Hydrogels show versatile properties and are of great interest in the fields of bioelectronics and tissue engineering.Understanding the dynamics of the water molecules trapped in the three-dimensional polymeric network...Hydrogels show versatile properties and are of great interest in the fields of bioelectronics and tissue engineering.Understanding the dynamics of the water molecules trapped in the three-dimensional polymeric networks of the hydrogels is crucial to elucidate their mechanical and swelling properties at the molecular level.In this report,the poly(DMAEMA-co-AA)hydrogels were synthesized and characterized by the macroscopic swelling measurements under different pH conditions.Furthermore,the microscopic structural dynamics of pH stimulus-responsive hydrogels were studied using FTIR and ultrafast IR spectroscopies from the viewpoint of the SCN-anionic solute as the local vibrational reporter.Ultrafast IR spectroscopic measurements showed the time constants of the vibrational population decay of SCN-were increased from 14±1 ps to 20±1 ps when the pH of the hydrogels varied from2.0 to 12.0.Rotational anisotropy measurements further revealed that the rotation of SCNanionic probe was restricted by the three-dimensional network formed in the hydrogels and the rotation of SCN-anionic probe cannot decay to zero especially at the pH of 7.0.These results are expected to provide a molecular-level understanding of the microscopic structure of the cross-linked polymeric network in the pH stimulus-responsive hydrogels.展开更多
The ship hull is simplified as a free beam with varying sections. Based on hydroelasticity and explosion mechanics theory,mechanical model and kinetic equation for hull girder vibration under non-contact explosion are...The ship hull is simplified as a free beam with varying sections. Based on hydroelasticity and explosion mechanics theory,mechanical model and kinetic equation for hull girder vibration under non-contact explosion are established. The equation is solved by Wilson-θ algorithm. On the basis of the above principles,a structure kinetics analysis program is compiled. The dynamic response of supposed warship under air explosion is calculated conveniently and quickly. Under the explosion condition designed in the paper,the positive pressure period of non-contact explosion wave is much less than the natural periods of the first four modes of hull girder and the resonance of ship girder overall vibration can be avoided. The ratio of midship maximum moment to ultimate bearing strength under non-contact explosion accelerates with the increment of impact factor.展开更多
基金supported by the National Natural Science Foundation of China(No.21873062)the Fundamental Research Funds for the Central Universities(GK202001009)+2 种基金the Natural Science Basis Research Plan in Shaanxi Province of China(No.2020JM-295)the 111 Project(B14041)Program for Changjiang Scholars and the Innovative Research Team in University(IRT-14R33)。
文摘Hydrogels show versatile properties and are of great interest in the fields of bioelectronics and tissue engineering.Understanding the dynamics of the water molecules trapped in the three-dimensional polymeric networks of the hydrogels is crucial to elucidate their mechanical and swelling properties at the molecular level.In this report,the poly(DMAEMA-co-AA)hydrogels were synthesized and characterized by the macroscopic swelling measurements under different pH conditions.Furthermore,the microscopic structural dynamics of pH stimulus-responsive hydrogels were studied using FTIR and ultrafast IR spectroscopies from the viewpoint of the SCN-anionic solute as the local vibrational reporter.Ultrafast IR spectroscopic measurements showed the time constants of the vibrational population decay of SCN-were increased from 14±1 ps to 20±1 ps when the pH of the hydrogels varied from2.0 to 12.0.Rotational anisotropy measurements further revealed that the rotation of SCNanionic probe was restricted by the three-dimensional network formed in the hydrogels and the rotation of SCN-anionic probe cannot decay to zero especially at the pH of 7.0.These results are expected to provide a molecular-level understanding of the microscopic structure of the cross-linked polymeric network in the pH stimulus-responsive hydrogels.
文摘The ship hull is simplified as a free beam with varying sections. Based on hydroelasticity and explosion mechanics theory,mechanical model and kinetic equation for hull girder vibration under non-contact explosion are established. The equation is solved by Wilson-θ algorithm. On the basis of the above principles,a structure kinetics analysis program is compiled. The dynamic response of supposed warship under air explosion is calculated conveniently and quickly. Under the explosion condition designed in the paper,the positive pressure period of non-contact explosion wave is much less than the natural periods of the first four modes of hull girder and the resonance of ship girder overall vibration can be avoided. The ratio of midship maximum moment to ultimate bearing strength under non-contact explosion accelerates with the increment of impact factor.
