The impact of cold rolling deformation,which was introduced after solid solution and before aging treatment,on microstructure evolution and mechanical properties of the as-extruded spray formed Al−9.8Zn−2.3Mg−1.73Cu−0...The impact of cold rolling deformation,which was introduced after solid solution and before aging treatment,on microstructure evolution and mechanical properties of the as-extruded spray formed Al−9.8Zn−2.3Mg−1.73Cu−0.13Cr(wt.%)alloy,was investigated.SEM,TEM,and EBSD were used to analyze the microstructures,and tensile tests were conducted to assess mechanical properties.The results indicate that the D1-T6 sample,subjected to 25%cold rolling deformation,exhibits finer grains(3.35μm)compared to the D0-T6 sample(grain size of 4.23μm)without cold rolling.Cold rolling refines the grains that grow in solution treatment.Due to the combined effects of finer and more dispersed precipitates,higher dislocation density and smaller grains,the yield strength and ultimate tensile strength of the D1-T6 sample can reach 663 and 737 MPa,respectively.In comparison to the as-extruded and D0-T6 samples,the yield strength of the D1-T6 sample increases by 415 and 92 MPa,respectively.展开更多
With the aim to improve the strength of Al-Zn-Mg-Cu alloy,the alloy billet containing Mn was produced by spray forming method,and the microstructural features were investigated using X-ray diffraction(XRD),optical m...With the aim to improve the strength of Al-Zn-Mg-Cu alloy,the alloy billet containing Mn was produced by spray forming method,and the microstructural features were investigated using X-ray diffraction(XRD),optical microscopy(OM),scanning electron microscopy(SEM),transmission electron microscopy(TEM) and differential scanning calorimetry(DSC).The results show that the billet mainly consists of fine equiaxial grains of MgZn2 and Al6Mn with size ranging from 5 μm to 25 μm.Nano-scaled MgZn2 is dispersed in the as-sprayed alloy,primary Al6Mn particles are precipitated at grain boundaries with an average size of 5 μm.A few CuAl2,Al3Zr and eutectic are also found in as-sprayed Al alloy.The volume fraction of the porosity is about 12%.DSC result indicates that most of the solutes are precipitated during spray forming process,and no obviously thermal effects occur below 450 ℃.Both matrix grains and Al6Mn particles grow monotonously with the increase of annealing temperature,but the growth rate of Al6Mn particles is markedly lower than that of Al grains,and the matrix grains grow rapidly when the annealing temperature is above 375 ℃.展开更多
A series of Al-6Si-3Cu-(0.3-2)Mg alloys were produced by a conventional casting process.Cooling slope technique wasemployed to produce feedstocks before they were thixoformed at50%liquid fraction.The effect of Mg on t...A series of Al-6Si-3Cu-(0.3-2)Mg alloys were produced by a conventional casting process.Cooling slope technique wasemployed to produce feedstocks before they were thixoformed at50%liquid fraction.The effect of Mg on the microstructure ofAl-Si-Cu aluminium alloys under as-cast and semisolid conditions was investigated.It was found that by adding Mg to Al-Si-Cualloy,some of the Al2Cu phase and silicon were consumed to form Al5Cu2Mg3Si5and Mg2Si phases.The needle-likeβ-Al5FeSi phasetransformed to Chinese-script-likeπ-Al8Mg3FeSi6with the addition of Mg.In the as-cast alloys,the primaryα(Al)was dendritic,butas the Mg content increased,the phase became less dendritic.Moreover,the Mg addition considerably modified the size of theα(Al)phase,but it had no significant effect on the silicon morphology.In the thixoformed alloys,the microstructure showed a fine globularprimary phase surrounded by uniformly distributed silicon and fragmented intermetallic phases.The eutectic silicon was modifiedfrom a flaky and acicular shape to fine fibrous particles.The effect of Mg on eutectic silicon during semisolid processing wasevident.The primary Mg2Si particles were modified from big polygonal particles to become smaller and more globular,whereas themorphology of the Chinese-script-likeπ-Al8Mg3FeSi6changed to a compact shape.The results also exhibit that as the Mg content inthe A319alloy increased,the hardness,yield strength and ultimate tensile strength of the thixoformed alloys significantly improved,but the elongation to fracture dropped.展开更多
