创作于1794—1795年间的《f小调钢琴奏呜曲》Op.2,No.1系德国作曲家路德维希·凡·贝多芬Ludwig van Beethoven的早期作品之一。在这首题献给海顿的钢琴奏鸣曲的柔板乐章(Adagio)中,作品清晰的层次和严谨的结构具有浓郁...创作于1794—1795年间的《f小调钢琴奏呜曲》Op.2,No.1系德国作曲家路德维希·凡·贝多芬Ludwig van Beethoven的早期作品之一。在这首题献给海顿的钢琴奏鸣曲的柔板乐章(Adagio)中,作品清晰的层次和严谨的结构具有浓郁的古典主义风格。作曲家对各音乐元素逻辑性的布局安排充分体现了他对音乐形式从宏观到微观之间联系的把握和独到处理。作为贝多芬第一首钢琴奏呜曲,该作品的风格和思想性对其之后的创作具有划时代的开端意义。展开更多
Mechanical properties and electronic structure of MgCu2, Mg2 Ca and MgZn2 phases were investigated by means of first principles calculations from CASTEP program based on density functional theory(DFT). The calculate...Mechanical properties and electronic structure of MgCu2, Mg2 Ca and MgZn2 phases were investigated by means of first principles calculations from CASTEP program based on density functional theory(DFT). The calculated lattice parameters are in good agreement with the experimental and literature values. The calculated heat of formation and cohesive energies showed that MgCu2 has the strongest alloying ability and structural stability. Elastic constants of MgCu2, Mg2 Ca and MgZn2 were calculated, and the bulk moduli, shear moduli, elastic moduli and Poisson ratio were derived. The calculated results show that MgCu2, Mg2 Ca and MgZn2 are all ductile phases. Among the three phases, MgCu2 has the strongest stiffness and the plasticity of MgZn2 phase is the best. Melting points of the three phases were predicted using cohesive energy and elastic constants. Density of states(DOS), Mulliken population, electron occupation number and charge density difference were discussed. Finally, Debye temperature was calculated and discussed.展开更多
Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density o...Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density on microstructure and properties of the PEO coatings were studied. It was found that pore density of the coatings decreased with increasing the current density. The tribological and hardness tests suggested that the ceramic coating produced under the current density of 15 A/dm2showed the best mechanical property, which matched well with the phase analysis. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves proved that the coating obtained under 15 A/dm2 displayed the best anti-corrosion property, which was directly connected with morphologies of coatings.展开更多
Based on protein-DNA complex crystal structural data in up-to-date Nucleic Acid Database,the related parameters of DNA Kinetic Structure were investigated by Monte-Carlo Multiple Integrals on the base of modified DNA ...Based on protein-DNA complex crystal structural data in up-to-date Nucleic Acid Database,the related parameters of DNA Kinetic Structure were investigated by Monte-Carlo Multiple Integrals on the base of modified DNA structure statistical mechanical model,and time complexity and precision were analyzed on the calculated results.展开更多
The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vesse...The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vessels. In order to study the thermal leakage and gap changes on the support structure, as well as radius temperature and stress distribution on GFRP tube, an experimental investigation has been taken. The results indicate that the support structure is proved to fit well as thermal-insulating and load-supporting part in cryo-genic vessels, furthermore has high security during cryogenic applications.展开更多
In recent years, great economic output of land has been achieved in economic-technological development areas in China, but the intensity of land use in some of these areas is very low. The degree of the low intensity ...In recent years, great economic output of land has been achieved in economic-technological development areas in China, but the intensity of land use in some of these areas is very low. The degree of the low intensity of land use needs to be evaluated. The current method of comprehensive evaluation and grading by one index system has the limitations due to the existence of differences between regions and industries. This paper evaluates industrial land use intensity by Total Factor Productivity (TFP) analysis, which not only measures the intensity but also illustrates the ef-ficiency of input factors. This method is applied to the Beijing Economic-technological Development Area (BDA). A comparison analysis on factor use efficiency and input structure of capital and labor between industries is also carried out in the absence of a labor-income ratio.展开更多
