第六十二讲 漫谈汽车涂料的功能特性及组成机理

汽车涂料就是指涂装在汽车车身及零部件上的涂料,一般系指制造新车用的涂料及辅助材料和车辆修补用涂料。汽车作为户外交通工具,有其特殊的使用条件,另外,随着近年来汽车工业的飞速发展,汽车的生产量越来越大,这就使汽车的涂装工艺完全转向高速率和现代化的流水作业。根据汽车涂料的特性,论述了汽车涂料的功能,阐述了车用涂料的组成物质及按物质类型分类,分析了涂料流变性能的重要性及涂料的成膜机理,介绍了汽车修补漆的组成,研究了汽车涂料的命名和型号,同时指出了车用面漆涂料的分类及常见类型。

“沙琪玛骨架”绿化混凝土的研制试验

以水泥、建筑废料、大粒径碎石、营养土、有机肥等为原料,研制出一种能适合植物生长、排列较松、耐冲刷又具有一定强度的空间骨架绿化混凝土,将其形象地称为”沙琪玛骨架”绿化混凝土.主要对其组成机理、结构特点、营养土灌浆、抗压力学性能和草种建植等方面进行了研制与试验,从抗压应力-应变曲线的多峰值跳跃现象说明了粗骨料之间接触点的粘结强度是决定“沙琪玛骨架”绿化混凝土强度的关键;通过植草试验说明“沙琪玛骨架”对提高植物的耐践踏性等方面的优点,讨论了绿化混凝土的生态、经济和社会应用价值.

Preparation, formation mechanism and mechanical properties of multilayered TiO_2-organic nanocomposite film

Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in an acid aqueous solution. The chemical compositions, surface morphologies and mechanical properties of the films were investigated by X-ray photoelectron spectrometer(XPS), scanning electron microscopy(SEM) and nanoindentation depth-sensing technique, respectively. The results indicate that the major chemical compositions of the films are Ti and O. The principal mechanism for the nucleation and growth of the films is homogeneous nucleation, and the layer number of films has great influence on the surface morphology and roughness of the films. In addition, mechanical nanoindentation testing presents a significant increase in hardness and fracture toughness of titanium dioxide multilayered films compared with single-layer titanium dioxide thin film.

次氯酸钠发生器及在水处理中的应用研究进展

本论文介绍了次氯酸钠发生器的机理以及系统组成,在原有的生产工艺上总结得出了最佳的电解工艺参数,以其在消毒效果、安全性和经济性的突出优势,越来越在水处理中应用广泛,并对次氯酸钠发生系统朝着高浓度化、自动化和高效化以及在海水中应用方向发展作出展望。

Recent Advances in Colloidal Lubricant Detergents

Overbased lubricant detergents are important components in lubricating oil. Recently, a lot of papers about the synthesis mechanism, colloidal structure, acid neutralization and antifrictiorL properties of overbased detergents have been published with the development of experimental techniques, which can help us better understand the process of preparation and application of overbased detergents and propound new strategies for improving various performances of overbased detergents. In the future, the synthesis of environmentally friendly and multi-functional lubricant detergent using biodegradable vegetable oil instead of mineral oil as raw materials will be a primary objective for the colloidal lubricant detergent industry.This paper mainly presents the latest advances in the investigation of colloidal lubricant detergents.

The Effect of Kaolinite Structure Changes on Its Transformation Temperature of Phases

The relationship between kaolinite structure and the temperature of thermal transformation of phase was discussed in this paper through grinding and heating treatment. The results show that the structure of kaolinite is destroyed rapidly with mechanical grinding time, and the kaolinite structure collapses completely after 1 h grinding. The temperature of thermal transformation of phase of decreases with the destruction of kaolinite structure. This result has a great significance for the utilization of kaolinitic rocks in China coal measures.