This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely ...This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely wall angle(35°-55°),feed rate(1-4 m/min),spindle rotational speed(50-1000 r/min),and lubricant(grease and hydraulic oil)are varied to probe detailed processing effects.The pre-and post-SPIF mechanical properties and microstructures are characterized by conducting tensile tests and optical microscopy,respectively.It is shown that an increase in the wall angle,feed rate and rotational speed causes microscopic variations in the alloys such that the grains of AA5754 and the second phase particles of AA6061 elongate.As a result,the ultimate tensile strength of the formed parts is increased by 10%for AA5754 and by 8%for AA6061.And,the ductility of AA5754 is decreased from 22.9%to 12%and that of AA6061 is decreased from 16%to 10.7%.Regarding the lubricant effect,it is shown that the mechanical properties remain insensitive to the type of lubricant employed.These results indicate that SPIF processing modifies the microstructure of Al alloys in a way to enhance the strength at the cost of ductility.展开更多
An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that t...An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.展开更多
The microstructure formation and grains refinement of two Mg-based alloys,i.e.AZ31 and AZ91D,were reported using an electromagnetic vibration(EMV) technique.These two alloys were solidified at various vibration freque...The microstructure formation and grains refinement of two Mg-based alloys,i.e.AZ31 and AZ91D,were reported using an electromagnetic vibration(EMV) technique.These two alloys were solidified at various vibration frequencies and the microstructures were observed.The average size of grains was quantitatively measured as a function of vibration frequencies. Moreover,the grain size distribution was outlined versus number fraction.A novel model was proposed to account for the microstructure formation and grain refinement when considering the significant difference of the electrical resistivity properties of the solid and the liquid during EMV processing in the semisolid state.The remarkable difference originates uncoupled movement between the mobile solid and the sluggish liquid,which can activate melt flow.The microstructure evolution can be well explained when the fluid flow intensity versus vibration frequency is taken into account.Moreover,the influence of the static magnetic field on texture formation is also considered,which plays an important role at higher vibration frequencies.展开更多
Maceral composition and aromatic compounds were determined on columnsamples to study the peat-forming environments of Permian coal seam 2 and Carboniferouscoal seam 9^(-2) from the Xingtai coalfield,China.The macerals...Maceral composition and aromatic compounds were determined on columnsamples to study the peat-forming environments of Permian coal seam 2 and Carboniferouscoal seam 9^(-2) from the Xingtai coalfield,China.The macerals were dominated by inertinitein seam 2 and by vitrinite in seam 9^(-2).Three maceral groups were selected as indicatorsof peat-forming environments.Two triangle diagrams were drawn based on the indicatorsto explicate the peat-forming environments of permian seam 2 and Carboniferousseam 9^(-2).The results indicate that the peat of carboniferous seam 9^(-2) formed dominantlyin wet swamps,whereas the peat of Permian seam 2 formed dominantly in dry swampsand open moor environments.展开更多
AZ61Mg alloy was multi directionally forged(MDFed) during decreasing temperature condition from 643 K to 483 K at a true strain rate of 3×10-3 s-1 up to cumulative strain of∑△ε=4.0 at maximum.A pass strain of...AZ61Mg alloy was multi directionally forged(MDFed) during decreasing temperature condition from 643 K to 483 K at a true strain rate of 3×10-3 s-1 up to cumulative strain of∑△ε=4.0 at maximum.A pass strain of△ε=0.8 was employed.While average grain size decreased gradually with increasing cumulative strain,the evolution of fine-grained structure strongly depended on the MDF temperature.Under the condition where the temperature was higher than the most adequate one,grain coarsening partially took place during MDF.In contrast,at lower temperature,inhomogeneous microstructure composed of the initial coarse and newly appeared fine grains was evolved.After straining over∑△ε=3.2(i.e.,over 4 passes of MDF) ,equiaxed ultrafine grains(UFGs) having average size of about and lower than 1μm were uniformly evolved.While the MDFed alloy to∑△ε=4.0 possessed relatively high hardness of HV 99,and it accepted further about 20%cold rolling almost without cracking.Because of the superior formability of the UFGed AZ61Mg alloy,the hardness was further easily raised to HV 120 by following cold rolling.展开更多
