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聚烯烃结晶成核剂的研究进展 被引量:18
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作者 蒋海斌 张晓红 乔金樑 《石油化工》 CAS CSCD 北大核心 2011年第10期1027-1036,共10页
概述了聚丙烯成核剂和聚乙烯成核剂的发展概况,包括有机成核剂、无机成核剂和高分子成核剂,其中,以有机成核剂为主;介绍了聚丙烯α晶型成核剂和β晶型成核剂成核机理的研究进展以及结晶动力学的研究进展;分析了聚烯烃成核剂的发展方向,... 概述了聚丙烯成核剂和聚乙烯成核剂的发展概况,包括有机成核剂、无机成核剂和高分子成核剂,其中,以有机成核剂为主;介绍了聚丙烯α晶型成核剂和β晶型成核剂成核机理的研究进展以及结晶动力学的研究进展;分析了聚烯烃成核剂的发展方向,认为超细或纳米尺度成核剂、原位成核技术以及利用超细粉末橡胶提高成核效率是聚烯烃成核剂的重要发展方向。 展开更多
关键词 聚烯烃 聚丙烯 聚乙烯 成核剂 结品
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线形聚丙烯/低密度聚乙烯发泡体系的结晶行为研究 被引量:6
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作者 刘伟 刘本刚 +2 位作者 王向东 许国志 张玉霞 《中国塑料》 CAS CSCD 北大核心 2010年第12期63-71,共9页
通过差示扫描量热仪研究了不同比例线形聚丙烯(PP)/低密度聚乙烯(PE-LD)共混发泡体系的结晶熔融行为和非等温结晶动力学,并使用热台偏光显微镜对线形PP/PE-LD共混发泡体系的结晶形态进行了表征。结果表明,PE-LD的加入会降低线形PP的结... 通过差示扫描量热仪研究了不同比例线形聚丙烯(PP)/低密度聚乙烯(PE-LD)共混发泡体系的结晶熔融行为和非等温结晶动力学,并使用热台偏光显微镜对线形PP/PE-LD共混发泡体系的结晶形态进行了表征。结果表明,PE-LD的加入会降低线形PP的结晶峰温和绝对结晶度,但对其熔融行为影响不显著;而通过非等温结晶动力学研究表明,PE-LD支链的成核作用,改变线形PP结晶过程中的成核和增长方式能够增加球晶数的同时降低球晶半径,形成的晶核具有物理交联点作用,有效地提高了共混物的熔体强度,增加了共混体系的可发性。 展开更多
关键词 线形聚丙烯 低密度聚乙烯 发泡 结品行为 晶动力学
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聚丙烯/多壁碳纳米管复合材料的结晶行为 被引量:10
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作者 李宏伟 高绪珊 童俨 《中国塑料》 CAS CSCD 北大核心 2005年第4期23-28,共6页
用溶液絮凝法制备了碳纳米管含量为0.5%~5%的聚丙烯(PP)/多壁碳纳米管(MWNT)复合材料。SEM研究表明MWNT在复合材料中呈纳米级分散。用DSC法研究了MWNT含量对PP非等温结晶性能的影响,发现MWNT作为PP的成核剂,使PP的结晶峰温向高温方向移... 用溶液絮凝法制备了碳纳米管含量为0.5%~5%的聚丙烯(PP)/多壁碳纳米管(MWNT)复合材料。SEM研究表明MWNT在复合材料中呈纳米级分散。用DSC法研究了MWNT含量对PP非等温结晶性能的影响,发现MWNT作为PP的成核剂,使PP的结晶峰温向高温方向移动;由于MWNT对PP链段运动的阻碍作用,非等温结晶峰温并不随MWNT含量增加而增加;复合材料的结晶总速率均比纯PP大,但在碳纳米管含量0.5%~5%范围内随MWNT含量增加总速率反而降低;MWNT的加入对材料的结晶度影响不大,复合材料中PP的结晶晶型没有改变。当MWNT含量为0.5%时,观察到PP的球晶尺寸降低。 展开更多
关键词 复合材料 结品行为 碳纳米管 聚内烯
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成核剂CDBS和纳米碳酸钙对聚丙烯结晶行为和力学性能的影响 被引量:2
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作者 黄毅萍 张炎 +2 位作者 陈雷 陈烨 陈广美 《应用化学》 CAS CSCD 北大核心 2008年第1期67-72,共6页
研究了聚丙烯(PP)中同时加入成核剂1,3;2,4-对氯二苄叉山梨糖醇(CDBS)和纳米碳酸钙(nm-CaCO3)后的等温结晶和非等温结晶过程的结果表明,加入纳米碳酸钙可有效提高PP的结晶温度和结晶速度,对结晶度没有明显的影响。成核剂的加入,使PP的... 研究了聚丙烯(PP)中同时加入成核剂1,3;2,4-对氯二苄叉山梨糖醇(CDBS)和纳米碳酸钙(nm-CaCO3)后的等温结晶和非等温结晶过程的结果表明,加入纳米碳酸钙可有效提高PP的结晶温度和结晶速度,对结晶度没有明显的影响。成核剂的加入,使PP的结晶温度提高了约20℃,结晶速度明显加快,结晶度明显提高(达38%)。XRD和PLM观察表明,PP中加入成核剂后,成核密度增加十分显著,晶型没有明显变化,只是α晶型的晶面生长出现择优取向。加入成核剂的PP雾度由56%降低到12%,成核剂CDBS对PP具有很好的增透效果。力学性能测试显示,纳米碳酸钙和成核剂的加入使PP的抗冲击强度从33 J/m增加到约44 J/m,但CDBS的加入使PP的断裂伸长率由153%降低至127%。 展开更多
关键词 聚丙烯 成核剂对氯二苄叉山梨糖醇 纳米碳酸钙 结品行为 雾度 力学性能
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聚乳酸/可反应性纳米SiO_2复合材料的等温结晶动力学 被引量:2
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作者 郭有钢 张予东 +1 位作者 徐翔民 张普玉 《中国塑料》 CAS CSCD 北大核心 2010年第12期30-35,共6页
采用熔融共混法制备了聚乳酸/可反应性纳米二氧化硅(PLLA/RNS)复合材料。利用差示扫描量热仪研究了RNS对PLLA等温结晶行为的影响;用Avrami方程研究了PLLA及其复合材料的等温结晶动力学。结果表明,加入RNS对PLLA结晶起到了异相成核作用,... 采用熔融共混法制备了聚乳酸/可反应性纳米二氧化硅(PLLA/RNS)复合材料。利用差示扫描量热仪研究了RNS对PLLA等温结晶行为的影响;用Avrami方程研究了PLLA及其复合材料的等温结晶动力学。结果表明,加入RNS对PLLA结晶起到了异相成核作用,随着RNS含量的增加,PLLA的结晶速率(K)提高,半结晶时间(t1/2)减小,而Avrami指数(n)变化不大,说明RNS没有改变PLLA结晶的成核机理;利用Arrhenius方程和Lauritzen-Hoffman理论分别对PLLS及其复合材料的结晶活化能(ΔE)、成核参数(Kg)和折叠链端表面自由能(eσ)进行计算后发现复合材料的ΔE比纯PLLA的小,Kg、eσ略有增加。这表明加入RNS降低了复合材料的ΔE,从而有效地促进了PLLA基体的结晶。 展开更多
关键词 聚乳酸 纳米二氧化硅 等温结品动力学 复合材料
