Mesoporous molecular series Ti-KIT-1 samples were prepared by three different post-handling methods using Ti(OEt)4 as the Ti source and KIT-1 as the support.The three post-synthetic methods were impregnated method,gra...Mesoporous molecular series Ti-KIT-1 samples were prepared by three different post-handling methods using Ti(OEt)4 as the Ti source and KIT-1 as the support.The three post-synthetic methods were impregnated method,grafting method and colloidal method.The Ti-KIT-1 samples were characterized by FT-IR,DRS,XRD,TG-DSC and physical adsorption-desorption of nitrogen.Experimental results showed that the Ti-KIT-1 samples remained the original mesoporous structure with a smaller specific BET surface area compared to the parent KIT-1 sieve.DRS and FT-IR indicate the existence of tetrahedral titanium(Ⅳ),TG-DSC and chemical analyse method proved that TiO2 weight percentage of grafting sample is much more than impregnated and colloidal samples.The grafting method is a good post-handling method that can effectively make use of a titanium source and promise the original mesoporous structure.展开更多
The textural features and acidic properties of sulfated mesoporous lanthana‐zirconia solid acids （SO42？/meso‐La0.1Zr0.9Oδ） were efficiently tuned by modifying the conditions used to prepare the meso‐La0.1Zr0.9O...The textural features and acidic properties of sulfated mesoporous lanthana‐zirconia solid acids （SO42？/meso‐La0.1Zr0.9Oδ） were efficiently tuned by modifying the conditions used to prepare the meso‐La0.1Zr0.9Oδcomposites, such as the molar ratio of the template to La and Zr metal ions （Nt/m）, molar ratio of ammonia to La and Zr metal ions （Na/m）, hydrothermal temperature （Thydro）, and hy‐drothermal time （thydro）. The effect of the textural features and acidic properties on the catalytic performance of solid acid catalysts for alkenylation of p‐xylene with phenylacetylene was investi‐gated. Various characterization techniques such as N2 physisorption, X‐ray diffraction, NH3 temper‐ature‐programmed desorption, and thermogravimetric analysis were employed to reveal the rela‐tionship between the nature of catalyst and its catalytic performance. It was found that the catalytic performance significantly depended on the textural features and acidic properties, which were strongly affected by preparation conditions of the meso‐La0.1Zr0.9Oδcomposite. Appropriate acidic sites and high accessibility were required to obtain satisfactory catalytic reactions for this reaction. It was also found that the average crystallite size of t‐ZrO2 affected by the preparation conditions had significant influence on the ultrastrong acidic sites of the catalysts. The optimized SO42？/meso‐La0.1Zr0.9Oδcatalyst exhibited much superior catalytic activity and coke‐resistant stabil‐ity. Moreover, the developed SO42？/meso‐La0.1Zr0.9Oδcatalyst demonstrated excellent catalytic per‐formance for alkenylation of diverse aromatics with phenylacetylene to their correspondingα‐arylstyrenes. Combining the previously established complete regeneration of used catalysts by a facile calcination process with the improved catalytic properties, the developed SO42？/meso‐La0.1Zr0.9Oδ solid acid could be a potential catalyst for industrial production ofα‐arylstyrenes through clean and atom efficient solid‐acid‐mediated Friedel‐Crafts alkenylation of diverse aromatics with phenylacetylene.展开更多
The influence of extrusion temperature on microstructure and mechanical properties of heterogeneous Mg−1Gd/Mg−13Gd laminate prepared by accumulated extrusion bonding was investigated.The results reveal that the Mg−1Gd...The influence of extrusion temperature on microstructure and mechanical properties of heterogeneous Mg−1Gd/Mg−13Gd laminate prepared by accumulated extrusion bonding was investigated.The results reveal that the Mg−1Gd/Mg−13Gd laminate forms a significant difference in grain size between the successive layers when extruded at 330℃,and this difference gradually disappears as the extrusion temperature increases from 380 to 430℃.Besides,the growth rate of recrystallized grains in fine-grained layers is faster than that in coarse-grained layers.Moreover,the diffusion ability of Gd element increases with elevating extrusion temperatures,promoting the increase and coarsening of precipitates in fine-grained layers.Tensile tests indicate that the sample extruded at 380℃ has a superior combination of strength and ductility.This is mainly attributed to the synergy of the heterogeneous texture between coarse and fine-grained layers,hetero-deformation induced strengthening and hardening.The fine-grained layers facilitate the activation of prismaticáañslips,while coarse-grained layers make it easier to active basaláañand pyramidalác+añslips,especially for the sample extruded at 380℃.The activation of pyramidalác+añslips contributes to coordinating further plastic deformation.展开更多
The tensile property of bi-axial warp knitted fabrics is tested and compared with that of the plain weave fabric. The results show that there are obvious differences between the tensile property of a bi-axial warp kni...The tensile property of bi-axial warp knitted fabrics is tested and compared with that of the plain weave fabric. The results show that there are obvious differences between the tensile property of a bi-axial warp knitted fabric and that of a plain weave fabric.The former can give fuller play to the property of a high modulus yarn than the latter. The tensile strength of a bi-axial warp knitted fabric is linear with the number of yarns in the direction of force.展开更多
文摘Mesoporous molecular series Ti-KIT-1 samples were prepared by three different post-handling methods using Ti(OEt)4 as the Ti source and KIT-1 as the support.The three post-synthetic methods were impregnated method,grafting method and colloidal method.The Ti-KIT-1 samples were characterized by FT-IR,DRS,XRD,TG-DSC and physical adsorption-desorption of nitrogen.Experimental results showed that the Ti-KIT-1 samples remained the original mesoporous structure with a smaller specific BET surface area compared to the parent KIT-1 sieve.DRS and FT-IR indicate the existence of tetrahedral titanium(Ⅳ),TG-DSC and chemical analyse method proved that TiO2 weight percentage of grafting sample is much more than impregnated and colloidal samples.The grafting method is a good post-handling method that can effectively make use of a titanium source and promise the original mesoporous structure.