The comers with small radii on cross sections are crucial for forming hydroformed components with polygonal sections. In this paper, warm hydroforming experiments of AZ61A magnesium alloy tubes were cartied out to stu...The comers with small radii on cross sections are crucial for forming hydroformed components with polygonal sections. In this paper, warm hydroforming experiments of AZ61A magnesium alloy tubes were cartied out to study the forming regularity of round comers by using a demonstration part with square sections. Effects of temperature on radius forming, thinning ratio distribution and microstructure were revealed and a component with relative outer corner radius of 3.0 was obtained by warm hydroforming at 240℃. The minimum thickness of the formed square section was located in the transition position between the corner and the straight wall. The thinning ratio of the round corner increased with the increase of forming temperature. Fotmability of the magnesium tube was improved by raising temperature under the effect of dynamic recrystallization at 240℃.展开更多
The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule...The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule (referring to dichloromethane, chloroform and acetonitrile), can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1:1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.展开更多
For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchange...For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchangensis "Caucasus" obtained using hybrid citrange of American origin _ C. Kinokuni X C.ichanglemon, which gives an eatable lemon with a chemical composition similar to the normal lemon fruit and without any damage it can resist frost at -16 ℃ temperature and b) spontaneous mutations of trifoliata: #1 and #2 which are distinguished among trifoliata species. Their fruits don't contain or contain a small amount of the substances that deteriorate the taste: naringin, porcine and so on. They are characterized by high index of frost resistance. In the experiment when obtaining sexual hybrids of the Washington naval orange the above mentioned components were used and hybrid seedlings were obtained, which are distinguished according to their phenotypic hereditary features. Selected seedlings represent the best initial material for a successful future work.展开更多
The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A...The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A1-AIN- 50SiB material (prepared by ball-milling powders) and AI- AIN-50SiM material (prepared by mixing powders) exhibited the semi-continuous Si structures and the isolated Si islands, respectively. Subsequently, the AI-AIN-50Si materials were selected as the model materials by phase identification and microstructure analysis. The dynamic microstructural evolu- tion of AI-AIN-50Si materials was investigated using the computational fluid dynamics (CFD) method. Mathematical models and simulation results showed that the in situ synthesis of AIN was strongly influenced by the structure and the flow- path ((Cg,N2/lg,N2)+(Cs,AlN/ls,AiN)). The flow paths of AI-AIN-50Si^B material were restricted by the semi-continuous Si. These Si structures can promote the formation of the strong turbulence with gradually weakened fluctuation, so that the in situ synthesis of AIN was interconnected and surrounded by an interpenetrating Si network. In contrast, the flow paths of AI- AIN-50Si^B material can easily pass through the isolated Si due to its mild turbulence with linear relationship. As a result, AIN was separated by the isolated Si and agglomerated in the matrix. Overall, the present work provides new insights into dynamic microstructural evolution in in situ reaction sinter- ing systems.展开更多
基金the support from the National Natural Science Foundation of China(No.52271177)the Science and Technology Innovation Leaders Projects in Hunan Province,China(No.2021RC4036).
