The power consumption per unit GDP of China was 3 times higher than that of US and 5 times higher than that of Japan. This high energy consuming has prevented economy from developing at a constant high speed, and is a...The power consumption per unit GDP of China was 3 times higher than that of US and 5 times higher than that of Japan. This high energy consuming has prevented economy from developing at a constant high speed, and is also harmful to environ-ment. The p醦er analyzes the problems of high energy consumption and associate electric elasticity, and points out the way of rapid growth of economy by high energy consumption instead of high energy efficiency is the way of unsustainable.展开更多
The processes of nutrient depletion and soil degradation within smallholder farms of central Kenya are spatially heterogeneous, determined by both biophysical and socio-economic factors. A monitoring study involving n...The processes of nutrient depletion and soil degradation within smallholder farms of central Kenya are spatially heterogeneous, determined by both biophysical and socio-economic factors. A monitoring study involving nutrient stocks, flows and balances was conducted in central Kenya to explore between and within-farm variability in soil fertility management and identify spatial niches for targeting soil fertility management strategies. Focus group discussions were conducted and farms grouped into 3 farm types （rich, medium and poor）. Nine case-study farms - three from each of the farm types - were randomly selected from the 50 farms studied, for detailed resource flow mapping. The farms were visited to record movement of nutrients inputs using a monitoring protocol covering soil, crops, livestock, and socio-economic aspects of the farm. Soil in different plots were sampled at a depth of 0-20 cm and analyzed for texture, pH, C, N, available P, exchangeable K＋, Mg2＋ and Ca2＋. Results revealed that wealthy farmers added an average of 51.3 kg/ha N, 37 kg/ha P, and 244 kg/ha K, compared to 25.9 kg/ha N, 14.5 kg/ha P and 50.7 kg/ha K for the poor farmers. In all farm types, home fields received more nutrient inputs compared to the outfields. Consequently, maize grain yields, partial nutrient balances and soil nutrient stocks were significantly higher in wealthy farms and home fields compared to poor farms and outfields, respectively. These results imply that different soil management strategies are required to achieve similar yields on the different field and farm types and avert soil degradation.展开更多
For the geological disposal of high level radioactive wastes, an excavation damaged zone （EDZ） having high hydraulic conductivity resulting from the development of fractures in the rock adjacent to the tunnels will ...For the geological disposal of high level radioactive wastes, an excavation damaged zone （EDZ） having high hydraulic conductivity resulting from the development of fractures in the rock adjacent to the tunnels will be one of the potential pathways for radioactive contaminant transport. The potential pathways will be sealed by closure components, that is, a combination of tunnel plug, backfill and grout, the latter material being a clay-based mixture in consideration of the need for long-term stability of the seals. Clay-based grout is one of the effective candidate materials that can be used to interrupt the migration of radionuclides through an EDZ. Laboratory testing of clay-based grout using pulverized bentonite, with the objective of improvement in grout penetration into a rockmass, was conducted. The results showed that the pulverization of clay-based grout had a positive effect on filtration.展开更多
Single-atom catalysts(SACs)have emerged as one of the most competitive catalysts toward a variety of important electrochemical reactions,thanks to their maximum atom economy,unique electronic and geometric structures....Single-atom catalysts(SACs)have emerged as one of the most competitive catalysts toward a variety of important electrochemical reactions,thanks to their maximum atom economy,unique electronic and geometric structures.However,the role of SACs supports on the catalytic performance does not receive enough research attentions.Here,we report an efficient route for synthesis of single atom Zn loading on the N-doped carbon nano-onions(ZnN/CNO).ZnN/CNO catalysts show an excellent high selectivity for CO_(2) electro-reduction to CO with a Faradaic efficiency of CO(FECO)up to 97%at -0.47 V(vs.reversible hydrogen electrode,RHE)and remarkable durability without activity decay.To our knowledge,ZnN/CNO is the best activity for the Zn based catalysts up to now,and superior to single atom Zn loading on the two-dimensional planar and porous structure of graphene substrate,although the graphene with larger surface area.The exact role of such carbon nano-onions(CNO)support is studied systematically by coupling characterizations and electrochemistry with density functional theory(DFT)calculations,which have attributed such good performance to the increased curvature.Such increased curvature modifies the surface charge,which then changes the adsorption energies of key intermediates,and improves the selectivity for CO generation accordingly.展开更多
By probing into the relationship of senior students’demand for“internationalization”,students’expected economic returns in future careers,and their individual concept of modernity,this study attempts to explore se...By probing into the relationship of senior students’demand for“internationalization”,students’expected economic returns in future careers,and their individual concept of modernity,this study attempts to explore several factors that are influencing the demand for overseas higher education.展开更多
文摘The power consumption per unit GDP of China was 3 times higher than that of US and 5 times higher than that of Japan. This high energy consuming has prevented economy from developing at a constant high speed, and is also harmful to environ-ment. The p醦er analyzes the problems of high energy consumption and associate electric elasticity, and points out the way of rapid growth of economy by high energy consumption instead of high energy efficiency is the way of unsustainable.
