The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers （T700, T300 and M40） before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal condu...The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers （T700, T300 and M40） before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal conductivity of carbon/carbon composites with different carbon fibers as preform were studied. The results show that M40 carbon fiber has the largest crystallite size and the least d002, T300 follows, and TT00 the third. With the increase of heat treatment temperature, the surface state and crystal size of carbon fibers change correspondingly. M40 carbon fiber exhibits the best graphitization property, followed by T300 and then T700. The different microstructure and surface state of different carbon fibers lead to the different microstructures of pyrocarbon and then result in the different thermal conductivities of carbon/carbon composites. The carbon/carbon composite with M40 as preform has the best microstructure in pyrocarbon and the highest thermal conductivity.展开更多
The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-fie...The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our soliton model. The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium, the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium, but the proton-soliton disperses for quite great fluctuation of the ＂force constant and damping coefficient. In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T ≤ 273 K under influences of damping and externally applied electric-field in ice crvstal. This shows that our model is available and appropriate to ice.展开更多
Ni-Ce0.8Sm.2O.9 （Ni-SDC） cermet was selected as anode material for reduced temperature （800℃） solid oxide fuel cells in this study. The influence of NiO powder fabrication methods for Ni-SDC cermets on the electr...Ni-Ce0.8Sm.2O.9 （Ni-SDC） cermet was selected as anode material for reduced temperature （800℃） solid oxide fuel cells in this study. The influence of NiO powder fabrication methods for Ni-SDC cermets on the electrode performance was investigated so that the result obtained can be applied to make high-quality anode. Three kinds of NiO powder were synthesized with a fourth kind being available in the market. Four types of anode precursors were fabricated with these NiO powders and Ce0.8Sm.2O.9 （SDC）, and then were reduced to anode wafers for sequencing measurement. The electrical conductivity of the anodes was measured and the effect ofmicrostructure was investigated. It was found that the anode electrical conductivity depends strongly on the NiO powder morphologies, microstructure of the cermet anode and particle sizes, which are decided by NiO powder preparation technique. The highest electrical conductivity is obtained for anode cermets with NiO powder synthesized by NiCO3-2Ni（OH）2-4H2O or Ni（NO3）2-6H2O decomposition technique.展开更多
Based on constructal theory,the constructs of the leaf-like fins are optimized by taking minimum entransy dissipation rate(for the fixed total thermal current,i.e.,the equivalent thermal resistance) as optimization ob...Based on constructal theory,the constructs of the leaf-like fins are optimized by taking minimum entransy dissipation rate(for the fixed total thermal current,i.e.,the equivalent thermal resistance) as optimization objective.The optimal constructs of the leaf-like fins with minimum dimensionless equivalent thermal resistance are obtained.The results show that there exists an optimal elemental leaf-like fin number,which leads to an optimal global heat conduction performance of the first order leaf-like fin.The Biot number has little effects on the optimal elemental fin number,optimal ratios of length and width of the elemental and first order leaf-like fins;with the increase of the thermal conductivity ratio of the vein and blade,the optimal elemental fin number and optimal ratio of the length and width of the elemental leaf-like fin increase,and the optimal shape of the first order leaf-like fin becomes tubbier.The optimal construct based on entransy dissipation rate minimization is obviously different from that based on maximum temperature difference minimization.The dimensionless equivalent thermal resistance based on entransy dissipation rate minimization is reduced by 11.54% compared to that based on maximum temperature difference minimization,and the global heat conduction performance of the leaf-like fin is effectively improved.For the same volumes of the elemental and first order leaf-like fins,the minimum dimensionless equivalent thermal resistance of the first order of the leaf-like fin is reduced by 30.10% compared to that of the elemental leaf-like fin,and the global heat conduction performance of the first order leaf-like fin is obviously better than that of the elemental leaf-like fin.Essentially,this is because the temperature gradient field of the first order leaf-like fin based on entransy dissipation rate minimization is more homogenous than that of the elemental leaf-like fin.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the leaf-like fin,and can provide some guidelines for the thermal design of the fins from the viewpoint of heat transfer optimization.展开更多
基金Project(201012200233)supported by the Freedom Explore Program of Central South University,China
文摘The microstructure and surface state of three kinds of polyacrylonitrile-based carbon fibers （T700, T300 and M40） before and after high temperature treatment were investigated. Also, the pyrocarbon and thermal conductivity of carbon/carbon composites with different carbon fibers as preform were studied. The results show that M40 carbon fiber has the largest crystallite size and the least d002, T300 follows, and TT00 the third. With the increase of heat treatment temperature, the surface state and crystal size of carbon fibers change correspondingly. M40 carbon fiber exhibits the best graphitization property, followed by T300 and then T700. The different microstructure and surface state of different carbon fibers lead to the different microstructures of pyrocarbon and then result in the different thermal conductivities of carbon/carbon composites. The carbon/carbon composite with M40 as preform has the best microstructure in pyrocarbon and the highest thermal conductivity.