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304不锈钢热变形过程奥氏体动态再结晶及流变应力研究 被引量:10
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作者 熊家强 谢刚 唐广波 《云南冶金》 2008年第5期37-42,共6页
住800~1200℃温度范同和0.5~10s^-1应变速率条件下对304不锈钢进行单道次热压缩实验,结合显做组织分析,研究了304不锈钢的热变形过程中奥氏体动态再结品规律及流变应力。确定了该材料的动态再结晶参数、热变形方程。根据变形条件... 住800~1200℃温度范同和0.5~10s^-1应变速率条件下对304不锈钢进行单道次热压缩实验,结合显做组织分析,研究了304不锈钢的热变形过程中奥氏体动态再结品规律及流变应力。确定了该材料的动态再结晶参数、热变形方程。根据变形条件和流变应力曲线形式将热变形过程流变应力曲线分成3种类型,分别回归得到了它们的表达式。 展开更多
关键词 304不锈钢 热变形 动态再结品 流变应力
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理想薄板坯连铸结晶器内腔宽面部分曲面的获得 被引量:2
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作者 韩精华 武建琦 +5 位作者 张瑞忠 刘耀辉 李军 魏鹏义 周英超 魏祖康 《重型机械》 2005年第5期35-38,共4页
薄板坯连铸机结晶器内腔宽面通常由若干简单几何曲面拼接而成,使铸坯坯壳在结晶器内自上而下移动过程中承受较大的非均匀变形,从而在铸坯坯壳内产生“弯”、“扭”、“剪”应力。理想的薄板坯连铸机结晶器内腔宽面应该具有三个几何特征... 薄板坯连铸机结晶器内腔宽面通常由若干简单几何曲面拼接而成,使铸坯坯壳在结晶器内自上而下移动过程中承受较大的非均匀变形,从而在铸坯坯壳内产生“弯”、“扭”、“剪”应力。理想的薄板坯连铸机结晶器内腔宽面应该具有三个几何特征,即满足薄板坯连铸基本生产工艺几何尺寸和形状要求;曲率连续、曲率变化率最小;考虑铸坯坯壳受到冷却作用而凝固收缩的影响因素。本文详述了邯钢理想薄板坯结晶器内腔宽面部分曲面的获取过程。 展开更多
关键词 结品 宽面 曲面
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空间立体结构对芳香聚酰胺及其嵌段共聚物结晶行为的影响
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作者 张艺 程开良 +2 位作者 郑毅敏 张全灵 许家瑞 《中山大学学报(自然科学版)》 CAS CSCD 北大核心 2004年第5期47-50,54,共5页
采用高温溶液直接缩聚一步法和两步法分别合成了含全对位结构和含间位结构芳香聚酰胺预聚物及其脂肪聚酰胺-芳香聚酰胺-脂肪聚酰胺嵌段共聚物。采用差示扫描量热法(DSC)和广角X射线衍射法(WAXD)对所设计合成的不同空间立体结构的芳香聚... 采用高温溶液直接缩聚一步法和两步法分别合成了含全对位结构和含间位结构芳香聚酰胺预聚物及其脂肪聚酰胺-芳香聚酰胺-脂肪聚酰胺嵌段共聚物。采用差示扫描量热法(DSC)和广角X射线衍射法(WAXD)对所设计合成的不同空间立体结构的芳香聚酰胺及其与较低相对分子质量尼龙6的嵌段共聚物的结晶行为与结晶结构进行研究。结果表明,空间立体结构的变化显著影响预聚物和共聚物的结晶形态及结晶熔融行为,间位结构的引入使硬链段对软链段熔融结晶行为的影响更为深刻,结晶结构更为松散,晶粒尺寸增大,更有利于增强软硬分子间的相互作用从而抑制硬链段分子链本身的自聚集倾向。 展开更多
关键词 空间立体 芳香聚酰胺 嵌段共聚物 结品熔融行为
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镍基耐蚀材料结晶裂纹的研究综述
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作者 范瑞君 胡晓琦 《一重技术》 2010年第4期21-23,共3页
总结了解研究焊接结晶裂纹的几种主要试验方法,并简述了影响其焊接结晶裂纹的主要元素。
关键词 镍基耐蚀材料 结品裂纹 试验办法 影响因素
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CSP低碳钢薄板组织演变及强化机理研究 被引量:53
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作者 康永林 于浩 +5 位作者 王克鲁 傅杰 柳得橹 王中丙 毛新平 陈贵江 《钢铁》 CAS CSCD 北大核心 2003年第8期20-26,共7页
 通过热力学计算和析出物形貌观察表明,析出物对铸坯晶粒的生长起到一定的限制作用。6道次连轧模拟计算结果与观察结果吻合较好,同时也表明,再结晶是组织细化的主要原因。各种强化方式定量计算的结果表明,细晶强化是主要的强化方式,沉...  通过热力学计算和析出物形貌观察表明,析出物对铸坯晶粒的生长起到一定的限制作用。6道次连轧模拟计算结果与观察结果吻合较好,同时也表明,再结晶是组织细化的主要原因。各种强化方式定量计算的结果表明,细晶强化是主要的强化方式,沉淀强化和位错强化次之,且它们对屈服强度的贡献相近。 展开更多
关键词 薄板坯连铸连轧 CSP工艺 低碳钢 薄板 组织演变 强化机理 组织细化 结品 析出
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尼龙6/粘土纳米复合材料的性能研究进展 被引量:1
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作者 王玉花 程超 《广东化工》 CAS 2007年第9期36-38,共3页
粘土是一种层状硅酸盐,以纳米尺寸分布在聚合物中能提高聚合物的各种性能,本文综述了尼龙6/粘土纳米复合材料在机械性能、热稳定性、阻隔性能、结晶性能和流变行为等与纯尼龙6性能相比的优越性,同时详细地论述了性能得到改善的机理。
关键词 纳米复合材料 尼龙6 阻隔 结品 流变
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不同浓度Cu-Al2O3弥散强化铜合金退火行为的研究
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作者 郭明星 李周 汪明朴 《金属热处理》 EI CAS CSCD 北大核心 2005年第C00期215-217,共3页
通过力学性能测试和金相观察对中、低浓度Cu—Al2O3弥散强化铜合金的退火行为进行了研究。结果表明:低浓度弥散强化铜合金具有一定的抗高温软化性能,500℃退火后发生再结晶,900℃退火后已基本完全再结晶,屈强比约为56%。中浓度合... 通过力学性能测试和金相观察对中、低浓度Cu—Al2O3弥散强化铜合金的退火行为进行了研究。结果表明:低浓度弥散强化铜合金具有一定的抗高温软化性能,500℃退火后发生再结晶,900℃退火后已基本完全再结晶,屈强比约为56%。中浓度合金抗高温软化性能较好,900℃退火后,合金仍然以回复过程为主,金相尺度下不能看到再结晶晶粒,屈强比可达70%。弥散强化铜合金优越的抗高温软化性能归功于铜基体内均匀弥散分布有纳米Al2O3粒子。 展开更多
