In this work,we describe a novel facile method to prepare long one-dimensional hybrid nanofibers by using hydrated bacterial cellulose nanofibers(BCF)as a template.Silver(Ag)nanoparticles with an average diameter of 1...In this work,we describe a novel facile method to prepare long one-dimensional hybrid nanofibers by using hydrated bacterial cellulose nanofibers(BCF)as a template.Silver(Ag)nanoparticles with an average diameter of 1.5 nm were well dispersed on BCF via a simple in situ chemical-reduction between AgNO3and NaBH4at a relatively low temperature.A growth mechanism is proposed that Ag nanoparticles are uniformly anchored onto BCF by coordination with BC-containing hydroxyl groups.The bare BCF and as-prepared Ag/BCF hybrid nanofibers were characterized by several techniques including transmission electron microscopy,X-ray diffraction,thermogravimetric analyses,and ultraviolet-visible(UV-Vis)absorption spectra.The antibacterial properties of Ag/BCF hybrid nanofibers against Escherichia coli(E.coli,Gram-negative)and Staphylococcu saureus(S.saureus,Gram-positive)bacteria were evaluated by using modified Kirby Bauer method and colony forming count method.The results show that Ag nanoparticles are well dispersed on BCF surface via in situ chemical-reduction.The Ag/BCF hybrid nanofiber presents strong antibacterial property and thus offers its candidature for use as functional antimicrobial agents.展开更多
The energy crisis and environmental pollution are serious challenges that humanity will face for the long-term. Despite tremendous efforts, the development of environmentally friendly methods to fabricate new energy m...The energy crisis and environmental pollution are serious challenges that humanity will face for the long-term. Despite tremendous efforts, the development of environmentally friendly methods to fabricate new energy materials is still challenging. Here we report, for the first time, a new strategy to fabricate various doped carbon nanofiber (CNF) aerogels by pyrolysis of bacterial cellulose (BC) pellicles which had adsorbed or were dyed with different toxic organic dyes. The proposed strategy makes it possible to remove the toxic dyes from waste-water and then synthesize doped CNF aerogels using the dyed BC pellicles as precursors. Compared with other reported processes for preparing heteroatom doped carbon (HDC) nanomaterials, the present synthetic method has some significant advantages, such as being green, general, low-cost and easily scalable. Moreover, the as-prepared doped CNF aerogels exhibit great potential as electrocatalysts for the oxygen reduction reaction (ORR) and as electrode materials for supercapacitors.展开更多
基金Supported by the National Natural Science Foundation of China(21206076) the Natural Science Foundation of Jiangsu Province(BK2012401 and BK2011715) National High Technology Research and Development Program of China(2011AA050701)
文摘In this work,we describe a novel facile method to prepare long one-dimensional hybrid nanofibers by using hydrated bacterial cellulose nanofibers(BCF)as a template.Silver(Ag)nanoparticles with an average diameter of 1.5 nm were well dispersed on BCF via a simple in situ chemical-reduction between AgNO3and NaBH4at a relatively low temperature.A growth mechanism is proposed that Ag nanoparticles are uniformly anchored onto BCF by coordination with BC-containing hydroxyl groups.The bare BCF and as-prepared Ag/BCF hybrid nanofibers were characterized by several techniques including transmission electron microscopy,X-ray diffraction,thermogravimetric analyses,and ultraviolet-visible(UV-Vis)absorption spectra.The antibacterial properties of Ag/BCF hybrid nanofibers against Escherichia coli(E.coli,Gram-negative)and Staphylococcu saureus(S.saureus,Gram-positive)bacteria were evaluated by using modified Kirby Bauer method and colony forming count method.The results show that Ag nanoparticles are well dispersed on BCF surface via in situ chemical-reduction.The Ag/BCF hybrid nanofiber presents strong antibacterial property and thus offers its candidature for use as functional antimicrobial agents.
基金This work is supported by the Ministry of Science and Technology of China (Grants 2010CB934700, 2013CB933900, 2014CB931800), the National Natural Science Foundation of China (Grants 21431006, 91022032, 91227103, 21061160492, J1030412), the Chinese Academy of Sciences (Grant KJZD-EW- M01-1), and Hainan Province Science and Technology Department (CXY20130046) for financial support. We thank Ms. C. Y. Zhong for kindly providing purified bacterial cellulose pellicles.
文摘The energy crisis and environmental pollution are serious challenges that humanity will face for the long-term. Despite tremendous efforts, the development of environmentally friendly methods to fabricate new energy materials is still challenging. Here we report, for the first time, a new strategy to fabricate various doped carbon nanofiber (CNF) aerogels by pyrolysis of bacterial cellulose (BC) pellicles which had adsorbed or were dyed with different toxic organic dyes. The proposed strategy makes it possible to remove the toxic dyes from waste-water and then synthesize doped CNF aerogels using the dyed BC pellicles as precursors. Compared with other reported processes for preparing heteroatom doped carbon (HDC) nanomaterials, the present synthetic method has some significant advantages, such as being green, general, low-cost and easily scalable. Moreover, the as-prepared doped CNF aerogels exhibit great potential as electrocatalysts for the oxygen reduction reaction (ORR) and as electrode materials for supercapacitors.