文摘The processes of nutrient depletion and soil degradation within smallholder farms of central Kenya are spatially heterogeneous, determined by both biophysical and socio-economic factors. A monitoring study involving nutrient stocks, flows and balances was conducted in central Kenya to explore between and within-farm variability in soil fertility management and identify spatial niches for targeting soil fertility management strategies. Focus group discussions were conducted and farms grouped into 3 farm types （rich, medium and poor）. Nine case-study farms - three from each of the farm types - were randomly selected from the 50 farms studied, for detailed resource flow mapping. The farms were visited to record movement of nutrients inputs using a monitoring protocol covering soil, crops, livestock, and socio-economic aspects of the farm. Soil in different plots were sampled at a depth of 0-20 cm and analyzed for texture, pH, C, N, available P, exchangeable K＋, Mg2＋ and Ca2＋. Results revealed that wealthy farmers added an average of 51.3 kg/ha N, 37 kg/ha P, and 244 kg/ha K, compared to 25.9 kg/ha N, 14.5 kg/ha P and 50.7 kg/ha K for the poor farmers. In all farm types, home fields received more nutrient inputs compared to the outfields. Consequently, maize grain yields, partial nutrient balances and soil nutrient stocks were significantly higher in wealthy farms and home fields compared to poor farms and outfields, respectively. These results imply that different soil management strategies are required to achieve similar yields on the different field and farm types and avert soil degradation.
文摘For the geological disposal of high level radioactive wastes, an excavation damaged zone （EDZ） having high hydraulic conductivity resulting from the development of fractures in the rock adjacent to the tunnels will be one of the potential pathways for radioactive contaminant transport. The potential pathways will be sealed by closure components, that is, a combination of tunnel plug, backfill and grout, the latter material being a clay-based mixture in consideration of the need for long-term stability of the seals. Clay-based grout is one of the effective candidate materials that can be used to interrupt the migration of radionuclides through an EDZ. Laboratory testing of clay-based grout using pulverized bentonite, with the objective of improvement in grout penetration into a rockmass, was conducted. The results showed that the pulverization of clay-based grout had a positive effect on filtration.
基金This work was supported by the National Key R&D Program of China(2020YFA0710404)the Beijing Natural Science Foundation(2182077)the National Natural Science Foundation of China(21477136,51972281,and 21703250).
文摘Single-atom catalysts(SACs)have emerged as one of the most competitive catalysts toward a variety of important electrochemical reactions,thanks to their maximum atom economy,unique electronic and geometric structures.However,the role of SACs supports on the catalytic performance does not receive enough research attentions.Here,we report an efficient route for synthesis of single atom Zn loading on the N-doped carbon nano-onions(ZnN/CNO).ZnN/CNO catalysts show an excellent high selectivity for CO_(2) electro-reduction to CO with a Faradaic efficiency of CO(FECO)up to 97%at -0.47 V(vs.reversible hydrogen electrode,RHE)and remarkable durability without activity decay.To our knowledge,ZnN/CNO is the best activity for the Zn based catalysts up to now,and superior to single atom Zn loading on the two-dimensional planar and porous structure of graphene substrate,although the graphene with larger surface area.The exact role of such carbon nano-onions(CNO)support is studied systematically by coupling characterizations and electrochemistry with density functional theory(DFT)calculations,which have attributed such good performance to the increased curvature.Such increased curvature modifies the surface charge,which then changes the adsorption energies of key intermediates,and improves the selectivity for CO generation accordingly.
基金The authors are grateful to the Study of Demand for Higher Education with Reference to Educational Finance in HK and China’s Mainland.(ARGC Funded Research Project,2003-2004).
文摘By probing into the relationship of senior students’demand for“internationalization”,students’expected economic returns in future careers,and their individual concept of modernity,this study attempts to explore several factors that are influencing the demand for overseas higher education.