关键词 Cu—Al2O3弥散强化铜合金 退火 回复 结品
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维生素C磷酸酯镁提纯方法的改进 被引量:1
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作者 张玮 韩文爱 《河北化工》 2008年第3期39-40,共2页
对维生素C磷酸酯镁分离提纯的溶剂及工艺条件进行了优化选择。以甲醇为重结晶溶剂,当其用量是粗品溶液体积量3倍时产品纯度为95.2%(wt%),收率达90%以上。
关键词 维生素C磷酸酯镁 提纯 结品溶剂
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Pore structure effect on reservoir electrical properties and well logging evaluation 被引量:5
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作者 边环玲 关雎 +2 位作者 毛志强 鞠晓东 韩桂琴 《Applied Geophysics》 SCIE CSCD 2014年第4期374-383,508,共11页
The reservoir pore structure controls the reservoir quality and resistivity response of hydrocarbon-bearing zones and thus, critically affects logging interpretation. We use petrophysical data in three types of reserv... The reservoir pore structure controls the reservoir quality and resistivity response of hydrocarbon-bearing zones and thus, critically affects logging interpretation. We use petrophysical data in three types of reservoir with different pore structure characteristics to show that the complexity of pore structure had a significant effect on the effective porosity and permeability regardless of geological factors responsible for the formation of pore structure. Moreover,, the distribution and content of conductive fluids in the reservoir varies dramatically owing to pore structure differences, which also induces resistivity variations in reservoir rocks. Hence, the origin of low-resistivity hydrocarbon-bearing zones, except for those with conductive matrix and mud filtrate invasion, is attributed to the complexity of the pore structures. Consequently, reservoir-specific evaluation models, parameters, and criteria should be chosen for resistivity log interpretation to make a reliable evaluation of reservoir quality and fluids. 展开更多
关键词 pore structure reservoir quality RESISTIVITY low-resistivity hydrocarbon-bearing zone log evaluation
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Novel Substrate pn Junction Isolation for RF Integrated Inductors on Silicon 被引量:5
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作者 刘畅 陈学良 严金龙 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2001年第12期1486-1489,共4页
A new method for reducing the substrate rated losses of integrated spiral inductors is presented.The method is to block the eddy currents induced by spiral inductors by directly forming pn junction isolation in the S... A new method for reducing the substrate rated losses of integrated spiral inductors is presented.The method is to block the eddy currents induced by spiral inductors by directly forming pn junction isolation in the Si substrate. The substrate pn junction can be realized by using the standard silicon technologies without any additional processing steps.Integrated inductors on silicon are designed and fabricated. S parameters of the inductor based equivalent circuit are investigated and the inductor parameters are calculated.The impacts of the substrate pn junction isolation on the inductor quality factor are studied.The experimental results show that substrate pn junction isolation in certain depth has achieved a significant improvement.At 3GHz,the substrate pn junction isolation increases the inductor quality factor by 40%. 展开更多
