Hammett方程及其线性自由能变化关系的应用

从热力学角度上对Hammett方程进行了简单的讨论 ,并举例说明其在化学上的一些应用 .

Comparative analysis of coal and coal-shale intrinsic factors affecting spontaneous combustion

Coal and coal-shales tend to undergo spontaneous combustion under favourable atmospheric conditions. Spontaneous combustion liability index and intrinsic properties of coals and coal-shales varies between （above and below） coal seams. The spontaneous combustion liability index （obtained from the Wits-Ehac Index） and intrinsic properties （obtained from proximate, ultimate, and petrographic analysis） of fourteen samples representative of in situ coal （bituminous） and fourteen coal-shales obtained in Witbank coalfield, South Africa were experimentally studied. Comparative analysis of the relationships between the spontaneous combustion liability index and intrinsic properties of coals and coalshales were established to evaluate their effects on self-heating potential. The intrinsic properties show linear relationship with spontaneous combustion liability and therefore, identifies the factors affecting spontaneous combustion of these materials. The influence of coal-shales intrinsic properties towards spontaneous combustion liability shows higher correlation coefficients than the coals. Both coals and coal-shales show inertinite maceral as major constituents than the vitrinite and liptinite macerals, hence the reactivity of inertinite macerals may show greater influence on spontaneous combustion liability. A definite positive or negative trends exists between the intrinsic properties and spontaneous combustion liability index. This research is part of a larger project which is considering the influence of intrinsic properties of coals and coal-shales on spontaneous combustion liability.

Effect of Fluctuating Temperatures on Forest SoilNitrogen Mineralization

Nitrogen mineralization in forest soil was studied in laboratory by incubating undisturbed soil cores enclosed within PVC columns at different temperatures to compare the effect of fluctuating temperature with that of constant temperature, and to find out whether soil nitrification shows linearity over time. The results showed that there was no significant difference between soil nitrification at fluctuating temperature and that at constant temperature, and suggested that it must be careful to make the conclusion that soil nitrification has linearity over time.

Comparison Between Reconstructions of Global Anthropogenic Land Cover Change over Past Two Millennia

Three global datasets, the History Database of the Global Environment （HYDE）, Kaplan and Krurnhardt （KK） and Pongratz of reconstructed anthropogenic land cover change （ALCC） were introduced and compared in this paper. The HYDE dataset was recon- structed by Goldewijk and his colleagues at the National institute of Public ttealth and the Environment in Netherland, covering the past 12 000 years. The KK dataset was reconstructed by Kaplan and his colleagues, the Soil-Vegetation-Atmosphere Research Group at the Institute of Environmental Engineering in Switzerland, covering the past 8000 years. The Pongratz dataset was reconstructed by Pon- gratz and her colleagues at the Max Planck Institute for Meteorology in Germany, coveting AD 800-1992. The results show that the reconstructed datasets are quite different from each other due to the different methods used. The three datasets all allocated the historical ALCC according to human population density. The main reason causing the differences among the three datasets lies on the different relationships between population density and land use used in each reconstructed dataset. The KK dataset is better than the other two datasets for two important reasons. First, it used the nonlinear relationship between population density and land use, while the other two used the linear relationship. Second, Kaplan and his colleagues adopted the technological development and intensification parameters and considered the wood harvesting and the long-term fallow area resulted from shifting cultivation, which were neglected in the recon- structions of the other two datasets. Therefore, the KK dataset is more suitable as one of the anthropogenic forcing fields for climate simulation over the past two millennia that is recently concerned by two projects, the National Basic Research Program and the Strategic and Special Frontier Project of Science and Technology of the Chinese Academy of Sciences.

Model test of helical angle effect on coal loading performance of shear drum

The work presented in this paper focuses on improving coal loading performance of shear drum.Employing the similarity theory,we carried out a dimensional analysis of the correlation parameters which influence coal loading performance of shear drum.On the basis of similarity criterion,proportional relationship between the model and the prototype was taken on the condition of taking 1/3 as the similarity coefficient.Besides taking 1600 mm drum as the prototype,four helical angle models of shearer drums(15°,18°,21°,24°) were developed.Simultaneously,based on an established cutting test-bed,coal loading performance tests for the four drums were carried out at the same drum rotational and haulage speeds.After analyzing the data of coal-loading performance and torque,we concluded that:both the coal loading performance and torque vary along the track of the parabola with the opening side facing downwards;the best coal loading performance arises when the helical angle is at 19.3°,while the biggest torque arises at 22.1°;and the coal loading performance had nonlinear relationship with the torque.

The Project Siberian High in CMIP5 Models

The Siberian high(SH)experienced a decline from the 1970s to 1990s and a recovery in recent years.The evolution of the SH under global warming is unclear.In this study,41 Coupled Model Intercomparison Project Phase 5(CMIP5)climate models are evaluated in terms of their ability to simulate the temporal evolution of the SH in the 19th and 20th centuries and the spatial pattern of the SH during 1981–2005.The results show that 12models can capture the temporal evolution of the SH center intensity(SHCI)for 1872–2005.The linear correlation coefficient between the SHCI from the Twentieth Century Reanalysis and the simulated SHCI from the multi-model ensemble(MME)of the 12 models is 0.3 on annual and inter-annual scales(above the 99%confidence level).On decadal and multi-decadal time scales,the MME also captures the pronounced reduction(between 1981–2000and 1881–1900 period)and the recovery(during1991–2005)of the SH intensity.Finally,the future evolution of the SH is investigated using the MME of the 12models under the+4.5 and+8.5 W m-2 Representative Concentration Pathway(RCP)scenarios(RCP4.5 and RCP8.5).It is shown that the SHCI,similar to the SHCI in the 20th century,has no significant long-term trend in the 21st century under global warming(RCP8.5 scenario).At the end of 21st century(2081–2100),the SH shows stronger interannual variability than the SH at the end of20th century(1981–2000).The increased interannual variability likely favors the increased interannual variability in winter air temperature over midlatitude Eurasia at the end of 21st century.

Cr∶Nd∶GSGG晶体1.061μm受激发射截面随温度变化特性研究

测量了Cr∶Nd∶GSGG晶体从 - 70℃到 +80℃温度下的荧光发射光谱和荧光寿命 ,计算了该晶体在不同温度下 1 .0 61 μm受激发射截面 。

Tensile behaviors of filaments with misfit of chirality

Slender chiral filaments are ubiquitous in both artificial and biological materials.Due to their chiral microstructures,chiral filaments usually exhibit favorable properties such as superior elasticity and unusual stretch-twist coupling deformation.However,how these chiral microstructures affect the elastic behavior of filaments remains unclear.In this paper,a refined Cosserat rod model with misfit or mismatching of chirality induced by inhomogeneous arrangement of chiral microstructures incorporated is developed.Using the refined rod model,the force-displacement relationships and variation of structural chirality during the tensile processes of two typical helical structures,i.e.,single-strand helix and double-strand helix,are investigated.The results show that the misfit of chirality can lead to a bend-twist deformation with a high coupling degree,which makes the rod much“soft”when stretched.The chiral filaments undergo an unusual twist when stretched,corresponding to an obviously nonlinear variation of structural chirality.The work suggests that the misfit of chirality can be used to tune the elastic behavior of chiral filaments,which is helpful in guiding the design of flexible actuators and soft devices.