文摘The impact of cold rolling deformation,which was introduced after solid solution and before aging treatment,on microstructure evolution and mechanical properties of the as-extruded spray formed Al−9.8Zn−2.3Mg−1.73Cu−0.13Cr(wt.%)alloy,was investigated.SEM,TEM,and EBSD were used to analyze the microstructures,and tensile tests were conducted to assess mechanical properties.The results indicate that the D1-T6 sample,subjected to 25%cold rolling deformation,exhibits finer grains(3.35μm)compared to the D0-T6 sample(grain size of 4.23μm)without cold rolling.Cold rolling refines the grains that grow in solution treatment.Due to the combined effects of finer and more dispersed precipitates,higher dislocation density and smaller grains,the yield strength and ultimate tensile strength of the D1-T6 sample can reach 663 and 737 MPa,respectively.In comparison to the as-extruded and D0-T6 samples,the yield strength of the D1-T6 sample increases by 415 and 92 MPa,respectively.
基金Project(2006CB605204) supported by the National Basic Research Program of China
文摘With the aim to improve the strength of Al-Zn-Mg-Cu alloy,the alloy billet containing Mn was produced by spray forming method,and the microstructural features were investigated using X-ray diffraction(XRD),optical microscopy(OM),scanning electron microscopy(SEM),transmission electron microscopy(TEM) and differential scanning calorimetry(DSC).The results show that the billet mainly consists of fine equiaxial grains of MgZn2 and Al6Mn with size ranging from 5 μm to 25 μm.Nano-scaled MgZn2 is dispersed in the as-sprayed alloy,primary Al6Mn particles are precipitated at grain boundaries with an average size of 5 μm.A few CuAl2,Al3Zr and eutectic are also found in as-sprayed Al alloy.The volume fraction of the porosity is about 12%.DSC result indicates that most of the solutes are precipitated during spray forming process,and no obviously thermal effects occur below 450 ℃.Both matrix grains and Al6Mn particles grow monotonously with the increase of annealing temperature,but the growth rate of Al6Mn particles is markedly lower than that of Al grains,and the matrix grains grow rapidly when the annealing temperature is above 375 ℃.
基金Universiti Kebangsaan Malaysia(UKM)and the Ministry of Higher Education(MOHE),Malaysia,for financial support under research grants AP-2012-014 and FRGS/1/2014/TK01/UKM/01/2
文摘A series of Al-6Si-3Cu-(0.3-2)Mg alloys were produced by a conventional casting process.Cooling slope technique wasemployed to produce feedstocks before they were thixoformed at50%liquid fraction.The effect of Mg on the microstructure ofAl-Si-Cu aluminium alloys under as-cast and semisolid conditions was investigated.It was found that by adding Mg to Al-Si-Cualloy,some of the Al2Cu phase and silicon were consumed to form Al5Cu2Mg3Si5and Mg2Si phases.The needle-likeβ-Al5FeSi phasetransformed to Chinese-script-likeπ-Al8Mg3FeSi6with the addition of Mg.In the as-cast alloys,the primaryα(Al)was dendritic,butas the Mg content increased,the phase became less dendritic.Moreover,the Mg addition considerably modified the size of theα(Al)phase,but it had no significant effect on the silicon morphology.In the thixoformed alloys,the microstructure showed a fine globularprimary phase surrounded by uniformly distributed silicon and fragmented intermetallic phases.The eutectic silicon was modifiedfrom a flaky and acicular shape to fine fibrous particles.The effect of Mg on eutectic silicon during semisolid processing wasevident.The primary Mg2Si particles were modified from big polygonal particles to become smaller and more globular,whereas themorphology of the Chinese-script-likeπ-Al8Mg3FeSi6changed to a compact shape.The results also exhibit that as the Mg content inthe A319alloy increased,the hardness,yield strength and ultimate tensile strength of the thixoformed alloys significantly improved,but the elongation to fracture dropped.