关键词 Si integrated inductor quality factor eddy current pn junction isolation
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提高4A沸石产量的有效途径
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作者 秦慧虎 《无机硅化合物(天津)》 2006年第3期29-30,共2页
4A沸石生产过程中,水热合成反应(溶铝、混胶、结晶)在夹套反应釜中进行,结晶的4A沸石沉积于釜底。因此结晶时间成为影响产量的限制因子,本文针对性地提出增加结晶池,在反应釜中完成水热合反应之后,转入结晶池完成结晶工艺,提高... 4A沸石生产过程中,水热合成反应(溶铝、混胶、结晶)在夹套反应釜中进行,结晶的4A沸石沉积于釜底。因此结晶时间成为影响产量的限制因子,本文针对性地提出增加结晶池,在反应釜中完成水热合反应之后,转入结晶池完成结晶工艺,提高反应釜的利用率,从而提高产量。 展开更多
关键词 4A沸石 结品 产量 提高
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A Novel Local-Dielectric-Thickening Technique for Performance Improvements of Spiral Inductors on Si Substrates
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作者 杨荣 李俊峰 +3 位作者 赵玉印 柴淑敏 韩郑生 钱鹤 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第5期857-861,共5页
A novel local-dielectric-thickening technique i s presented for performance improvements of Si-based spiral inductors.This technique employs the processes of deposition,photolithography,and wet-etching,to locally thic... A novel local-dielectric-thickening technique i s presented for performance improvements of Si-based spiral inductors.This technique employs the processes of deposition,photolithography,and wet-etching,to locally thicken the oxide layer under the inductor,which can decrease the substrate loss and improve the inductor performance.Both the structures and processes are compact,economical,and compatible with CMOS processing.Several square spiral inductors with different inductances are fabricated,and the quality factors and the self-resonant frequencies both increase clearly with this proposed technique:for the 10nH,5nH,and 2nH inductors,the peak quality factors are effectively improved by 46.7%,49.7%,and 68.6%,respectively;however,the improvement percents of the self-resonant frequencies are more significant,which are 92.1%,91.0%,and no less than 68.1% respectively. 展开更多
关键词 SILICON INDUCTOR structure process quality factor self-resonant frequency
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Effects of Genotype and Planting Density on Agronomic Traits and Storage Root of Sweetpotato
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作者 闫会 李强 +5 位作者 张允刚 后猛 唐维 王欣 刘亚菊 马代夫 《Agricultural Science & Technology》 CAS 2017年第2期238-243,246,共7页
The effects ol different genotypes and planting densities on main agronomic traits, storage root traits and yield were studied with 6 high-quality sweetpotato varieties as study objects by 2-factor completely random d... The effects ol different genotypes and planting densities on main agronomic traits, storage root traits and yield were studied with 6 high-quality sweetpotato varieties as study objects by 2-factor completely random design. The results showed that there were significant differences in stem diameter, length of the longest vine and top/root (T/R) between different genotypes, T/R differed significantly under dif- ferent planting densities, and number of basal branches decreased with planting density increasing. Genotype and genotype x density showed significant or very sig- nificant effects on fresh root yield