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线扫描微分阳极溶出伏安法测定食盐中铜铅镉 被引量:3
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作者 宋远志 谢文 刘新忠 《中国公共卫生》 CAS CSCD 北大核心 2003年第1期93-94,共2页
关键词 线扫描微分 阳极溶出伏安法 食盐卫生 微量元素
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Sedimentary characteristics and depositional model of a Paleocene-Eocene salt lake in the Jiangling Depression,China 被引量:10
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作者 余小灿 王春连 +6 位作者 刘成林 张招崇 徐海明 黄华 谢腾骁 李皓楠 刘锦磊 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2015年第6期1426-1435,共10页
We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction anal... We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction analysis.On the basis of sedimentary characteristics we have summarized the petrological and mineralogical characteristics of the salt lake and proposed 9 types of grade IV salt rhythms.The deposition shows a desalting to salting order of halite-argillaceous-mudstone-mud dolostonemud anhydrock-glauberite-halite.The relationship among grade IV rhythms,water salinity and climate fluctuations was analyzed.Based on the analysis of the relationship between boron content and mudstone color and by combining the mineralogy and sedimentary environment characteristics,we propose that the early and late Paleocene Shashi Formation in the Jiangling Depression was a paleolacustrine depositional environment with a high salt content,which is a representation of the shallow water salt lake depositional model.The middle Paleocene Shashi Formation and the early Eocene Xingouzui Formation were salt and brackish sedimentary environments with low salt content in a deep paleolake,which represents a deep salt lake depositional model. 展开更多
关键词 Paleocene-Eocene salt lake salt rhythm depositional model Jiangling Depression
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Optimization of High-Gravity Chelated Iron Process for Removing H_2S Based on Response Surface Methodology 被引量:3
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作者 Luo Ying Zhang Zhongzhe +3 位作者 Qi Jibing Li Gang Qi Guisheng Liu Youzhi 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2015年第3期87-93,共7页
By using a mixture of N2 and H2S as the simulated APG(associated petroleum gas), the desulfurization experiment was performed in a cross-flow rotating packed bed(RPB) based on the chelated iron oxidation-reduction met... By using a mixture of N2 and H2S as the simulated APG(associated petroleum gas), the desulfurization experiment was performed in a cross-flow rotating packed bed(RPB) based on the chelated iron oxidation-reduction method. In order to determine the operating conditions of the system, the effects of the concentration of Fe3+ ions(ranging from 0.1 to 0.2 mol/L), the liquid-gas volume ratio(ranging from 15 to 25 L/m3) and the high gravity factor(ranging from 36 to 126) on the removal of H2 S were studied by means of the Box-Behnken design(BBD) under response surface methodology(RSM). The overall results have demonstrated that the BBD with an experimental design can be used effectively in the optimization of the desulfurization process. The optimal conditions based on both individualized and combined responses(at a Fe3+ ion concentration of 0.16 mol/L, a liquid-gas volume ratio of 20.67 L/m3 and a high gravity factor of 87) were found. Under this optimum condition, the desulfurization efficiency could reach 98.81% when the H2 S concentration was 7 g/m3 in APG. In this work, the sulfur product was analyzed by X-ray diffraction(XRD), scanning electron microscopy(SEM) and the energy dispersive X-ray spectrometer(EDX). The results of analysis show that the sulfur is made of the high-purity orthorhombic crystals, which are advantageous to environmental conservation. 展开更多
关键词 hydrogen sulfide chelated iron high gravity technology response surface methodology Box-Behnken design
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Nanocrystalline Mg and Mg alloy powders by hydriding-dehydriding processing 被引量:4
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作者 王辛 王珩 +1 位作者 胡连喜 王尔德 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第7期1326-1330,共5页
