The adsorption and mechanism of Re(Ⅶ)on resin D318 were studied using chemical methods and IR spectrometry.At pH 5.2,the static and dynamic saturation adsorption capacities were 351.4 and 366.5 mg·g-1,respective...The adsorption and mechanism of Re(Ⅶ)on resin D318 were studied using chemical methods and IR spectrometry.At pH 5.2,the static and dynamic saturation adsorption capacities were 351.4 and 366.5 mg·g-1,respectively.The adsorption behavior obeyed the Freundlich empirical equation and the adsorption rate constant k298 was 6.37×10-4s-1.The desorption percentage was up to 99.7%when 2.0 mol·L-1KSCN was used for dynamic desorption.展开更多
The model developed in this research presents effective mechanisms in simulations of a discharge strip understood between the minimum and the maximum allowable values, aiming to determine the relationship between disc...The model developed in this research presents effective mechanisms in simulations of a discharge strip understood between the minimum and the maximum allowable values, aiming to determine the relationship between discharge and water application efficiency, deep percolation and runoff rates, and consequently to optimize the performance of the furrow irrigation systems with continuous flow. The flow applied in each furrow must be adapted to the length, to the field slope and to the nature of the ground. The authors studied the maximum non erosive flow （Q,,,~）, in function of parameters obtained from the dimensions of the furrow, being Pl and/92, respectively, the linear and exponential parameters of the potential functions that described the relationship between the area of the cross section of flow （or wetted perimeter） and height of flow; in this way, the multiplicative effect of,01 on the area of the cross section of flow is linear, while ,02 is exponential. It verified a conjugated effect of,or and p20n the value of Q,,~. The results of this research point out for the importance of having an estimate of the parameters of the geometry of the cross section of flow （,01 and ,02） the most precise as possible, being known that the dimensions of this section can result in impracticable values of Qmax, outside of the acceptable strip in the literature, that is from 1.2 to 4.0 L.sl. This sensibility analysis was also of great benefit to create an interface in the software SASIS, capable to guide the user of this tool in the input of appropriate values for ,01 and P2 to the process of simulation of the irrigation for furrow with continuous flow and of the optimization of its performance.展开更多
The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the intera...The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the interaction between two perpendicular π-systems of various oligothiophene substituted spirofluorenes is conducted. The results demonstrate that the interaction be- tween two perpendicular branches is reduced by oligothiophene substitutions. Photoexcitation induced relaxation is mainly located on one of the equivalent branches or the branch with longer conjugation length. In addition to these benefits brought by 9,9-spirobifluorene center, the specific oligothiophene moieties linked to the spirt center also have properties of significant merit, such as the ability to tune energy levels and emission colors by controlling the conjugation length.展开更多
基金Supported by the National Natural Science Foundation of China （30972405） and the Natural Science Foundation of Zhejiang Province （Y3090531）.
文摘The adsorption and mechanism of Re(Ⅶ)on resin D318 were studied using chemical methods and IR spectrometry.At pH 5.2,the static and dynamic saturation adsorption capacities were 351.4 and 366.5 mg·g-1,respectively.The adsorption behavior obeyed the Freundlich empirical equation and the adsorption rate constant k298 was 6.37×10-4s-1.The desorption percentage was up to 99.7%when 2.0 mol·L-1KSCN was used for dynamic desorption.
文摘The model developed in this research presents effective mechanisms in simulations of a discharge strip understood between the minimum and the maximum allowable values, aiming to determine the relationship between discharge and water application efficiency, deep percolation and runoff rates, and consequently to optimize the performance of the furrow irrigation systems with continuous flow. The flow applied in each furrow must be adapted to the length, to the field slope and to the nature of the ground. The authors studied the maximum non erosive flow （Q,,,~）, in function of parameters obtained from the dimensions of the furrow, being Pl and/92, respectively, the linear and exponential parameters of the potential functions that described the relationship between the area of the cross section of flow （or wetted perimeter） and height of flow; in this way, the multiplicative effect of,01 on the area of the cross section of flow is linear, while ,02 is exponential. It verified a conjugated effect of,or and p20n the value of Q,,~. The results of this research point out for the importance of having an estimate of the parameters of the geometry of the cross section of flow （,01 and ,02） the most precise as possible, being known that the dimensions of this section can result in impracticable values of Qmax, outside of the acceptable strip in the literature, that is from 1.2 to 4.0 L.sl. This sensibility analysis was also of great benefit to create an interface in the software SASIS, capable to guide the user of this tool in the input of appropriate values for ,01 and P2 to the process of simulation of the irrigation for furrow with continuous flow and of the optimization of its performance.
基金financially supported by the National Basic Research Program of China (Grant No. 2009CB930601)the National Natural Science Foundation of China (Grant Nos. 20804020, 60976019, 50903028 and 20974046)+2 种基金the Program for New Century Excellent Talents in University (Grant No. NCET-07-0446)the Scientific and Technological Innovation Teams of Colleges and Universities in Jiangsu Province (Grant No. TJ207035)the Scientific Research Foundation of Nanjing University of Posts and Telecommunications (Grant No. NY210017)
文摘The electronic structures and optical properties of oligothiophene substituted spirofluorenes are investigated theoretically with semi-empirical quantum chemical calculations. A theoretical investigation of the interaction between two perpendicular π-systems of various oligothiophene substituted spirofluorenes is conducted. The results demonstrate that the interaction be- tween two perpendicular branches is reduced by oligothiophene substitutions. Photoexcitation induced relaxation is mainly located on one of the equivalent branches or the branch with longer conjugation length. In addition to these benefits brought by 9,9-spirobifluorene center, the specific oligothiophene moieties linked to the spirt center also have properties of significant merit, such as the ability to tune energy levels and emission colors by controlling the conjugation length.