per plant, dry matter content and fresh root yield per hectare, fresh root yield per plant gradually decreased with planting density in- creasing, while fresh root yield per hectare increased with planting density increas- ing. Numbers of storage roots in different sizes of the 6 sweetpotato cultivars all exhibited an order of number of large-sized storage roots〈number of medium-sized storage roots〈small-sized storage root; and there were very significant differences in ratio of large-sized storage roots between different genotypes. The number of large- sized storage roots, ratio of large-sized storage roots and number of commercial storage roots deceased with planting density increasing, while there were no signifi- cant differences in number of medium-sized storage roots, number of small-sized storage roots, ratio of medium-sized storage roots and ratio of small-sized storage roots between different densities. Correlation analysis showed that there was signifi- cant positive correlation between number of basal branches and fresh root yield per plant; dry matter content in storage roots was in significant positive correlation with stem diameter, and in significant negative correlation with length of the longest vine; fresh root yield per hectare was in significant positive correlation with fresh root yield per plant, and in very significant negative correlation with dry matter content; and ratio of large-sized storage roots was in very significant positive correlation with number of large-sized storage root and fresh root yield per plant, and in very sig- nificant negative correlation with ratio of medium-sized storage roots and ratio of small-sized storage roots. This experiment showed that under the planting density of 7.5×104 plants/hm2, the 6 sweetpotato cultivars all reached the highest numbers of commercial storage roots and fresh root yields per hectare. 展开更多
关键词 SWEETPOTATO GENOTYPE Planting density Agronomic trait Storage root Commercial root Correlation
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Diagnosis of abdominal tuberculosis:Experience from 11 cases and review of the literature 被引量:20
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作者 Ali Uzunkoy MugeHarma MehmetHarma 《World Journal of Gastroenterology》 SCIE CAS CSCD 2004年第24期3647-3649,共3页
AIM:To analyze the experience within our hospital and to review the literature so as to establish the best means of diagnosis of abdominal tuberculosis. METHODS:The records of 11 patients (4 males,7 females, mean age ... AIM:To analyze the experience within our hospital and to review the literature so as to establish the best means of diagnosis of abdominal tuberculosis. METHODS:The records of 11 patients (4 males,7 females, mean age 39 years,range 18-65 years) diagnosed with abdominal tuberculosis in Harran University Hospital between January 1996 and October 2003 were analyzed retrospectively and the literature was reviewed. RESULTS:Ascites was present in all cases.Other common findings were weight loss (81%),weakness (81%),abdominal mass (72%),abdominal pain (72%),abdominal distension (63%),anorexia (45%) and night sweat (36%).The average hemoglobin was 8.2 g/dL and the average FAR was 