The fluorine-containing organic polymer was synthesized from 3, 3', 4, 4'-Bisphenyltetracarboxylic (BPDA), and 2,2-Bis (3-amino-4-hydroxyyphenyl) hexafluoropropane (6FHP). It is a first-step preparation of a p...The fluorine-containing organic polymer was synthesized from 3, 3', 4, 4'-Bisphenyltetracarboxylic (BPDA), and 2,2-Bis (3-amino-4-hydroxyyphenyl) hexafluoropropane (6FHP). It is a first-step preparation of a preimided hydroxy-containing polyimide, followed by the covalent bonding of an active chromophore, dispersed red 19 (DR19), onto the backbone of the polyimide via the Mitsunobu reaction. The nonlinear optical (NLO) containing polyimide was synthesized. The differential scanning calorimeter (DSC)and thermal gravimetric analysis (TGA) exhibited Tg and the temperature Tg at which 5 % mass losses occurring of polymer were 248 and 309 ℃, respectively. A reflective electro-optic (EO) modulator using this polymer was fabricated. The optical nonlinearities were determined to be d33 = 5. 209×10^-9 esu (poling voltage of 3.6 kV, 205 ℃) and d33 =7. 418×10^-9esu (poling voltage of 3. 8 kV, 210 ℃) by the second harmonic generation method in in-situ condition at a fundamental wavelength of 1 064 nm. The EO coefficients 733 of the polymer layer in the EO modulator were determined to be 2. 182 pm/V (poling voltage of 3.6 kV, 205 ℃) and 3. 107 pm/V (poling voltage of 3.8 kV, 210 ℃) at 1064 nm by an attenuated-total-reflection (ATR) method.展开更多
The photo-physical properties of oligo(fluorene-vinylene) functionalized anthracene linear oligomers (An-OFVn (n=1-4)) have been systemically investigated through experimental and theoretical methods. The steady...The photo-physical properties of oligo(fluorene-vinylene) functionalized anthracene linear oligomers (An-OFVn (n=1-4)) have been systemically investigated through experimental and theoretical methods. The steady-state spectral measurement shows that the increasing of fluorene-vinylene (FV) group could lead to the red shift of absorption spectra and restrain the excimer formation between oligomers. Quantum chemical calculations exhibit that the energy levels of HOMO, LUMO, and the band gap gradually converge to a constant in accompany with the increasing of FV unit. Meanwhile, the electronic cloud which distributes on the branch arms, also gradually enhances and makes the absorption spectral shape of oligomers become similar to that of branch arms step by step. The time-resolved fluorescence tests exhibits that the lifetime of excimer emission would be almost invariable after the number of FV group in oligomer is ≥2. In nonlinear optical test, the two-photon photoluminescence efficiency and two-photon absorption cross-section will both gradually enhance and be close to an extremum after the number of FV unit is equal to 4. These results will provide a guideline for the design of novel photo-electronic materials.展开更多
From the analysis of infrared (IR) transmission spectrum, it was showed that the SiO x films were produced when polymethyl phenethyl silane (PMPES) was treated with O 2 plasma, where the x ranged from 1.5 ...From the analysis of infrared (IR) transmission spectrum, it was showed that the SiO x films were produced when polymethyl phenethyl silane (PMPES) was treated with O 2 plasma, where the x ranged from 1.5 to 2. This film has a positive flat band voltage on the curve of high frequency C V chart, its value is dependent on the condition of O 2 plasma treatment and the thickness of PMPES film.展开更多
The transparent solid medium of a thermotropic liquid crystal polymer have a comb structure of mesogenic side chains which exhibit a nonlinear optical response of electronic origin.The main chain of the liquid crystal...The transparent solid medium of a thermotropic liquid crystal polymer have a comb structure of mesogenic side chains which exhibit a nonlinear optical response of electronic origin.The main chain of the liquid crystal polymers can be selected from a number of suitable polymerized monomeric and comonomeric structures such as polyvinyl,polysiloxane,polyoxyalkylene, polyester etc.The electrooptic light modulator is provided,which have potential to using in the systems of laser modulation and deflection,and information control in optical circuitry etc.展开更多
We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from...We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from a model fitting into the transient absorption experimental data. Here we present a direct ultrafast fluorescence quenching measurement by employing fs time-resolved transient fluorescence spectroscopy based on noncollinear optical parametric amplification technique. The rapid decay of the monomer's emission due to energy transfer was observed directly with a time constant of about 0.82 ps, in good agreement with the previous result.展开更多