The process of mechanically assisted hydriding and subsequent thermal dehydriding was proposed to produce nanocrystalline Mg and Mg alloy powders using pure Mg and Mg-5.5%Zn-0.6%Zr(mass fraction)(ZK60 Mg) alloy as the... The process of mechanically assisted hydriding and subsequent thermal dehydriding was proposed to produce nanocrystalline Mg and Mg alloy powders using pure Mg and Mg-5.5%Zn-0.6%Zr(mass fraction)(ZK60 Mg) alloy as the starting materal.The hydriding was achieved by room-temperature reaction milling in hydrogen.The dehydriding was carried out by vacuum annealing of the as-milled powders.The microstructure and morphology of both the as-milled and subsequently dehydrided powders were characterized by X-ray diffraction analysis(XRD) ,transmission electron microscopy(TEM) ,and scanning electron microscopy(SEM) ,respectively.The results show that,by reaction milling in hydrogen,both Mg and ZK60 Mg alloy can be fully hydrided to form nanocrystalline MgH2 with an average grain size of 10 nm.After subsequent thermal dehydriding at 300℃,the MgH2 can be turned into Mg again,and the newly formed Mg grains are nanocrystallines,with an average grain size of 25 nm. 展开更多
关键词 Mg Mg alloy HYDRIDING dehydriching hydrogen treatment NANOCRYSTALLINE
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Wear mechanism for spray deposited Al-Si/SiC_p composites under dry sliding condition 被引量:6
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作者 滕杰 李华培 陈刚 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第8期2875-2882,共8页
Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry slid... Al-Si/15%SiCp(volume fraction) composites with different silicon contents were fabricated by spray deposition technique, and typical microstructures of these composites were studied by optical microscopy(OM). Dry sliding wear tests were carried out using a block-on-ring wear machine to investigate the effect of applied load range of 10-220 N on the wear and friction behavior of these composites sliding against SAE 52100 grade bearing steel. Scanning electron microscopy(SEM) and energy-dispersive X-ray microanalysis(EDAX) were utilized to examine the morphologies of the worn surfaces in order to observe the wear characteristics and investigate the wear mechanism. The results show that the wear behavior of these composites is dependent on the silicon content in the matrix alloy and the applied load. Al-Si/15%SiCp composites with higher silicon content exhibit better wear resistance in the applied load range. Under lower loads, the major wear mechanisms are oxidation wear and abrasive wear for all tested composites. Under higher loads, severe adhesive wear becomes the main wear mechanisms for Al-7Si/15%SiCp and Al-13Si/15%SiCp composites, while Al-20Si/15%SiCp presents a compound wear mechanism, consisting of oxidation, abrasive wear and adhesion wear. 展开更多
关键词 dry sliding wear wear mechanism Al-Si/SiC_p composites spray deposition
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Meso-structure and fracture mechanism of mudstone at high temperature 被引量:3
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作者 Zhang Lianying Mao Xianbiao +2 位作者 Liu Ruixueab Li Yan Yin Huiguang 《International Journal of Mining Science and Technology》 SCIE EI 2014年第4期433-439,共7页
The meso-structure mineral composition and fracture mechanism of uniaxial compressed mudstone samples at high temperature were analyzed by XRD and scanning electron microscopy. The effect of tem- perature on mudstone ... The meso-structure mineral composition and fracture mechanism of uniaxial compressed mudstone samples at high temperature were analyzed by XRD and scanning electron microscopy. The effect of tem- perature on mudstone composition and fracture mechanism were studied from a meso-structural per- spective, and the relationship between meso-structure and macro-mechanical characteristics at high temperature was revealed. The findings demonstrated that the fluctuation in diffraction intensity of kao- linite in the mudstone caused the fluctuation in its mechanical properties. The overall structure under- went a phase change around 600℃, which led to the sudden change in the mechanical properties of mudstone samples. When the temperature reached 600 ℃, the crystalline state worsened and kaolinite disappeared; however, some illite was produced, indicating that the chemical reaction of the structure and sudden drop of bearing capacity of the mudstone. Mudst0ne fracturing at high temperature involves mainly intergranular and transgranular fractures, which are typical in micro-brittle tensile failure. Con- sidering the macro-fracture characteristics of mudstone, the results suggested that macro-fracture under external force corresoonds to the meso-fracture. 展开更多