50 mm/h (range 30-125).Elevated levels of cancer antigen CA-125 were determined in four patients.Abdominal ultrasound showed abnormalities in all cases:ascites in all,tuboovarian mass in five,omental thickening in 3,and enlarged lymph nodes (mesenteric,para-aortic) in 2.CT scans showed ascites in all,pelvic mass in 5,retroperitoneal lymphadenopathy in 4,mesenteric stranding in 4,omental stranding in 3, bowel wall thickening in 2 and mesenteric lymphadenopathy in 2.Only one patient had a chest radiograph suggestive of a new TB lesion.Two had a positive family history of pulmonary TB.None had acid-fast bacilli (AFB) in the sputum and the tuberculin test was positive in only two.Laparotomy was performed in 6 cases,laparoscopy in 4 and ultrasound- guided fine needle aspiration in 2.In those patients subjected to operation,the findings were multiple diffuse involvement of the visceral and parietal peritoneum,white ‘miliary nodules’or plaques,enlarged lymph nodes,ascites, ‘violin string’fibrinous strands,and omental thickening. Biopsy specimens showed granulomas,while ascitic fluid showed numerous lymphocytes.Both were negative for acid-fast bacilli by staining.PCR of ascitic fluid was positive for Mycobactenum tuberculosis ( M.tuberculosis) in all cases. CONCLUSION:Abdominal TB should be considered in all cases with ascites.Our experience suggests that PCR of ascitic fluid obtained by ultrasound-guided fine needle aspiration is a reliable method for its diagnosis and should at least be attempted before surgical intervention. 展开更多
关键词 ABDOMEN Adolescent Adult Aged ASCITES Diagnosis Differential Female Humans Male Middle Aged Peritonitis Tuberculous Retrospective Studies Tuberculosis Gastrointestinal Tuberculosis Lymph Node
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Preparation of High Viscosity PAO from Mixed Alpha-Olefins over Metallocene Catalyst 被引量:7
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作者 Jiang Hongbo Xu Xinlei +1 位作者 Hong Xianzhong Song Shangfei 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2018年第2期90-96,共7页
Polymerization of mixed alpha-olefins originating from the Fischer-Tropsch synthesis catalyzed by theBu)_3/[Me_2NHPh]^+[B(C_6F_5)_4]^-,was studied.The effects of the Zr/olefin mole ratio,Al/Zr mole ratio,reaction temp... Polymerization of mixed alpha-olefins originating from the Fischer-Tropsch synthesis catalyzed by theBu)_3/[Me_2NHPh]^+[B(C_6F_5)_4]^-,was studied.The effects of the Zr/olefin mole ratio,Al/Zr mole ratio,reaction temperature,and reaction time on the viscosity and molecular weight of the product were investigated.The conversion under optimized conditions reached 97.3%.The product structure was characterized by ^(13)C NMR spectrometry and ~1H NMR spectrometry,and the conversion of olefins with different carbon numbers under different conditions was determined by GC analysis.The polymer obtained under optimized conditions has a high viscosity index of 262 with a narrow molecular weight distribution of 1.95,which is a desired component for lubricating base oil. 展开更多
关键词 poly alpha-olefn METALLOCENE mixedalpha-olefns lubricating base oil POLYMERIZATION
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