Using pyromellitic dianhydride (PMDA) and 4,4’ diaminodiphenyl ether (ODA) as monomer materials, polyimide thin films have been prepared onto glass substrate by vapor deposition polymerization under a vacuum of 2.666...Using pyromellitic dianhydride (PMDA) and 4,4’ diaminodiphenyl ether (ODA) as monomer materials, polyimide thin films have been prepared onto glass substrate by vapor deposition polymerization under a vacuum of 2.666×10 -3 Pa and thermal curing of polyamic acid film in a vacuum at temperature of 150~200 ℃ for 60 min. In this process, the polymerization can be carried out through controlling the stoichiometric ratio, heating time and deposition ratio of the two monomers. The composition, the structure and properties of the polyimide films are investigated with IR spectrum, XRD, and SEM methods. The results show that the polyimide films by vapor deposition polymerization have good electrical properties and thermal stability. Therefore, the vapor deposition polymerization process is considered as a possible method of polymerization for other polymers.展开更多
The preparation of a nonlinear directional coupler in polymer PMMA/DR1 film by photobleaching is studied. We find it easier to obtain a required coupling length by controlling photo bleaching time than by controlling ...The preparation of a nonlinear directional coupler in polymer PMMA/DR1 film by photobleaching is studied. We find it easier to obtain a required coupling length by controlling photo bleaching time than by controlling the dimension of the coupler. The transmittance of each arm is measured when the pulse input light energy changes in our experiment. The experimental results show that the coupling length will change with the intensity of input light due to optical nonlinearities of the polymer PMMA/DR1 at 1 064 nm.展开更多
A simple setup for the measurement of transmission loss in polymer thin film optical waveguides is described. A new electro-optic polymer film has been prepared. The transmission loss of the film is measured before an...A simple setup for the measurement of transmission loss in polymer thin film optical waveguides is described. A new electro-optic polymer film has been prepared. The transmission loss of the film is measured before and after corona poling. And the loss is determined to be 1.84 dB/cm and 2.14 dB/cm, respectively.展开更多
In this paper, by applying the extended 3acobi elliptic function expansion method, the envelope periodic solutions and corresponding dark soliton solution, bright soliton solution to Bose-Einstein condensation in line...In this paper, by applying the extended 3acobi elliptic function expansion method, the envelope periodic solutions and corresponding dark soliton solution, bright soliton solution to Bose-Einstein condensation in linear magnetic field and time-dependent laser field are obtained.展开更多
In order to modify inorganic particles as chromatic electrophoretic particles, an approach was designed and used to prepare Fe203 red electrophoretic particles. These Fe203-cationic hybrid nanoparticles (Fe203-CHNPs...In order to modify inorganic particles as chromatic electrophoretic particles, an approach was designed and used to prepare Fe203 red electrophoretic particles. These Fe203-cationic hybrid nanoparticles (Fe203-CHNPs)were prepared through Fe203 core covered with polymer shell which was composed of SiO2 and P (DMAEMA-co-HMA) by using atom transfer radical polymerization (ATRP)technique. The SiO:-coating could introduce the functional group on the surfaceof inorganic particles, through which the polymer shell could be formed by using ATRP tech- nique. The results of Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA)confirmed the chemical compositions of Fe2O3-CHNPs; the images of transmission elec- tron microscopy (TEM) indicated the core-shell structure of Fe2O3-CHNPs; the measurements of dynamic light scatter- ing (DLS) showed a 253.7 nm average particle size with narrow size distribution; and the zeta potential measurements identified the high chargeability of Fe2O3-CHNPs. Furthermore, the resulting nanoparticles were successfully applied in the electrophoretic display cell, which demonstrated that it was an effective approach to preparing chromatic elec- trophoretic particles.展开更多