关键词 Mudstone Mineral composition SEM Meso-fracture Macro-fracture
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Effect of precipitation on internal friction of AZ91 magnesium alloy 被引量:1
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作者 刘树伟 姜海昌 +1 位作者 李秀艳 戎利建 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第B07期453-457,共5页
The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA... The effect of precipitation on the internal friction(IF)of AZ91 magnesium alloy was investigated by using X-ray diffraction(XRD)analysis,scanning electron microscope(SEM)observation,and dynamic mechanical analysis(DMA).Six different states of alloy were prepared by applying different heat treatment processes:as-cast,in-complete solid solution,complete solid solution,micro-precipitation,continuous precipitation and continuous-discontinuous precipitation.It was found that the internal friction of in-completely solid-solutionized,completely solid-solutionized and micro-precipitated specimens showed a similar characteristic,and the grain boundary relaxation is completed depressed due to the Al atoms supersaturated in theα-Mg solution.However,a thermal relaxation internal friction peak was observed for continuously precipitated and continuously-discontinuously precipitated specimens at around 438 K and frequency of about 1 Hz,which was attributed to the grain boundaries relaxation.Furthermore,it was found that the relaxation of theβ-Mg17Al12/α-Mg phase interfaces should give its contribution to the background internal friction in the as-cast,continuously precipitated and continuously-discontinuously precipitated specimens. 展开更多
关键词 PRECIPITATION solutionization isothermal treatment AGING internal friction
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Preparation High-Temperature Behavior of Conversion Coating of Alumina Film on FeCrAI (Ce) Stainless Steel
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作者 H. Essom 《Journal of Chemistry and Chemical Engineering》 2012年第12期1083-1092,共10页
FeCrAI (Ce) stainless steel was functionalized by a conversion treatment in order to allow alumina by diffusion coatings with strong interfacial bonding. The very porous conversion coating produced in a pack alumini... FeCrAI (Ce) stainless steel was functionalized by a conversion treatment in order to allow alumina by diffusion coatings with strong interfacial bonding. The very porous conversion coating produced in a pack aluminization technique had excellent adhesion and was conductive enough to permit conditions favorable for the precipitation of alumina oxyhydroxide during aluminum diffusion coatings. In this work, the bed was prepared as a mixture of A1, NH4C1 and A1203. In the high-activity bed were heat-treated at 1,173 K in an atmosphere made up of team with subsequent air-cooling. The effect of the bed content on the coating was examined. With the high-activity, the desired Fe2Al5 was formed as the outermost coating layer. The coating presented chemical composition gradients suitable for strong adhesion. The improvement of the thermal oxidation behaviour was studied at 1,373 K. Two different aqueous environments, which are (1) NaC1 and (2) H2SO4, are employed for using the technique of potentiodynamic polarization curve. The obtained experimental electrochemical parameters (Ecorr, Jcorr etc,) were used to compare the corrosion resistance of the tested steel state complemented by MEB (electronic scanning microscopy) in combination with dispersive analysis X in energy (EDS) or X ray diffraction indicated that the elements concentration maximum was located in the vicinity of the interface especially in the FeCrAI (Ce) coated by spherical A1203 powder. These results an discussed in terms of an addition effect on the development of the microstructure of oxide films. 展开更多
关键词 COATING ALUMINA corrosion MORPHOLOGY heat treatment adhesion.