Microstructure and phase transformation of disodium guanosine 5′-monophosphate(5′-GMPNa_2) are extremely important for controlling the process and understanding the mechanism of crystallization. In this work, the th...Microstructure and phase transformation of disodium guanosine 5′-monophosphate(5′-GMPNa_2) are extremely important for controlling the process and understanding the mechanism of crystallization. In this work, the thermodynamic properties of polymorphous 5′-GMPNa_2 especially the solubility were studied, the solubility results show that 5′-GMPNa_2 is more soluble in ethanol–water(E–W) than in isopropanol–water(I–W). The amorphous form of 5′-GMPNa_2 is more soluble than the crystalline form at the same mole fraction and temperature. Meanwhile, the crystalline forms and morphologies of the residual solids were characterized by PXRD and SEM. The results indicate that solid forms of 5′-GMPNa_2 transformed spontaneously from amorphous to crystalline when the ethanol proportion is ≥20%. In addition, increasing the pH facilitates the dissolution of 5′-GMPNa_2 and helps to maintain the crystalline form. The associated Gibbs free energy values were calculated to verify the trend of transformation from amorphous to crystalline 5′-GMPNa_2. These results should help to guide the industrial crystallization process and to obtain the crystalline form of 5′-GMPNa_2.展开更多
By performing ab initio molecular dynamics simulations, we have investigated the microstructure, dynamical and electronic properties of liquid phosphorus (P) under high temperature and pressure. In our simulations, ...By performing ab initio molecular dynamics simulations, we have investigated the microstructure, dynamical and electronic properties of liquid phosphorus (P) under high temperature and pressure. In our simulations, the calculated coordination number (CN) changes discontinuously with density, and seems to increase rapidly after liquid P is compressed to 2.5 g/cm3. Under compression, liquid P shows the first-order liquid-liquid phase transition from the molecular liquid composed of the tetrahedral P4 molecules to complex polymeric form with three-dimensional network structure, accompanied by the nonmetal to metal transition of the electronic structure. The order parameters Q6 and Q4 are sensitive to the microstructural change of liquid P. By calculating diffusion coefficients, we show the dynamical anomaly of liquid P by compression. At lower temperatures, a maximum exists at the diffusion coefficients as a function of density; at higher temperatures, the anomalous behavior is weakened. The excess entropy shows the same phenomena as the diffusion coefficients. By analysis of the angle distribution functions and angular limited triplet correlation functions, we can clearly find that the Peierls distortion in polymeric form of liquid P is reduced by further compression.展开更多
The relationships between mechanical characteristics of rock and microcosmic mechanism at high temperatures were investigated by MTS815, as well as the stress-strain behavior of granite under the action of temperature...The relationships between mechanical characteristics of rock and microcosmic mechanism at high temperatures were investigated by MTS815, as well as the stress-strain behavior of granite under the action of temperatures ranging from room temperature to 1200 ℃. Based on a micropore structure analyzer and SEM, the changes in rock porosity and micro structural morphology of sample fractures and brittle-plastic characteristics under high temperatures were analyzed. The results are as follows: 1) Mechanical characteristics do not show obvious variations before 800 ℃; strength decreases suddenly after 800 ℃ and bearing capacity is almost lost at 1200 ℃. 2) Rock porosity increases with rising temperatures; the threshold temperature is about 800 ℃; at this temperature its effect is basically uniform with strength decreasing rapidly. 3) The failure type of granite is a brittle tensile fracture at temperatures below 800 ℃ which transforms into plasticity at temperatures higher than 800 ℃ and crystal formation takes place at this time. Chemical reactions take place at 1200 ℃. Failure of granite under high temperature is a common result of thermal stress as indicated by an increase in the thermal expansion coefficient, transformation to crystal formation of minerals and structural chemical reactions.展开更多
In this paper,structural dynamic characteristics of a high-speed light special catamaran-wave piercing catamaran are analyzed using the FEA software MSC-NASTRAN. The dynamic reduction method is introduced to eliminate...In this paper,structural dynamic characteristics of a high-speed light special catamaran-wave piercing catamaran are analyzed using the FEA software MSC-NASTRAN. The dynamic reduction method is introduced to eliminate the local vibration modes in order to obtain the whole ship's mode shapes. In the post-processor, a lot of accessorial methods are adopted to eliminate the local vibrations, so that the whole ship's mode shapes can be identified. The modal analysis indicates that the dynamic reduction method fits for mode shapes identifying. In the end,the test results of a catamaran named Frederick G. Greed are used for reference to validate the obtained results. The comparison process shows that the results are credible. A special mode shape, which is quite different with that of conventional monohull ship, is also pointed out. The obtained results provide a valuable reference for the coming computation of catamaran's vihration characteristics.展开更多