PbS quantum dots were prepared in the aqueous medium from readily available precursors. The shape of the particles isapproximately spherical, and the average particle size observed from HRTEM image was 7-8 nm. We appl...PbS quantum dots were prepared in the aqueous medium from readily available precursors. The shape of the particles isapproximately spherical, and the average particle size observed from HRTEM image was 7-8 nm. We applied PbS quantumdots and PMMA polymer to fabricate PbS quantum dots-PMMA composites, and investigate the photoluminescence PbSquantum dots in PMMA matrix with different mass ratio. PbS quantum dots in PMMA matrix have broad emission be-tween 900 nm and 1 500 nm and photoluminescence peak at 1 179 nm. Additionally, the photoluminescence intensityincreases with increasing the dopant concentration. PbS quantum dots-PMMA polymer composites can be potentially usedfor polymer optical fiber and electroluminescence (EL) in optical communication.展开更多
The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV...The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV/Vis regime as well as the linear polarizabiliti y and nonlinear hyperpolarizability are calculated by using quantum chemical ab initio and semiempirical methods. The relationship of its optical property to el ectric field is obtained. Some physical mechanism of electric field effect on mo lecular optical property is discussed by means of electron distribution and intr amolecular charge transfer.展开更多
In this paper, detailed optical of the solar parabolic dish concentrator is presented. The system has diameter D = 2,800 mm and focal length f = 1,400 mm. The efficient conversion of solar radiation in heat at these t...In this paper, detailed optical of the solar parabolic dish concentrator is presented. The system has diameter D = 2,800 mm and focal length f = 1,400 mm. The efficient conversion of solar radiation in heat at these temperature levels requires a use of concentrating solar collectors. In this paper, detailed optical design of the solar parabolic dish concentrator is presented. The parabolic dish of the solar system consists from 12 curvilinear trapezoidal reflective petals. This paper presents optical simulations of the parabolic solar concentrator unit using the ray-tracing software TracePro. The total flux on receiver and the distribution of irradiance for absorbed flux on center and periphery receiver are given. The total flux at the focal region is 4,031.3 W. The goal of this paper is to present optical design of a low-tech solar concentrator, that can be used as a potentially low-cost tool for laboratory-scale research on the medium-temperature thermal processes, cooling, industrial processes, solar cooking and polygeneration systems, etc.展开更多
The nonlinear optic characteristics of an intense laser pulse propagating in partially stripped plasmas are investigated analytically. The phase and group velocity of the laser pulse propagation as well as the three g...The nonlinear optic characteristics of an intense laser pulse propagating in partially stripped plasmas are investigated analytically. The phase and group velocity of the laser pulse propagation as well as the three general expressions governing the nonlinear optic behavior, based on the photon number conservation, are obtained by considering the partially stripped plasma as a nonlinear optic medium. The numerical result shows that the presence of the bound electrons in partially stripped plasma can significantly change the propagating property of the intense laser pulse.展开更多
We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers (Tr-OFVn, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorp...We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers (Tr-OFVn, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligolners gradually enhance in company with the extension of π- conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing organic materials for two-photon applications.展开更多
The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conj...The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.展开更多
Nano-silver/polyvinylpyrrolidone(PVP)composite materials were successfully synthesized bi-insitu from silver nitrate solution with N-vinyl pyrrolidone (NVP) monomer,containing neither initiator nor reductant, in ultra...Nano-silver/polyvinylpyrrolidone(PVP)composite materials were successfully synthesized bi-insitu from silver nitrate solution with N-vinyl pyrrolidone (NVP) monomer,containing neither initiator nor reductant, in ultraviolet irradiation conditions.The resultant Ag/PVP nanocomposites were characterized by infrared spectroscopy (FT-IR), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD).TEM show that nano silver particles are homogeneously dispersed in PVP polymer matrix, and the mean size of spherical silver particles is about 5 nm.The spectroscopy of XPS and FTIR showed that there is an interaction between nano silver not only with carbonyl oxygen but also with the nitrogen group within the NVP molecule through the p-π conjugation effect in the nano-silver/PVP composites system.展开更多