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Characteristics and genesis of clay minerals in the northern margin of the Qaidam Basin 被引量:1
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作者 Wang Linlin Jiang Bo +2 位作者 Peng Dehua Yin Chengming Zeng Chunlin 《Mining Science and Technology》 EI CAS 2011年第1期141-145,共5页
In order to develop appropriate reservoir protection measures in the northern margin of the Qaidam Basin and improve its oil and gas recovery efficiency,characteristics of clay minerals from eleven clay rock samples f... In order to develop appropriate reservoir protection measures in the northern margin of the Qaidam Basin and improve its oil and gas recovery efficiency,characteristics of clay minerals from eleven clay rock samples from the northern margin of the Qaidam Basin were investigated using X-ray diffraction analysis,the Scanning Electron Microscope(SEM)and energy spectrum analysis.Clay mineral composition and distribution characteristics of the main hydrocarbon reservoirs,i.e.,from the Jurassic and Paleogene-Neogene,were explored.We analyzed the main factors which affected these attributes.The results show that the major clay minerals in the northern margin are chlorite,kaolinite,illite,smectite and illite/smectite inter-stratified minerals.Illite is the most widely spread clay mineral in this area. Chlorite is mainly found in the entire Neogene and in shallow horizons of the Paleogene.Smectite is enriched in the shallow Paleogene-Neogene.There are large amounts of kaolinite and illite/smectite inter-stratified minerals in the Jurassic.The major factors affecting the different development of clay minerals in the region are properties of parent rocks,paleoclimate and paleowater media conditions, diagenesis transformation,tectonic and terrain conditions. 展开更多
关键词 Qaidam Basin Northern marginal area Clay mineral Distribution characteristics Genesis
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Biocidal Effect of Gamma Radiation on the Ecology of Filamentous Fungal Populations Associated with Stone Deterioration
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作者 Douglas Boniek Isolda de Castro Mendes +1 位作者 Antonio Femando Batista dos Santos Maria Aparecida de Resende Stoianoff 《Journal of Environmental Science and Engineering(A)》 2017年第5期252-259,共8页
This study focused on the identification of the filamentous fungi associated with soapstone samples exposed to outdoor conditions and the biocidal effect of gamma radiations on isolated fungal populations in Minas Ger... This study focused on the identification of the filamentous fungi associated with soapstone samples exposed to outdoor conditions and the biocidal effect of gamma radiations on isolated fungal populations in Minas Gerais State in Brazil. Two soapstone blocks were placed outdoors under tropical environmental conditions for 12 months. A total of 9 filamentous fungal populations were identified on their surfaces, namely Acremomium (cf.) alternatum, Alternaria alternata, Aspergillusfumigatus, Calcarisporium (cf.) arbuscula, Cladosporium cladosporioides, Curvularia lunata, Epicoccum nigrum, Fusarium equiseti and Penicillium citrinum. The gamma radiation assay was then carried out as a test of biocidal action by exposing all fungal populations to the ionizing radiation. The results showed that only the C. cladosporioides species was resistant to this biocidal agent, since it was able to increase its population post exposure. Scanning electron microscopy images identified the microbial colonization on the soapstone blocks and the stone elementar composition was analyzed by energy dispersive X-ray spectrometry. After treatment, there was no structural and aesthetic alteration in the soapstone samples, and evidencing that gamma radiation can be used as a biocidal agent. However, the resistance of the black fungal population indicates caution in the choice of gamma irradiation as biocidal treatment. 展开更多
关键词 Gamma radiation biocidal STONE ECOLOGY filamentous fungi.
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New High Tc-Value Investigated in Superconducting System YBa2(C u3)1-xA gxO6.5x+δ
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作者 Emad K. Al-Shakarchi Salwan K.J. Al-Ani Wedad. M. Faysal 《Journal of Physical Science and Application》 2012年第9期352-358,共7页
A ceramic superconductor compound with composition YBa2(C u3)1-xA gxO6.5x+δhas been prepared experimentally by solid state reaction from principal roots of high purity materials like Y203, BaO, CuO and Ag20. The s... A ceramic superconductor compound with composition YBa2(C u3)1-xA gxO6.5x+δhas been prepared experimentally by solid state reaction from principal roots of high purity materials like Y203, BaO, CuO and Ag20. The study was concentrated on the effect of partial substitution of Ag with respect to Cu atoms by the ratios (x = 0, 1, 0.2, 0.3, 0.4 and 0.5) through different analysis and measurements. X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Resistivity measurement is play an important role to show the improvement on high superconducting phase. It was found that the best substituted value of (x = 0.5) investigated a favor value of Tc equal nearly to (123 K), due to more excess of Ag atoms in the structure. X-ray diffraction showed an orthorhombic structure related to high-To phase with high stability through diminishing some peaks related to low temperature superconducting phase, that was related to presence of multiphase derivative from YBCO-phase. SEM pictures give us more details on the surface morphology, grain and grain boundaries, it gives an indication on successful of sintering process, the last one is very important in forming superconducting phase. 展开更多
关键词 Superconductor compound 123-compound resistivity measurements X-ray diffraction.
