传统的锂离子电池研究多注重本身相关机理以及储能能力的提高,而结构化电池不仅能够储能,且可以作为结构本身承受一定载荷.本文设计了一种新型结构化电池石墨负极板,通过修正准静态下石墨的力学指标得到对应高应变率下的压缩应力-应变...传统的锂离子电池研究多注重本身相关机理以及储能能力的提高,而结构化电池不仅能够储能,且可以作为结构本身承受一定载荷.本文设计了一种新型结构化电池石墨负极板,通过修正准静态下石墨的力学指标得到对应高应变率下的压缩应力-应变曲线、失效应变,采用数值分析方法对石墨负极板的承载能力进行了分析.同时,由于荷电状态(State of charge, SOC)会影响石墨的弹性模量、失效应变、厚度以及压缩应力-应变曲线等力学性能,因此在石墨的本构方程中考虑并修正了SOC产生的影响.通过有限元模拟了不同SOC下石墨负极板受到冲击后的响应,结果表明随着应变率或SOC增大,石墨负极板承载高速冲击的能力也随之降低.本文的研究成果可以为结构化电池负极的结构设计提供参考.展开更多
Na^＋ doped sample Li0.95Na0.05FePO4 was prepared through solid state method. Structure characterization shows Na^＋ is successfully introduced into the LiFePO4 matrix. Scanning electron microscopy shows the particle ...Na^＋ doped sample Li0.95Na0.05FePO4 was prepared through solid state method. Structure characterization shows Na^＋ is successfully introduced into the LiFePO4 matrix. Scanning electron microscopy shows the particle size mainly ranges in 1-3 μm. X-ray diffraction Rietveld refinement demonstrates lattice distortion with an increased cell volume. As one cathode material, it has a discharge capacity of 150 mAh/g at 0.1 C rate. The material exhibits a capacity of 109 and 107 mAh/g at 5 and 7.5 C respectively. When cycled at 1 and 5 C, the material retains 84% （after 1000 cycles） and 86% （after 350 cycles） of the initial discharge capacity respectively indicating excellent structure stability and cycling performance. Na^＋ doping enhances the electrochemical activity especially the cycle performance effectively.展开更多
Developing high-performance lithium ion batteries(LIBs)using manganese oxides as anodes is attractive due to their high theoretical capacity and abundant resources.Herein,we report a facile synthesis of hierarchical s...Developing high-performance lithium ion batteries(LIBs)using manganese oxides as anodes is attractive due to their high theoretical capacity and abundant resources.Herein,we report a facile synthesis of hierarchical spherical MnO2 containing coherent amorphous/crystalline domained by a simple yet effective redox precipitation reaction at room temperature.Further,flower-like CoMn2O4 constructed by single-crystalline spinel nanosheets has been fabricated using MnO2 as precursor.This mild methodology avoids undesired particle aggregation and loss of active surface area in conventional hydrothermal or solid-state processes.Moreover,both MnO2 and CoMn2O4 nanosheets manifest superior lithium-ion storage properties,rendering them promising applications in LIBs and other energy-related fields.展开更多
文摘传统的锂离子电池研究多注重本身相关机理以及储能能力的提高,而结构化电池不仅能够储能,且可以作为结构本身承受一定载荷.本文设计了一种新型结构化电池石墨负极板,通过修正准静态下石墨的力学指标得到对应高应变率下的压缩应力-应变曲线、失效应变,采用数值分析方法对石墨负极板的承载能力进行了分析.同时,由于荷电状态(State of charge, SOC)会影响石墨的弹性模量、失效应变、厚度以及压缩应力-应变曲线等力学性能,因此在石墨的本构方程中考虑并修正了SOC产生的影响.通过有限元模拟了不同SOC下石墨负极板受到冲击后的响应,结果表明随着应变率或SOC增大,石墨负极板承载高速冲击的能力也随之降低.本文的研究成果可以为结构化电池负极的结构设计提供参考.
基金V. ACKNOWLEDGMENTS The work was supported by the Natural Science Foundation of Anhui province （No.90414178） and USTC-NSRL Association funding （No.KY2060030010）.
文摘Na^＋ doped sample Li0.95Na0.05FePO4 was prepared through solid state method. Structure characterization shows Na^＋ is successfully introduced into the LiFePO4 matrix. Scanning electron microscopy shows the particle size mainly ranges in 1-3 μm. X-ray diffraction Rietveld refinement demonstrates lattice distortion with an increased cell volume. As one cathode material, it has a discharge capacity of 150 mAh/g at 0.1 C rate. The material exhibits a capacity of 109 and 107 mAh/g at 5 and 7.5 C respectively. When cycled at 1 and 5 C, the material retains 84% （after 1000 cycles） and 86% （after 350 cycles） of the initial discharge capacity respectively indicating excellent structure stability and cycling performance. Na^＋ doping enhances the electrochemical activity especially the cycle performance effectively.
基金Project(JCYJ20170817110251498)supported by the Basic Research Project of the Science and Technology Innovation Commission of Shenzhen,ChinaProject(2016TQ03C919)supported by the Guangdong Special Support for the Science and Technology Leading Young Scientist,ChinaProject(21603094)supported by the National Natural Science Foundation of China
文摘Developing high-performance lithium ion batteries(LIBs)using manganese oxides as anodes is attractive due to their high theoretical capacity and abundant resources.Herein,we report a facile synthesis of hierarchical spherical MnO2 containing coherent amorphous/crystalline domained by a simple yet effective redox precipitation reaction at room temperature.Further,flower-like CoMn2O4 constructed by single-crystalline spinel nanosheets has been fabricated using MnO2 as precursor.This mild methodology avoids undesired particle aggregation and loss of active surface area in conventional hydrothermal or solid-state processes.Moreover,both MnO2 and CoMn2O4 nanosheets manifest superior lithium-ion storage properties,rendering them promising applications in LIBs and other energy-related fields.