We study the formation of a dynamically-stabilized dissipation-managed bright soliton in a quasi-onedimensional Bose-Einstein condensate by including an imaginary three-body recombination loss term and an imaginary li...We study the formation of a dynamically-stabilized dissipation-managed bright soliton in a quasi-onedimensional Bose-Einstein condensate by including an imaginary three-body recombination loss term and an imaginary linear feeding one in the Gross Pitaevskii equation, trapped in a shallow optical-lattice potential. Based on the direct approach of perturbation theory for the nonlinear Schroedinger equation, we demonstrate that the height (as well as width) of bright soliton may have little change through selecting experimental parameters.展开更多
基金Jiangsu Planned Projects for Postdoctoral ResearchFunds(No0602037B)the Natural Science Foundation of Higher Edu-cation Institutions of Jiangsu Province (No05KJB150016)+1 种基金the Nation-al Natural Science Foundation of China (No50377005)the Fund ofJiangsu University (No06JDG015)
文摘The fluorine-containing organic polymer was synthesized from 3, 3', 4, 4'-Bisphenyltetracarboxylic (BPDA), and 2,2-Bis (3-amino-4-hydroxyyphenyl) hexafluoropropane (6FHP). It is a first-step preparation of a preimided hydroxy-containing polyimide, followed by the covalent bonding of an active chromophore, dispersed red 19 (DR19), onto the backbone of the polyimide via the Mitsunobu reaction. The nonlinear optical (NLO) containing polyimide was synthesized. The differential scanning calorimeter (DSC)and thermal gravimetric analysis (TGA) exhibited Tg and the temperature Tg at which 5 % mass losses occurring of polymer were 248 and 309 ℃, respectively. A reflective electro-optic (EO) modulator using this polymer was fabricated. The optical nonlinearities were determined to be d33 = 5. 209×10^-9 esu (poling voltage of 3.6 kV, 205 ℃) and d33 =7. 418×10^-9esu (poling voltage of 3. 8 kV, 210 ℃) by the second harmonic generation method in in-situ condition at a fundamental wavelength of 1 064 nm. The EO coefficients 733 of the polymer layer in the EO modulator were determined to be 2. 182 pm/V (poling voltage of 3.6 kV, 205 ℃) and 3. 107 pm/V (poling voltage of 3.8 kV, 210 ℃) at 1064 nm by an attenuated-total-reflection (ATR) method.
文摘The photo-physical properties of oligo(fluorene-vinylene) functionalized anthracene linear oligomers (An-OFVn (n=1-4)) have been systemically investigated through experimental and theoretical methods. The steady-state spectral measurement shows that the increasing of fluorene-vinylene (FV) group could lead to the red shift of absorption spectra and restrain the excimer formation between oligomers. Quantum chemical calculations exhibit that the energy levels of HOMO, LUMO, and the band gap gradually converge to a constant in accompany with the increasing of FV unit. Meanwhile, the electronic cloud which distributes on the branch arms, also gradually enhances and makes the absorption spectral shape of oligomers become similar to that of branch arms step by step. The time-resolved fluorescence tests exhibits that the lifetime of excimer emission would be almost invariable after the number of FV group in oligomer is ≥2. In nonlinear optical test, the two-photon photoluminescence efficiency and two-photon absorption cross-section will both gradually enhance and be close to an extremum after the number of FV unit is equal to 4. These results will provide a guideline for the design of novel photo-electronic materials.
文摘From the analysis of infrared (IR) transmission spectrum, it was showed that the SiO x films were produced when polymethyl phenethyl silane (PMPES) was treated with O 2 plasma, where the x ranged from 1.5 to 2. This film has a positive flat band voltage on the curve of high frequency C V chart, its value is dependent on the condition of O 2 plasma treatment and the thickness of PMPES film.
文摘The transparent solid medium of a thermotropic liquid crystal polymer have a comb structure of mesogenic side chains which exhibit a nonlinear optical response of electronic origin.The main chain of the liquid crystal polymers can be selected from a number of suitable polymerized monomeric and comonomeric structures such as polyvinyl,polysiloxane,polyoxyalkylene, polyester etc.The electrooptic light modulator is provided,which have potential to using in the systems of laser modulation and deflection,and information control in optical circuitry etc.