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Preparation and electrochemical performance of Li_2Mn_(0.5)Fe_(0.5)SiO_4 cathode material with sol-gel method for lithium ion batteries
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作者 胡传跃 郭军 +1 位作者 文瑾 彭秧锡 《Journal of Central South University》 SCIE EI CAS 2014年第4期1285-1289,共5页
Li2Fe0.5Mn0.5SiO4 material was synthesized by a citric acid-assisted sol-gel method. The influence of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+) on the electrochemical properties of Li2Fe0.5Mn0.5... Li2Fe0.5Mn0.5SiO4 material was synthesized by a citric acid-assisted sol-gel method. The influence of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+) on the electrochemical properties of Li2Fe0.5Mn0.5SiO4 was studied. The final sample was identified as Li2Fe0.5Mn0.5SiO4 with a Pmn21 monoclinic structure by X-ray diffraction analysis. The crystal phases components and crystal phase structure of the Li2Fe0.5Mn0.4SiO4 material were improved as the increase of the stoichiometric ratio value of n(citric acid) to n(Fe2+-Mn2+). Field-emission scanning electron microscopy verified that the Li2Fe0.5Mn0.5SiO4 particles are agglomerates of Li2Fe0.5Mn0.5SiO4 primary particles with a geometric mean diameter of 220 nm. The Li2Fe0.5Mn0.5SiO4 sample was used as an electrode material for rechargeable lithium ion batteries, and the electrochemical measurements were carried out at room temperature. The Li2Fe0.5Mn0.5SiO4 electrode delivered a first discharge capacity of 230.1 mAh/g at the current density of 10 mA/g in first cycle and about 162 mAh/g after 20 cycles at the current density of 20 mA/g. 展开更多
关键词 lithium ion battery Li2Fe0.5Mn0.5SiO4 citric acid assisted sol-gel method cathode
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Hydrothermal synthesis and characterization of rare-earth ruthenate pyrochlore compounds R_2Ru_2O_7(R=Pr_(3+),Sm(3+)-Ho(3+)) 被引量:4
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作者 YAO LinRan, WANG Dong, PENG Wen, HU WeiWei, YUAN HongMing & FENG ShouHua State key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry, Jilin University, Changchun 130023, China 《Science China Chemistry》 SCIE EI CAS 2011年第6期941-946,共6页
A series of pyrochlore oxides, R2Ru2O7 (R=Pr3+, Sm3+–Ho3+) were synthesized under mild hydrothermal conditions. All the samples crystallize in uniform octahedron characteristically. The products were characterized by... A series of pyrochlore oxides, R2Ru2O7 (R=Pr3+, Sm3+–Ho3+) were synthesized under mild hydrothermal conditions. All the samples crystallize in uniform octahedron characteristically. The products were characterized by powder X-ray diffraction, scanning electron microscopy, energy-disperse X-ray spectroscopy, and dc susceptibility, and the factors that affected the crystallization were discussed. It was found that the purity of products depends strongly on the raw materials and the amount of alkalinity in the initial reaction mixtures. The ZFC and FC susceptibilities of all of the compounds R2Ru2O7 at low temperature were also measured and discussed. 展开更多
关键词 hydrothermal synthesis pyrochlore compounds magnetic properties
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Magnetization of microorganism cells by thermal decomposition method 被引量:5
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作者 ZHANG DeYuan ZHANG WenQiang CAI Jun 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第5期1275-1280,共6页
The bio-limited forming technology, a new technology organically integrating microbiology, manufacturing science and materials science, is used in the manufacturing of magnetic or conductive microstructures of differe... The bio-limited forming technology, a new technology organically integrating microbiology, manufacturing science and materials science, is used in the manufacturing of magnetic or conductive microstructures of different standard shapes. This paper explores the feasibility of magnetizing microorganism with thermal decomposition method. The principle of thermal decomposition of iron pentacarbonyl has been adopted to investigate the cells of Spirulina (a type of nature micro-helical microorganism) coated with pure iron. Further analysis have been conducted on the observations results of hollow micro-helical magnetic particles form, components and the phase structure obtained by using various tools including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray detector (EDX), transmission electron microscopy (TEM), and X-ray diffraction analysis (XRD). Results showed that Spirulina cells could be coated with iron particles after the completion of thermal decomposition process, with well-kept shape of natural helixes and consistent components of different sampling points on the surface layer and thickness of layer. After the heat treatment at 700°C, the type of the surface iron layer formed was α-Fe. The paper also investigates the kinetics of the cell magnetization technology by thermal decomposition. 展开更多
