自结合层材料在热喷涂中的应用与比较

介绍了3种具有自结合特性的金属喷涂丝材,它们作为结合底层材料,制备的涂层可以大幅度提高工作涂层与基体的结合强度。通过对比,认为F75(Ni/Al)合金合金丝在3种丝材中喷涂成本低,结合强度高,可以作为提高涂层与基体结合强度的首选材料。

几种自结合层材料在热喷涂中的应用

自结合层又称粘接层或打底层,在经净化和粗化处理后的工件有效面上先喷涂一层具有自结合性能的金属、合金或复合材料,以提高涂层与基体的结合性能或增加其功能特性。在进行粗化处理的基体上喷涂普通材料。

热障涂层在内燃机中的应用

随着热能发动机向高温高效方向发展,在其燃烧系统中工作的许多零部件将经受更严酷的高温。高应力、热冲击、燃气腐蚀和粒子冲蚀作用。这就对发动机材料性能提出了更高的要求。陶瓷材料由于具有耐腐、耐氧化、耐高温、高硬度和较低的摩擦系数等特性而受到广泛的重视。然而。

Fabrication and ablation property of carbon/carbon composites with novel SiC-ZrB_2 coating

A novel SiC?ZrB2 coating was prepared using a two-step technique by slurry-sintering and chemical vapor reaction on carbon/carbon (C/C) composites. The SiC?ZrB2 coating was composed of the scattered ZrB2 phase and the continuous SiC phase. It was observed that a good adhesion was built between the coating and the C/C composites. The SiC?ZrB2 coating samples exhibited a better ablation resistance in comparison with the uncoated C/C composites. The SiO2?ZrO2 barrier layer, the heat dissipation of the gaseous products and the pinning effect of ZrO2 all contributed to the good ablation resistance of the SiC?ZrB2 coated composites.

Microstructures,mechanical and oxidation behaviors of C/C composites modified by NiAl alloy

Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning electron microscopy. The fracture behavior, infiltration and oxidation mechanism were further discussed. The results indicated that NiAl alloy exhibited good wettability on the C/C preform because a TiC reaction layer formed at the interface. Multi-layer（PyC/TiC/NiAl＋TiC） coating evenly and compactly distributed on the surface of the carbon fiber in tubular form. The penetration depth of molten NiAl alloys depended on the reaction between the PyC and titanium. The impact fracture was inclined to along the interface between the NiAl permeability layer and C/C matrix. Al_2TiO_5 and TiO_2 formed on the surface, while the interior multi-layer tubular structure partially remained after oxidation at 1773 K for 30 min.

材料设计参数对双层多孔路面吸声性能影响

为提升双层多孔路面吸声性能,增强对轮胎与路面接触源头噪声的消减效果,给路面降噪功能优化设计提供依据,分析层间结合材料用量、底面层空隙率对双层多孔路面吸声性能的影响规律。采用表面声学阻抗试验获取混合料吸声系数曲线,对比不同层间结合材料用量、底面层空隙率对双层多孔路面吸声系数峰值和峰值频率的影响,并采用层间剪切、拉拔强度试验分析层间黏结性能。基于层间材料用量和底面层空隙率优化,提出一种采用聚氨酯表面层与改性沥青混合料底面层复合的双层多孔路面结构,通过室内试验分析复合路面材料的基本力学特性和吸声性能。研究结果表明:增加层间改性乳化沥青材料用量能够提升层间黏结强度,但会损失双层多孔路面的吸声效果,主要吸声频谱也会受到影响;提高底面层空隙率能够提升双层多孔路面的吸声性能,特别是对于高频噪声的吸收;而当底面层空隙率小于20%时,吸声系数峰值衰减较快。在聚氨酯材料提供足够黏结强度和表面层力学性能的条件下,复合型路面未采用层间结合材料,并提高了底面层空隙率,因此呈现出显著的高、低频吸声效果。为保持双层多孔沥青路面吸声性能和黏结强度的均衡,底面层空隙率不宜低于20%,在保障足够有效吸声功能基础上,宜使用较高的层间结合材料用量。采用复合式双层多孔路面可以同步提高表面层和底面层的空隙率,从而增强吸声性能,具有更为突出的材料力学特性。

Design and characterization of Ti6Al4V/20CoCrMo−highly porous Ti6Al4V biomedical bilayer processed by powder metallurgy

The aim of this work was to develop a Ti6Al4V/20CoCrMo−highly porous Ti6Al4V bilayer for biomedical applications.Conventional powder metallurgy technique,with semi-solid state sintering as consolidation step,was employed to fabricate samples with a compact top layer and a porous bottom layer to better mimic natural bone.The densification behavior of the bilayer specimen was studied by dilatometry and the resulting microstructure was observed by scan electron microscopy(SEM)and computed microtomography(CMT),while the mechanical properties and corrosion resistance were evaluated by compression and potentiodynamic tests,respectively.The results indicate that bilayer samples without cracks were obtained at the interface which has no negative impact on the densification.Permeability values of the highly porous layer were in the lower range of those of human bones.The compression behavior is dictated by the highly porous Ti6Al4V layer.Additionally,the corrosion resistance of Ti6Al4V/20CoCrMo is better than that of Ti6Al4V,which improves the performance of the bilayer sample.This work provides an insight into the important aspects of a bilayer fabrication by powder metallurgy and properties of Ti6Al4V/20CoCrMo−highly porous Ti6Al4V structure,which can potentially benefit the production of customized implants with improved wear performance and increased in vivo lifetime.