基金financially supported by the National Natural Science Foundation of China (21276041)the Program for New Century Excellent Talents in University of Ministry of Education (NCET-12-0079)+1 种基金the Natural Science Foundation of Liaoning Province (2015020200)the Fundamental Research Funds for the Central Universities (DUT15LK41)~~
文摘The textural features and acidic properties of sulfated mesoporous lanthana‐zirconia solid acids （SO42？/meso‐La0.1Zr0.9Oδ） were efficiently tuned by modifying the conditions used to prepare the meso‐La0.1Zr0.9Oδcomposites, such as the molar ratio of the template to La and Zr metal ions （Nt/m）, molar ratio of ammonia to La and Zr metal ions （Na/m）, hydrothermal temperature （Thydro）, and hy‐drothermal time （thydro）. The effect of the textural features and acidic properties on the catalytic performance of solid acid catalysts for alkenylation of p‐xylene with phenylacetylene was investi‐gated. Various characterization techniques such as N2 physisorption, X‐ray diffraction, NH3 temper‐ature‐programmed desorption, and thermogravimetric analysis were employed to reveal the rela‐tionship between the nature of catalyst and its catalytic performance. It was found that the catalytic performance significantly depended on the textural features and acidic properties, which were strongly affected by preparation conditions of the meso‐La0.1Zr0.9Oδcomposite. Appropriate acidic sites and high accessibility were required to obtain satisfactory catalytic reactions for this reaction. It was also found that the average crystallite size of t‐ZrO2 affected by the preparation conditions had significant influence on the ultrastrong acidic sites of the catalysts. The optimized SO42？/meso‐La0.1Zr0.9Oδcatalyst exhibited much superior catalytic activity and coke‐resistant stabil‐ity. Moreover, the developed SO42？/meso‐La0.1Zr0.9Oδcatalyst demonstrated excellent catalytic per‐formance for alkenylation of diverse aromatics with phenylacetylene to their correspondingα‐arylstyrenes. Combining the previously established complete regeneration of used catalysts by a facile calcination process with the improved catalytic properties, the developed SO42？/meso‐La0.1Zr0.9Oδ solid acid could be a potential catalyst for industrial production ofα‐arylstyrenes through clean and atom efficient solid‐acid‐mediated Friedel‐Crafts alkenylation of diverse aromatics with phenylacetylene.
基金financially supported by the National Natural Science Foundation of China (Nos.52071035,U1764253)。
文摘The influence of extrusion temperature on microstructure and mechanical properties of heterogeneous Mg−1Gd/Mg−13Gd laminate prepared by accumulated extrusion bonding was investigated.The results reveal that the Mg−1Gd/Mg−13Gd laminate forms a significant difference in grain size between the successive layers when extruded at 330℃,and this difference gradually disappears as the extrusion temperature increases from 380 to 430℃.Besides,the growth rate of recrystallized grains in fine-grained layers is faster than that in coarse-grained layers.Moreover,the diffusion ability of Gd element increases with elevating extrusion temperatures,promoting the increase and coarsening of precipitates in fine-grained layers.Tensile tests indicate that the sample extruded at 380℃ has a superior combination of strength and ductility.This is mainly attributed to the synergy of the heterogeneous texture between coarse and fine-grained layers,hetero-deformation induced strengthening and hardening.The fine-grained layers facilitate the activation of prismaticáañslips,while coarse-grained layers make it easier to active basaláañand pyramidalác+añslips,especially for the sample extruded at 380℃.The activation of pyramidalác+añslips contributes to coordinating further plastic deformation.
文摘The tensile property of bi-axial warp knitted fabrics is tested and compared with that of the plain weave fabric. The results show that there are obvious differences between the tensile property of a bi-axial warp knitted fabric and that of a plain weave fabric.The former can give fuller play to the property of a high modulus yarn than the latter. The tensile strength of a bi-axial warp knitted fabric is linear with the number of yarns in the direction of force.