基金This work was supported by the National Natural Science Foundation of China (No.20925313 and No.60438020), the National Basic Research Program of China (No.2009CB929404), and the Chinese Academy of Sciences Innovation Program (KJCX2-YW-W25).
文摘We have reported previously the ultrafast energy transfer process with a time constant of 0.8 ps from a monomeric to a dimeric subunit within a perylenetetracarboxylic diimide trimer, which was derived indirectly from a model fitting into the transient absorption experimental data. Here we present a direct ultrafast fluorescence quenching measurement by employing fs time-resolved transient fluorescence spectroscopy based on noncollinear optical parametric amplification technique. The rapid decay of the monomer's emission due to energy transfer was observed directly with a time constant of about 0.82 ps, in good agreement with the previous result.
文摘Using pyromellitic dianhydride (PMDA) and 4,4’ diaminodiphenyl ether (ODA) as monomer materials, polyimide thin films have been prepared onto glass substrate by vapor deposition polymerization under a vacuum of 2.666×10 -3 Pa and thermal curing of polyamic acid film in a vacuum at temperature of 150~200 ℃ for 60 min. In this process, the polymerization can be carried out through controlling the stoichiometric ratio, heating time and deposition ratio of the two monomers. The composition, the structure and properties of the polyimide films are investigated with IR spectrum, XRD, and SEM methods. The results show that the polyimide films by vapor deposition polymerization have good electrical properties and thermal stability. Therefore, the vapor deposition polymerization process is considered as a possible method of polymerization for other polymers.
文摘The preparation of a nonlinear directional coupler in polymer PMMA/DR1 film by photobleaching is studied. We find it easier to obtain a required coupling length by controlling photo bleaching time than by controlling the dimension of the coupler. The transmittance of each arm is measured when the pulse input light energy changes in our experiment. The experimental results show that the coupling length will change with the intensity of input light due to optical nonlinearities of the polymer PMMA/DR1 at 1 064 nm.
文摘A simple setup for the measurement of transmission loss in polymer thin film optical waveguides is described. A new electro-optic polymer film has been prepared. The transmission loss of the film is measured before and after corona poling. And the loss is determined to be 1.84 dB/cm and 2.14 dB/cm, respectively.
基金Supported by National Natural Science Foundation of China under Grant No.90511009
文摘In this paper, by applying the extended 3acobi elliptic function expansion method, the envelope periodic solutions and corresponding dark soliton solution, bright soliton solution to Bose-Einstein condensation in linear magnetic field and time-dependent laser field are obtained.
文摘In order to modify inorganic particles as chromatic electrophoretic particles, an approach was designed and used to prepare Fe203 red electrophoretic particles. These Fe203-cationic hybrid nanoparticles (Fe203-CHNPs)were prepared through Fe203 core covered with polymer shell which was composed of SiO2 and P (DMAEMA-co-HMA) by using atom transfer radical polymerization (ATRP)technique. The SiO:-coating could introduce the functional group on the surfaceof inorganic particles, through which the polymer shell could be formed by using ATRP tech- nique. The results of Fourier transform infrared spectra (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA)confirmed the chemical compositions of Fe2O3-CHNPs; the images of transmission elec- tron microscopy (TEM) indicated the core-shell structure of Fe2O3-CHNPs; the measurements of dynamic light scatter- ing (DLS) showed a 253.7 nm average particle size with narrow size distribution; and the zeta potential measurements identified the high chargeability of Fe2O3-CHNPs. Furthermore, the resulting nanoparticles were successfully applied in the electrophoretic display cell, which demonstrated that it was an effective approach to preparing chromatic elec- trophoretic particles.