Bonding interface zone of Mg-Gd-Y/Mg-Zn-Gd laminated composite fabricated by equal channel angular extrusion

In order to improve the mechanical properties and corrosion resistance of Mg alloys,the equal channel angular extrusion (ECAE)was employed to fabricate the Mg-5Gd-5Y/Mg-2Zn-1Gd(GW55/ZG21)laminated composites.After fabrication and annealing treatment,the microstructural evolution,phase constitution,microhardness,and bonding strength were investigated on the bonding interface zone of GW55/ZG21 laminated composites.The bonding interface zone of GW55/ZG21 laminated composites comprises a lot of Mg3(Y,Gd)2Zn3 particles along the bonding interface,some rod Mg24(Y,Gd)5 phases on GW55 side,and a precipitation free zone(PFZ)on ZG21 side.After annealing treatment,Mg3(Y,Gd)2Zn3 particles along the bonding interface increase, rod Mg24(Y,Gd)5 phases on GW55 side decrease,and PFZ is broadened.Meanwhile,the hardness on the bonding interface zone decreases and the bonding strength increases from 126 MPa to 162 MPa.

Modifying element diffusion pathway by transition layer structure in high-entropy alloy particle reinforced Cu matrix composites

The Al0.3CoCrFeNi high-entropy alloy(HEA)particles reinforced Cu matrix composites(CMCs)were fabricated by mechanical alloying and sintering.Transition layer structure was obtained by multi-step ball milling to investigate the related influence on element diffusion behavior and wear properties of CMCs.The results indicate that a new Cu transition layer is generated,and the thickness is about 5μm.Cr element diffuses into the interface via the transition layer,which forms the complex oxide.Because of the structure of Cu transition layer,the diffusion rates of Ni,Co and Fe increase,especially the Ni element.The wear resistance of CMCs is improved by 30%,which is due to the improvement of interface bonding strength,compared with the CMCs without transition layer.This method is applicable to the development of advanced HEA reinforced metallic matrix composites.

Microstructures and properties of Cu/Ag(Invar) composites fabricated by powder metallurgy

The Ag(Invar)composite powder prepared by ball milling was used to fabricate the Cu/Ag(Invar)composites.Microstructures and properties of the composites were studied after sintering and thermo-mechanical treatment.The results indicatethat during ball milling,micro-forging weld and work-hardening fracture result in that the average particle size of the Ag(Invar)powder increases rapidly at first,and then decreases sharply,finally tends to be constant.Compared with the Cu/Invar ones,thesinterability of the composites is greatly improved,resulting in that the pores in them are smaller in amount and size.After thethermo-mechanical treatment,the Cu/Ag(Invar)composites are nearly fully dense with the optimum phase composition and elementdistribution.More importantly,Cu and the Invar alloy in the composites distribute continuously in a three-dimensional(3D)networkstructure.Cu/Invar interface diffusion is effectively inhibited by the Ag barrier layer,leading to a great improvement of themechanical and thermal properties of the Cu/Ag(Invar)composites.

The interfacial fracture behavior of foam core composite sandwich structures by a viscoelastic cohesive model

A sandwich beam model consisting of two face sheets and a foam core bonded by a viscoelastic adhesive layer is considered in order to investigate interfacial fracture behavior. Firstly, a cohesive zone model in conjunction with a Maxwell element in parallel, or with a Kelvin element in series, respectively, is employed to describe the characteristics of viscoelasticity for the adhesive layer. The models can be implemented into the implicit finite element code. Next, the parametric study shows that the in- fluences of loading rates on the cohesive zone energy and strength are quite different for different models. Finally, a sandwich double cantilever beam model is adopted to simulate the interface crack growth between the face sheet and core. Numerical examples are presented for various loading rates to demonstrate the efficacy of the rate-dependent cohesive models.

Magnetoelectric cylindrical layered composite structure with multi-resonance frequencies

A combined ME composite structure is made of several cylindrical layered composites in series or parallel connection.Due to the cylindrical structure,the combined structure does not need more space.The characteristics of multi-resonance frequencies have been studied.Each resonance frequency of the structure can be adjusted by changing the cylinder diameter of the corresponding cylindrical layered composites.The number of resonance frequencies increases as the number of cylindrical layered composites increases.The multi-resonance frequencies behavior makes these cylindrical layered composite structures suitable for applications in multifuctional devices with multi-frequencies operation.

Optical bistability based on surface plasmon coupled between a noble metal film and a metal grating involving Kerr materials

A phenomenon about optical bistability is successfully investigated in a layered structure consisting of a silver film with Kerr medium and a silver grating sandwiched between semi-infinite linear dielectrics.This type of structure can lead to the optical bistability phenomena occurring in reflection and transmission.There exists an optimal thickness of the metal grating that can cut off the effect of the near-field enhancement and may have the lowest effect on conversion from surface plasmon to light.This structure can realize the functions of the beam splitter and the polarization splitter and will be essential for future classical and quantum information processing.