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偏氟乙烯/三氟乙烯共聚物介电松弛的结晶度效应
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作者 张兴元 古川猛夫 《高分子学报》 SCIE EI CAS CSCD 北大核心 1995年第2期161-169,共9页
用改进的介电松弛谱仪(精度2‰)测定了VDF/TrFE(7/27、65/35、52/48mol%)共聚物溶液成膜、液氮淬火、熔融慢冷和热处理试样在-120—130℃、10-2一104Hz范围的复数介电常数.介电松弛研... 用改进的介电松弛谱仪(精度2‰)测定了VDF/TrFE(7/27、65/35、52/48mol%)共聚物溶液成膜、液氮淬火、熔融慢冷和热处理试样在-120—130℃、10-2一104Hz范围的复数介电常数.介电松弛研究结果显示低结晶度的淬火试样较高结晶度的熔融慢冷和热处理试样的Tc高.结晶度上升,居里点处的介电常数增大.室温以下的介电频率谱分别由代表非晶区分子运动的β松弛(低频部)和局域运动的γ松弛(高频部)叠合而成.随结晶度提高,β松弛峰减小,γ松弛峰增大;非晶松弛强度减弱.晶区松弛强度增强. 展开更多
关键词 偏氟乙烯/三氟乙烯共聚物 介电松弛 结晶度效应
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Strength criterion for crystalline rocks considering grain size effect and tensile-compressive strength ratio
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作者 ZHANG Cheng-han JI Hong-guang +3 位作者 JIANG Peng YOU Shuang GENG Qian-cheng JIAO Chen-jiang 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2365-2378,共14页
The macroscopic mechanical properties of rocks are significantly influenced by their microstructure.As a material bonded by mineral grains,the grain morphology of crystalline rock is the primary factor influencing the... The macroscopic mechanical properties of rocks are significantly influenced by their microstructure.As a material bonded by mineral grains,the grain morphology of crystalline rock is the primary factor influencing the strength.However,most strength criteria neglect the strength variations caused by different grain characteristics in rocks.Furthermore,the traditional linear criteria tend to overestimate tensile strength and exhibit apex singularity.To address these shortcomings,a piecewise strength criterion that considers the grain size effect has been proposed.A part of an ellipse was employed to construct the envelope of the tensive-shear region on the meridian plane,to accurately reproduce the low tensile-compressive strength ratio.Based on the analysis of experimental data,both linear and exponential modification functions that account for grain size effects were integrated into the proposed criterion.The corresponding finite element algorithm has been implemented.The accuracy and applicability of the proposed criterion were validated by comparing with the experimental data. 展开更多
关键词 crystalline rock grain size effect strength criterion tensile-compressive strength ratio finite element algorithm
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