文摘This study performs single point incremental forming(SPIF)on two aluminum alloys(i.e.AA5754 and AA6061),and analyzes their post forming mechanical properties and microstructure evolution.The forming parameters namely wall angle(35°-55°),feed rate(1-4 m/min),spindle rotational speed(50-1000 r/min),and lubricant(grease and hydraulic oil)are varied to probe detailed processing effects.The pre-and post-SPIF mechanical properties and microstructures are characterized by conducting tensile tests and optical microscopy,respectively.It is shown that an increase in the wall angle,feed rate and rotational speed causes microscopic variations in the alloys such that the grains of AA5754 and the second phase particles of AA6061 elongate.As a result,the ultimate tensile strength of the formed parts is increased by 10%for AA5754 and by 8%for AA6061.And,the ductility of AA5754 is decreased from 22.9%to 12%and that of AA6061 is decreased from 16%to 10.7%.Regarding the lubricant effect,it is shown that the mechanical properties remain insensitive to the type of lubricant employed.These results indicate that SPIF processing modifies the microstructure of Al alloys in a way to enhance the strength at the cost of ductility.
基金Supported by the Key Program of National Natural Science Foundation of China(50736001) the National High Technology Research and Development Program of China(2006AA09A209-5) the Major State Basic Research Development Program of China(2009CB219507)
文摘An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature.
文摘The microstructure formation and grains refinement of two Mg-based alloys,i.e.AZ31 and AZ91D,were reported using an electromagnetic vibration(EMV) technique.These two alloys were solidified at various vibration frequencies and the microstructures were observed.The average size of grains was quantitatively measured as a function of vibration frequencies. Moreover,the grain size distribution was outlined versus number fraction.A novel model was proposed to account for the microstructure formation and grain refinement when considering the significant difference of the electrical resistivity properties of the solid and the liquid during EMV processing in the semisolid state.The remarkable difference originates uncoupled movement between the mobile solid and the sluggish liquid,which can activate melt flow.The microstructure evolution can be well explained when the fluid flow intensity versus vibration frequency is taken into account.Moreover,the influence of the static magnetic field on texture formation is also considered,which plays an important role at higher vibration frequencies.
基金Supported by the National Natural Science Foundation of China(40773040)the National Basic Research Program of China (2003CB214607)
文摘Maceral composition and aromatic compounds were determined on columnsamples to study the peat-forming environments of Permian coal seam 2 and Carboniferouscoal seam 9^(-2) from the Xingtai coalfield,China.The macerals were dominated by inertinitein seam 2 and by vitrinite in seam 9^(-2).Three maceral groups were selected as indicatorsof peat-forming environments.Two triangle diagrams were drawn based on the indicatorsto explicate the peat-forming environments of permian seam 2 and Carboniferousseam 9^(-2).The results indicate that the peat of carboniferous seam 9^(-2) formed dominantlyin wet swamps,whereas the peat of Permian seam 2 formed dominantly in dry swampsand open moor environments.
基金support given by the Light Metals Educational Foundation,Japan,and Ministry of Education,Culture,Sports and Technology,Japan,with Grant No.20560647
文摘AZ61Mg alloy was multi directionally forged(MDFed) during decreasing temperature condition from 643 K to 483 K at a true strain rate of 3×10-3 s-1 up to cumulative strain of∑△ε=4.0 at maximum.A pass strain of△ε=0.8 was employed.While average grain size decreased gradually with increasing cumulative strain,the evolution of fine-grained structure strongly depended on the MDF temperature.Under the condition where the temperature was higher than the most adequate one,grain coarsening partially took place during MDF.In contrast,at lower temperature,inhomogeneous microstructure composed of the initial coarse and newly appeared fine grains was evolved.After straining over∑△ε=3.2(i.e.,over 4 passes of MDF) ,equiaxed ultrafine grains(UFGs) having average size of about and lower than 1μm were uniformly evolved.While the MDFed alloy to∑△ε=4.0 possessed relatively high hardness of HV 99,and it accepted further about 20%cold rolling almost without cracking.Because of the superior formability of the UFGed AZ61Mg alloy,the hardness was further easily raised to HV 120 by following cold rolling.