A new metastable β type titanium alloy called TB-13 with the combination of excellent strength and ductility was developed successfully.In order to develop a perspective on this new alloy,the influence of several com...A new metastable β type titanium alloy called TB-13 with the combination of excellent strength and ductility was developed successfully.In order to develop a perspective on this new alloy,the influence of several commonly used heat treatments on the microstructure and properties was studied.In solution-treated and quenched samples,a low-temperature aging at 480°C results in the precipitation of finerαphase.The precipitation of coarserαphase plate at higher aging temperature(560°C)leads to the increase of tensile ductility but reduction of strength.During low-temperature aging at 300°C,quite homogeneous distribution of fine isothermalωphase particles was found.The isothermalωphase provides nucleation sites forαphase during two-step aging process and makesαphase extremely fine and disperse uniformly in β matrix.Thus,TB-13 alloy is strengthened and its mechanical properties are improved.展开更多
Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic response...Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic responses of three-stage soil slope and frame structure were studied by performing a series of bidirectional Wenchuan motions in terms of the failure mode of three-stage structure, the acceleration of soil slope, the displacement of frame structure, and the anchor stress of frame structure. The response accelerations in both horizontal and vertical directions are the most largely amplified at the slope top of each stage subjected to different shaking cases. The platforms among the stages reduce the amplification effect of response acceleration. The residual displacement of frame structure increases significantly as the intensity of shaking case increases. The frame structure at each stage presents a combined displacement mode consisting of a translation and a rotation around the vertex. The anchor stress of frame structure is mainly increased by the first intense pulse of Wenchuan seismic wave, and it is sensitive to the intensity of shaking case. The anchor stress of frame structure at the first stage is the most considerably enlarged by earthquake loading.展开更多
文摘创作于1794—1795年间的《f小调钢琴奏呜曲》Op.2,No.1系德国作曲家路德维希·凡·贝多芬Ludwig van Beethoven的早期作品之一。在这首题献给海顿的钢琴奏鸣曲的柔板乐章(Adagio)中,作品清晰的层次和严谨的结构具有浓郁的古典主义风格。作曲家对各音乐元素逻辑性的布局安排充分体现了他对音乐形式从宏观到微观之间联系的把握和独到处理。作为贝多芬第一首钢琴奏呜曲,该作品的风格和思想性对其之后的创作具有划时代的开端意义。
基金Project(2013201018)supported by Scientific and Technological Project of Liaoning Province,China
文摘Mechanical properties and electronic structure of MgCu2, Mg2 Ca and MgZn2 phases were investigated by means of first principles calculations from CASTEP program based on density functional theory(DFT). The calculated lattice parameters are in good agreement with the experimental and literature values. The calculated heat of formation and cohesive energies showed that MgCu2 has the strongest alloying ability and structural stability. Elastic constants of MgCu2, Mg2 Ca and MgZn2 were calculated, and the bulk moduli, shear moduli, elastic moduli and Poisson ratio were derived. The calculated results show that MgCu2, Mg2 Ca and MgZn2 are all ductile phases. Among the three phases, MgCu2 has the strongest stiffness and the plasticity of MgZn2 phase is the best. Melting points of the three phases were predicted using cohesive energy and elastic constants. Density of states(DOS), Mulliken population, electron occupation number and charge density difference were discussed. Finally, Debye temperature was calculated and discussed.
基金Project(51371039)supported by the National Natural Science Foundation of China
文摘Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density on microstructure and properties of the PEO coatings were studied. It was found that pore density of the coatings decreased with increasing the current density. The tribological and hardness tests suggested that the ceramic coating produced under the current density of 15 A/dm2showed the best mechanical property, which matched well with the phase analysis. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves proved that the coating obtained under 15 A/dm2 displayed the best anti-corrosion property, which was directly connected with morphologies of coatings.