基金This work was supported by the National Key Basic ResearchDevelopment Program of China (Grant 2003CB314906)+1 种基金the Na-tional Natural Science Foundation of China (Grant 10674074)the Natural Science Foundation of Tianjin (Grant07JCYBJC06400)
文摘PbS quantum dots were prepared in the aqueous medium from readily available precursors. The shape of the particles isapproximately spherical, and the average particle size observed from HRTEM image was 7-8 nm. We applied PbS quantumdots and PMMA polymer to fabricate PbS quantum dots-PMMA composites, and investigate the photoluminescence PbSquantum dots in PMMA matrix with different mass ratio. PbS quantum dots in PMMA matrix have broad emission be-tween 900 nm and 1 500 nm and photoluminescence peak at 1 179 nm. Additionally, the photoluminescence intensityincreases with increasing the dopant concentration. PbS quantum dots-PMMA polymer composites can be potentially usedfor polymer optical fiber and electroluminescence (EL) in optical communication.
基金Natural Science Foundation from Shandong Province of China (Y2002A06)
文摘The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV/Vis regime as well as the linear polarizabiliti y and nonlinear hyperpolarizability are calculated by using quantum chemical ab initio and semiempirical methods. The relationship of its optical property to el ectric field is obtained. Some physical mechanism of electric field effect on mo lecular optical property is discussed by means of electron distribution and intr amolecular charge transfer.
文摘In this paper, detailed optical of the solar parabolic dish concentrator is presented. The system has diameter D = 2,800 mm and focal length f = 1,400 mm. The efficient conversion of solar radiation in heat at these temperature levels requires a use of concentrating solar collectors. In this paper, detailed optical design of the solar parabolic dish concentrator is presented. The parabolic dish of the solar system consists from 12 curvilinear trapezoidal reflective petals. This paper presents optical simulations of the parabolic solar concentrator unit using the ray-tracing software TracePro. The total flux on receiver and the distribution of irradiance for absorbed flux on center and periphery receiver are given. The total flux at the focal region is 4,031.3 W. The goal of this paper is to present optical design of a low-tech solar concentrator, that can be used as a potentially low-cost tool for laboratory-scale research on the medium-temperature thermal processes, cooling, industrial processes, solar cooking and polygeneration systems, etc.
基金the National Natural Science Foundation of China under
文摘The nonlinear optic characteristics of an intense laser pulse propagating in partially stripped plasmas are investigated analytically. The phase and group velocity of the laser pulse propagation as well as the three general expressions governing the nonlinear optic behavior, based on the photon number conservation, are obtained by considering the partially stripped plasma as a nonlinear optic medium. The numerical result shows that the presence of the bound electrons in partially stripped plasma can significantly change the propagating property of the intense laser pulse.
文摘We investigate the fluorene-vinylene unit dependent photo-physical properties of multi- branched truxene based oligomers (Tr-OFVn, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligolners gradually enhance in company with the extension of π- conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing organic materials for two-photon applications.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China. (No.21103161. No.11274142, No.11304058, No.11274034. and No.11004080) and the China Postdoctoral Science Foundation (No.2011MS00927 and No.2013T60319).
文摘The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.
文摘Nano-silver/polyvinylpyrrolidone(PVP)composite materials were successfully synthesized bi-insitu from silver nitrate solution with N-vinyl pyrrolidone (NVP) monomer,containing neither initiator nor reductant, in ultraviolet irradiation conditions.The resultant Ag/PVP nanocomposites were characterized by infrared spectroscopy (FT-IR), high resolution transmission electron microscopy (HRTEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD).TEM show that nano silver particles are homogeneously dispersed in PVP polymer matrix, and the mean size of spherical silver particles is about 5 nm.The spectroscopy of XPS and FTIR showed that there is an interaction between nano silver not only with carbonyl oxygen but also with the nitrogen group within the NVP molecule through the p-π conjugation effect in the nano-silver/PVP composites system.
基金Supported by National Natural Science Foundation of China under Grant Nos.10775049 and 10375022the Natural Science Foundation of Hunan Province under Grant No.09JJ6008the Education Ministry of Hunan Province under Grant No.09C637
文摘We study the formation of a dynamically-stabilized dissipation-managed bright soliton in a quasi-onedimensional Bose-Einstein condensate by including an imaginary three-body recombination loss term and an imaginary linear feeding one in the Gross Pitaevskii equation, trapped in a shallow optical-lattice potential. Based on the direct approach of perturbation theory for the nonlinear Schroedinger equation, we demonstrate that the height (as well as width) of bright soliton may have little change through selecting experimental parameters.