基金The project supported by National Natural Science Foundation of China under Grant No. 90306015
文摘The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our soliton model. The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium, the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium, but the proton-soliton disperses for quite great fluctuation of the ＂force constant and damping coefficient. In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T ≤ 273 K under influences of damping and externally applied electric-field in ice crvstal. This shows that our model is available and appropriate to ice.
文摘Ni-Ce0.8Sm.2O.9 （Ni-SDC） cermet was selected as anode material for reduced temperature （800℃） solid oxide fuel cells in this study. The influence of NiO powder fabrication methods for Ni-SDC cermets on the electrode performance was investigated so that the result obtained can be applied to make high-quality anode. Three kinds of NiO powder were synthesized with a fourth kind being available in the market. Four types of anode precursors were fabricated with these NiO powders and Ce0.8Sm.2O.9 （SDC）, and then were reduced to anode wafers for sequencing measurement. The electrical conductivity of the anodes was measured and the effect ofmicrostructure was investigated. It was found that the anode electrical conductivity depends strongly on the NiO powder morphologies, microstructure of the cermet anode and particle sizes, which are decided by NiO powder preparation technique. The highest electrical conductivity is obtained for anode cermets with NiO powder synthesized by NiCO3-2Ni（OH）2-4H2O or Ni（NO3）2-6H2O decomposition technique.
基金supported by the National Natural Science Foundation of China (Grant No. 51176203)the Natural Science Foundation of Naval University of Engineering (Grant No. HGDYDJJ10011)the Natural Science Foundation for Youngsters of Naval University of Engineering (Grant No. HGDQNJJ10017)
文摘Based on constructal theory,the constructs of the leaf-like fins are optimized by taking minimum entransy dissipation rate(for the fixed total thermal current,i.e.,the equivalent thermal resistance) as optimization objective.The optimal constructs of the leaf-like fins with minimum dimensionless equivalent thermal resistance are obtained.The results show that there exists an optimal elemental leaf-like fin number,which leads to an optimal global heat conduction performance of the first order leaf-like fin.The Biot number has little effects on the optimal elemental fin number,optimal ratios of length and width of the elemental and first order leaf-like fins;with the increase of the thermal conductivity ratio of the vein and blade,the optimal elemental fin number and optimal ratio of the length and width of the elemental leaf-like fin increase,and the optimal shape of the first order leaf-like fin becomes tubbier.The optimal construct based on entransy dissipation rate minimization is obviously different from that based on maximum temperature difference minimization.The dimensionless equivalent thermal resistance based on entransy dissipation rate minimization is reduced by 11.54% compared to that based on maximum temperature difference minimization,and the global heat conduction performance of the leaf-like fin is effectively improved.For the same volumes of the elemental and first order leaf-like fins,the minimum dimensionless equivalent thermal resistance of the first order of the leaf-like fin is reduced by 30.10% compared to that of the elemental leaf-like fin,and the global heat conduction performance of the first order leaf-like fin is obviously better than that of the elemental leaf-like fin.Essentially,this is because the temperature gradient field of the first order leaf-like fin based on entransy dissipation rate minimization is more homogenous than that of the elemental leaf-like fin.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the leaf-like fin,and can provide some guidelines for the thermal design of the fins from the viewpoint of heat transfer optimization.