关键词 BIO-MANUFACTURING bio-limited forming hollow micro-helical magnetic particles Fe(CO)5 thermal decomposition
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Research on magnetic metallization of microorganism cells using electroplating technique 被引量:3
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作者 CAI Jun ZHANG DeYuan +1 位作者 LAN MingMing LIAN ZhiYang 《Science China(Technological Sciences)》 SCIE EI CAS 2011年第6期1525-1531,共7页
Spirulina platensis were chosen as templates to produce microscopic helical soft-core magnetic particles by way of depositing ferromagnetic alloy onto their surface using electroplating technique,and the process of el... Spirulina platensis were chosen as templates to produce microscopic helical soft-core magnetic particles by way of depositing ferromagnetic alloy onto their surface using electroplating technique,and the process of electroplating ferromagnetic alloy onto microorganism cells was studied.The morphology and appearance of the coated Spirulina platensis were analyzed with optical microscopy and scanning electron microscopy,respectively,and the ingredients and phase structure of the alloy coating were analyzed with energy dispersive X-ray detector(EDX) and X-ray diffractive analysis(XRD),respectively.The result showed that the particles were successfully coated with uniform metal coating and their initial helical shape was perfectly replicated.The coating was NiFe alloy,and its phase structure was face-centered cubic structure.The magnetic properties of the coated particles were tested with vibrating sample magnetometer(VSM),and the result showed that the particles were ferro-magnetic,which means the magnetic electroplating of the microorganism cells was successfully achieved.The electrochemical reaction mechanism of the magnetic plating process was also analyzed;the result showed that the deposition of NiFe on the microorganism cells was anomalous codeposition,and that Fe2+ ion was preferential deposited when magnetic stirring was applied. 展开更多
关键词 bio-limited forming MICROORGANISM helical particles ELECTROPLATING magnetic metallization
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Formation of Extended Covalently Bonded Ni Porphyrin Networks on the Au(lll) Surface
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作者 Sergey A. Krasnikov Catherine M. Doyle +6 位作者 Natalia N. Sergeeva Alexei B. Preobrajenski Nikolay A.Vinogradov Yulia N. Sergeeva Alexei A. Zakharov Mathias O. Senge Attilio A. Cafolla 《Nano Research》 SCIE EI CAS CSCD 2011年第4期376-384,共9页
The growth and ordering of {5,10,15,20-tetrakis(4-bromophenyl)porphyrinato}nickel(II) (NiTBrPP) molecules on the Au(111) surface have been investigated using scanning tunnelling microscopy, X-ray absorption, c... The growth and ordering of {5,10,15,20-tetrakis(4-bromophenyl)porphyrinato}nickel(II) (NiTBrPP) molecules on the Au(111) surface have been investigated using scanning tunnelling microscopy, X-ray absorption, core-level photoemission, and microbeam low-energy electron diffraction. When deposited onto the substrate at room temperature, the NiTBrPP forms a well-ordered close-packed molecular layer in which the molecules have a flat orientation with the porphyrin macrocycle plane lying parallel to the substrate. Annealing of the NiTBrPP layer on the Au(111) surface at 525 K leads to dissociation of bromine from the porphyrin followed by the formation of covalent bonds between the phenyl substituents of the porphyrin. This results in the formation of continuous covalently bonded porphyrin networks, which are stable up to 800 K and can be recovered after exposure to ambient conditions. By controlling the experimental conditions, a robust, extended porphyrin network can be prepared on the Au(111) surface that has many potential applications such as protective coatings, in sensing or as a host structure for molecules and clusters. 展开更多
关键词 PORPHYRINS covalently bonded networks scanning tunnelling microscopy X-ray photoemission spectroscopy near-edge X-ray absorption fine structure Au(111)
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