Multimodality Treatment in Adult Patients with High-risk Soft-tissue Sarcomas

Objective： We enrolled retrospective data to determine the efficacy of combined chemotherapy and surgery for local tumour control and survival in patients with high-risk soft-tissue sarcomas. Methods： We collected data from 25 patients with high-risk soft-tissue sarcomas treated with four cycles of etoposide, ifosfamide and doxorubicin （EIA） followed by definitive surgery with or without postoperative radiotherapy and adjuvant chemotherapy. 21 patients received chemotherapy in a neoadjuvant/adjuvant clinical setting; eighteen of them completed adjuvant chemotherapy. Four patients received chemotherapy in an adjuvant setting only. Results： The objective response rate of neoadjuvant chemotherapy assessable in 21 patients was 43%. Including NED （n=7） and partial remissions （n=3）, the radiographic response rate was 47.6% with additional 42.9% stable diseases （n=9）. Surgery was performed in two patients before completing four neoadjuvant chemotherapy cycles because of disease progression. Median overall survival for all patients was 21.6＋ months. After completion of chemotherapy, in 62% of patients R0-resection could be performed. Conclusion： High proportion of R0-resections supports the idea of tumour down-staging after neoadjuvant treatment. Response to neoadjuvant chemotherapy is predictive for improved local tumour control resulting in long-term survival benefit.

Study on the Element Composition of Southern Celadon Porcelain and Coloring Mechanism

This paper mainly discusses the Si/Al molar ratio, RO/R2O molar ratio, Fe content, glazing and firing system on the thickness of Longquan Celadon pink coloring effects, and using a colorimeter, field emission scanning electron microscopy were used to analyze better experimental sample microstructure and color and so on. We explored the Longquan Celadon of pink coloration mechanism.

Study on the Element Composition of Southern Celadon Porcelain and Coloring Mechanism

This paper mainly discusses the Si/A1 molar ratio, RO/R20 molar ratio, Fe content, glazing and firing system on the thickness of Longquan Celadon pink coloring effects, and using a colorimeter, field emission scanning electron microscopy were used to analyze better experimental sample microstructure and color and so on. We explored the Longquan Celadon of pink coloration mechanism.

改性沥青混合料SMA的工程应用

通过对常用改性沥青混合料 SMA的性能介绍 ,对其材料特性、设计方法、施工及注意事项提出一些看法 。

Impact of structure and flow-path on in situ synthesis of AlN: Dynamic microstructural evolution of Al-AlN-Si materials

The AI-AIN-Si composites were prepared in the gas-in-liquid in situ synthesized flow-reaction-system, which was implemented by a powder metallurgy and reaction sin- tering route. The experimental results showed that A1-AIN- 50SiB material （prepared by ball-milling powders） and AI- AIN-50SiM material （prepared by mixing powders） exhibited the semi-continuous Si structures and the isolated Si islands, respectively. Subsequently, the AI-AIN-50Si materials were selected as the model materials by phase identification and microstructure analysis. The dynamic microstructural evolu- tion of AI-AIN-50Si materials was investigated using the computational fluid dynamics （CFD） method. Mathematical models and simulation results showed that the in situ synthesis of AIN was strongly influenced by the structure and the flow- path （（Cg,N2/lg,N2）＋（Cs,AlN/ls,AiN））. The flow paths of AI-AIN-50Si^B material were restricted by the semi-continuous Si. These Si structures can promote the formation of the strong turbulence with gradually weakened fluctuation, so that the in situ synthesis of AIN was interconnected and surrounded by an interpenetrating Si network. In contrast, the flow paths of AI- AIN-50Si^B material can easily pass through the isolated Si due to its mild turbulence with linear relationship. As a result, AIN was separated by the isolated Si and agglomerated in the matrix. Overall, the present work provides new insights into dynamic microstructural evolution in in situ reaction sinter- ing systems.

The formation of liquid bridge in different operating modes of AFM

The liquid bridge is one of the principal factors that cause artifacts in ambient-pressure atomic force microscope(AFM) images.Additionally, it is the main component of the adhesion force in ambient conditions. To understand the AFM imaging mechanism and the sample characteristics, it is essential to study the liquid bridge. This study interprets the physical mechanism involved in liquid bridge formation, which is composed of three different physical processes: the squeezing process, capillary condensation,and liquid film flow. We discuss the contributions of these three mechanisms to the volume and the capillary force of the liquid bridge in different AFM operation modes.