基金Sponsored by the National Natural Science Foundation of China for Distinguished Young Scholars(Grant No. 50525516)the National Key Technology R&D Program (Grant No. 2006BAE04B03)Program for New Century Excellent Talents in University
文摘The comers with small radii on cross sections are crucial for forming hydroformed components with polygonal sections. In this paper, warm hydroforming experiments of AZ61A magnesium alloy tubes were cartied out to study the forming regularity of round comers by using a demonstration part with square sections. Effects of temperature on radius forming, thinning ratio distribution and microstructure were revealed and a component with relative outer corner radius of 3.0 was obtained by warm hydroforming at 240℃. The minimum thickness of the formed square section was located in the transition position between the corner and the straight wall. The thinning ratio of the round corner increased with the increase of forming temperature. Fotmability of the magnesium tube was improved by raising temperature under the effect of dynamic recrystallization at 240℃.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China (No.20675009 and No. 90922023). The basis set aug-cc-pVDZ-PP for iodine atom is downloaded at the website http://bse.pnl.gov/ bse/portal.
文摘The theoretical calculation and spectroscopic experiments indicate a kind of triangular three bonding supramolecular complexes CBr4…X^-…-H-C, which consist of carbon tetrabromide, halide, and protic solvent molecule (referring to dichloromethane, chloroform and acetonitrile), can be formed in solution. The strength of halogen and hydrogen bonds in the triangular complexes using halide as common acceptor obeys the order of iodide〉bromide〉chloride. The halogen and hydrogen bonds work weak-cooperatively. Charge transfer bands of halogen bonding complexes between CBra and halide are observed in UV-Vis absorption spectroscopy in three solvents, and then the stoichiometry of 1:1, formation constants K and molar extinction coefficients ε of the halogen bonding complexes are obtained by Benesi-Hildebrand method. The K and ε show a dependence on the solvent dielectric constant and, on the whole, obey an order of iodide〉bromide〉chloride in the same solvents. Furthermore, the C-H vibrational frequencies of solvent molecules vary obviously with the addition of halide, which indicates the C-H…X- interaction. The experimental data indicate that the halogen bond and hydrogen bond coexist by sharing a common halide acceptor as predicted by calculation.
文摘For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchangensis "Caucasus" obtained using hybrid citrange of American origin _ C. Kinokuni X C.ichanglemon, which gives an eatable lemon with a chemical composition similar to the normal lemon fruit and without any damage it can resist frost at -16 ℃ temperature and b) spontaneous mutations of trifoliata: #1 and #2 which are distinguished among trifoliata species. Their fruits don't contain or contain a small amount of the substances that deteriorate the taste: naringin, porcine and so on. They are characterized by high index of frost resistance. In the experiment when obtaining sexual hybrids of the Washington naval orange the above mentioned components were used and hybrid seedlings were obtained, which are distinguished according to their phenotypic hereditary features. Selected seedlings represent the best initial material for a successful future work.
基金supported by the financial support of the National Natural Science Foundation of China (51171146 and 51101177)the Program for Key Science and Technology Innovative Research Team of Shaanxi Province (2013KCT-05)
文摘The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A1-AIN- 50SiB material (prepared by ball-milling powders) and AI- AIN-50SiM material (prepared by mixing powders) exhibited the semi-continuous Si structures and the isolated Si islands, respectively. Subsequently, the AI-AIN-50Si materials were selected as the model materials by phase identification and microstructure analysis. The dynamic microstructural evolu- tion of AI-AIN-50Si materials was investigated using the computational fluid dynamics (CFD) method. Mathematical models and simulation results showed that the in situ synthesis of AIN was strongly influenced by the structure and the flow- path ((Cg,N2/lg,N2)+(Cs,AlN/ls,AiN)). The flow paths of AI-AIN-50Si^B material were restricted by the semi-continuous Si. These Si structures can promote the formation of the strong turbulence with gradually weakened fluctuation, so that the in situ synthesis of AIN was interconnected and surrounded by an interpenetrating Si network. In contrast, the flow paths of AI- AIN-50Si^B material can easily pass through the isolated Si due to its mild turbulence with linear relationship. As a result, AIN was separated by the isolated Si and agglomerated in the matrix. Overall, the present work provides new insights into dynamic microstructural evolution in in situ reaction sinter- ing systems.