基金Supported by Inner Mongolia Natural Science Foundation(200711020112)Innovation Fundation of Inner Mongolia University of Science and Technology (2009NC064)~~
文摘Based on protein-DNA complex crystal structural data in up-to-date Nucleic Acid Database,the related parameters of DNA Kinetic Structure were investigated by Monte-Carlo Multiple Integrals on the base of modified DNA structure statistical mechanical model,and time complexity and precision were analyzed on the calculated results.
文摘The assembled form of thick-wall glass fiber reinforced plastics (GFRP) tube and 0Cr18Ni9 austenitic stainless steel pipes was designed as the radius thermal-insulating and load-supporting structure in cryogenic vessels. In order to study the thermal leakage and gap changes on the support structure, as well as radius temperature and stress distribution on GFRP tube, an experimental investigation has been taken. The results indicate that the support structure is proved to fit well as thermal-insulating and load-supporting part in cryo-genic vessels, furthermore has high security during cryogenic applications.
基金Under the auspices of Fundamental Research Funds for the Central Universities (No. 2009SD-5)
文摘In recent years, great economic output of land has been achieved in economic-technological development areas in China, but the intensity of land use in some of these areas is very low. The degree of the low intensity of land use needs to be evaluated. The current method of comprehensive evaluation and grading by one index system has the limitations due to the existence of differences between regions and industries. This paper evaluates industrial land use intensity by Total Factor Productivity (TFP) analysis, which not only measures the intensity but also illustrates the ef-ficiency of input factors. This method is applied to the Beijing Economic-technological Development Area (BDA). A comparison analysis on factor use efficiency and input structure of capital and labor between industries is also carried out in the absence of a labor-income ratio.
基金Supported by the Program for Changjiang Scholars and Innovative Research Team in University(IRT_14R28)the National Basic Research Program of China(2013CB733602)+4 种基金the Major Research Plan of the National Natural Science Foundation of China(21390204)the National Natural Science Foundation of China(21636003,21506090)Open Fund by Jiangsu Key Lab of Biomass-based Green Fuels and Chemicals(JSBGFC14005)Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Microstructure and phase transformation of disodium guanosine 5′-monophosphate(5′-GMPNa_2) are extremely important for controlling the process and understanding the mechanism of crystallization. In this work, the thermodynamic properties of polymorphous 5′-GMPNa_2 especially the solubility were studied, the solubility results show that 5′-GMPNa_2 is more soluble in ethanol–water(E–W) than in isopropanol–water(I–W). The amorphous form of 5′-GMPNa_2 is more soluble than the crystalline form at the same mole fraction and temperature. Meanwhile, the crystalline forms and morphologies of the residual solids were characterized by PXRD and SEM. The results indicate that solid forms of 5′-GMPNa_2 transformed spontaneously from amorphous to crystalline when the ethanol proportion is ≥20%. In addition, increasing the pH facilitates the dissolution of 5′-GMPNa_2 and helps to maintain the crystalline form. The associated Gibbs free energy values were calculated to verify the trend of transformation from amorphous to crystalline 5′-GMPNa_2. These results should help to guide the industrial crystallization process and to obtain the crystalline form of 5′-GMPNa_2.
基金The project supported by National Natural Science Foundation of China under Grant Nos.10374089 and 10674135the Knowledge Innovation Program of the Chinese Academy of Sciences under Grant No.KJCX2-SW-Wl7the Center for Computational Science,Hefei Institutes of Physical Sciences
文摘By performing ab initio molecular dynamics simulations, we have investigated the microstructure, dynamical and electronic properties of liquid phosphorus (P) under high temperature and pressure. In our simulations, the calculated coordination number (CN) changes discontinuously with density, and seems to increase rapidly after liquid P is compressed to 2.5 g/cm3. Under compression, liquid P shows the first-order liquid-liquid phase transition from the molecular liquid composed of the tetrahedral P4 molecules to complex polymeric form with three-dimensional network structure, accompanied by the nonmetal to metal transition of the electronic structure. The order parameters Q6 and Q4 are sensitive to the microstructural change of liquid P. By calculating diffusion coefficients, we show the dynamical anomaly of liquid P by compression. At lower temperatures, a maximum exists at the diffusion coefficients as a function of density; at higher temperatures, the anomalous behavior is weakened. The excess entropy shows the same phenomena as the diffusion coefficients. By analysis of the angle distribution functions and angular limited triplet correlation functions, we can clearly find that the Peierls distortion in polymeric form of liquid P is reduced by further compression.
