羧基氧原子与Cu(Ⅱ )配位相桥连 ,形成一维Z字链状结构 。 展开更多
关键词 亚氨基二乙酸 自组装 纳米晶体 线性反应器
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BACKSTEPPING-BASED ADAPTIVE CONTROL AND SYNCHRONIZATION OF CHAOTIC SYSTEMS
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作者 樊春霞 姜长生 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2003年第2期196-200,共5页
Backstepping method is applied to the problems of synchronization for chaotic systems. Synchronization controller is designed via selecting a series of Lyapunov functions on the basis of recursive idea. The method is ... Backstepping method is applied to the problems of synchronization for chaotic systems. Synchronization controller is designed via selecting a series of Lyapunov functions on the basis of recursive idea. The method is systematic and can deal with a class of chaotic system′s synchronization problems, which are important in safe communication with chaotic signal. Due to the nature of backstepping method, the designed controller possesses perfect robustness and adaptation. As an example, the controller based on backstepping method is employed to synchronize Lorenz system. The numerical simulation illustrates that the method is effective. Compared with the linear feedback synchronization controller, the control law can stabilize synchronization systems at a smaller synchronization error. Therefore the controller has a good performance. 展开更多
关键词 chaos synchronization Backstepping method adaptive control
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Development of Linearizing Feedback Control with a Variable Structure Observer for Continuous Stirred Tank Reactors 被引量:2
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作者 Bachir Daaou Abdellah Mansouri +1 位作者 Mohamed Bouhamida Mohammed Chenafa 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2012年第3期567-571,共5页
This paper deals with the design of an observer-based nonlinear control for continuous stirred tank reactors(CSTR).A variable structure observer is constructed to estimate the whole process state variables.This observ... This paper deals with the design of an observer-based nonlinear control for continuous stirred tank reactors(CSTR).A variable structure observer is constructed to estimate the whole process state variables.This observer is basically the conventional Luenberger observer with an additional switching term used to guarantee the robustness against modeling errors.The observer is coupled with a nonlinear controller,designed based on input-output linearization for controlling the reactor temperature.The asymptotical stability of the closed-loop system is shown by the Lyapunov stability theorem.Finally,computer simulations are developed for showing the performance of the proposed approach. 展开更多
关键词 variable structure observer linearizing feedback global stability continuous stirred tank reactors
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Bifurcation control and eigenstructure assignment in continuous solution polymerization of vinyl acetate 被引量:1
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作者 张楠 邱彤 陈丙珍 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第9期1523-1529,共7页
The major difficulty in achieving good performance of industrial polymerization reactors lies in the lack of understanding of their nonlinear dynamics and the lack of well-developed techniques for the control of nonli... The major difficulty in achieving good performance of industrial polymerization reactors lies in the lack of understanding of their nonlinear dynamics and the lack of well-developed techniques for the control of nonlinear processes, which are usually accompanied with bifurcation phenomenon. This work aims at investigating the nonlinear behavior of the parameterized nonlinear system of vinyl acetate polymerization and further modifying the bifurcation characteristics of this process via a washout filter-aid controller, with all the original steady state equilibria preserved. Advantages and possible extensions of the proposed methodology are discussed to provide scientific guide for further controller design and operation improvement. 展开更多
关键词 Vinyl acetate polymerization Nonlinear dynamics Bifurcation control Eigenvalue assignment Washout filters
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Reactor Network Synthesis Based on Instantaneous Objective Function Characteristic Curves 被引量:2
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作者 张治山 赵文 +2 位作者 王艳丽 周传光 袁希钢 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2003年第4期436-440,共5页
It is believed that whether the instantaneous objective function curves of plug-flow-reactor (PFR) and continuous-stirred-tank-reactor (CSTR) overlap or not, they have a consistent changing trend for complex reactions... It is believed that whether the instantaneous objective function curves of plug-flow-reactor (PFR) and continuous-stirred-tank-reactor (CSTR) overlap or not, they have a consistent changing trend for complex reactions (steady state, isothermal and constant volume). As a result of the relation of the objective functions (selectivity or yield) to the instantaneous objective functions (instantaneous selectivity or instantaneous reaction rate), the optimal reactor network configuration can be determined according to the changing trend of the instantaneous objective function curves. Further, a recent partition strategy for the reactor network synthesis based on the instantaneous objective function characteristic curves is proposed by extending the attainable region partition strategy from the concentration space to the instantaneous objective function-unreacted fraction of key reactant space. In this paper, the instantaneous objective function is closed to be the instantaneous selectivity and several samples are examined to illustrate the proposed method. The comparison with the previous work indicates it is a very convenient and practical systematic tool of the reactor network synthesis and seems also promising for overcoming the dimension limit of the attainable region partition strategy in the concentration space. 展开更多
关键词 reactor network synthesis instantaneous objective function PARTITION
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The Parameters of the Stellarator as a Neutron Source for a Subcritical Reactor
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作者 Vasiliy Rudakov 《Journal of Physical Science and Application》 2014年第2期90-99,共10页
The possibility of developing a stellarator-based neutron source designed for the nuclear reaction initiation in the blanket of hybrid reactor is studied. An analog of the Large Helical Device (LHD) stellarator desi... The possibility of developing a stellarator-based neutron source designed for the nuclear reaction initiation in the blanket of hybrid reactor is studied. An analog of the Large Helical Device (LHD) stellarator design, with linear dimensions increased by a factor of 1.5 is taken for the magnetic system. Plasma parameters and the deuterium-tritium (DT) mixture fusion power are calculated using the space-time numerical code under the assumption of the neoclassical transport in the ambipolarity regime. Using the 10 MW plasma heating sources, it is possible to obtain the DT fusion power of one-to-two tens MW. 展开更多
关键词 STELLARATOR subcritical reactor ambipolar electric field neoclassical transport neutron source fusion power
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