基金Projects 50579042 supported by the National Natural Science Foundation of China2002CB412705 by the National Basic Research and Development(973) Program of Chinaok060122 by the Young Foundation of China University of Mining & Technology
文摘The relationships between mechanical characteristics of rock and microcosmic mechanism at high temperatures were investigated by MTS815, as well as the stress-strain behavior of granite under the action of temperatures ranging from room temperature to 1200 ℃. Based on a micropore structure analyzer and SEM, the changes in rock porosity and micro structural morphology of sample fractures and brittle-plastic characteristics under high temperatures were analyzed. The results are as follows: 1) Mechanical characteristics do not show obvious variations before 800 ℃; strength decreases suddenly after 800 ℃ and bearing capacity is almost lost at 1200 ℃. 2) Rock porosity increases with rising temperatures; the threshold temperature is about 800 ℃; at this temperature its effect is basically uniform with strength decreasing rapidly. 3) The failure type of granite is a brittle tensile fracture at temperatures below 800 ℃ which transforms into plasticity at temperatures higher than 800 ℃ and crystal formation takes place at this time. Chemical reactions take place at 1200 ℃. Failure of granite under high temperature is a common result of thermal stress as indicated by an increase in the thermal expansion coefficient, transformation to crystal formation of minerals and structural chemical reactions.
文摘In this paper,structural dynamic characteristics of a high-speed light special catamaran-wave piercing catamaran are analyzed using the FEA software MSC-NASTRAN. The dynamic reduction method is introduced to eliminate the local vibration modes in order to obtain the whole ship's mode shapes. In the post-processor, a lot of accessorial methods are adopted to eliminate the local vibrations, so that the whole ship's mode shapes can be identified. The modal analysis indicates that the dynamic reduction method fits for mode shapes identifying. In the end,the test results of a catamaran named Frederick G. Greed are used for reference to validate the obtained results. The comparison process shows that the results are credible. A special mode shape, which is quite different with that of conventional monohull ship, is also pointed out. The obtained results provide a valuable reference for the coming computation of catamaran's vihration characteristics.
基金Project(2007CB613802)supported by the National Basic Research Program of ChinaProject(KP200912)supported by the Research Fund of the State Key Laboratory of Solidification Processing(NWPU),China
文摘A new metastable β type titanium alloy called TB-13 with the combination of excellent strength and ductility was developed successfully.In order to develop a perspective on this new alloy,the influence of several commonly used heat treatments on the microstructure and properties was studied.In solution-treated and quenched samples,a low-temperature aging at 480°C results in the precipitation of finerαphase.The precipitation of coarserαphase plate at higher aging temperature(560°C)leads to the increase of tensile ductility but reduction of strength.During low-temperature aging at 300°C,quite homogeneous distribution of fine isothermalωphase particles was found.The isothermalωphase provides nucleation sites forαphase during two-step aging process and makesαphase extremely fine and disperse uniformly in β matrix.Thus,TB-13 alloy is strengthened and its mechanical properties are improved.
基金Projects(51878667,51678571)supported by the National Natural Science Foundation of ChinaProject(2018zzts657)supported by the Central South University Postgraduates’Innovation,ChinaProject(2018JJ2517)supported by the Hunan Provincial Natural Science Foundation of China。
文摘Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic responses of three-stage soil slope and frame structure were studied by performing a series of bidirectional Wenchuan motions in terms of the failure mode of three-stage structure, the acceleration of soil slope, the displacement of frame structure, and the anchor stress of frame structure. The response accelerations in both horizontal and vertical directions are the most largely amplified at the slope top of each stage subjected to different shaking cases. The platforms among the stages reduce the amplification effect of response acceleration. The residual displacement of frame structure increases significantly as the intensity of shaking case increases. The frame structure at each stage presents a combined displacement mode consisting of a translation and a rotation around the vertex. The anchor stress of frame structure is mainly increased by the first intense pulse of Wenchuan seismic wave, and it is sensitive to the intensity of shaking case. The anchor stress of frame structure at the first stage is the most considerably enlarged by earthquake loading.