Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural ...Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural stability of NaMN was investigated.The physicochemical characterizations suggest that the introduction of Sc and Zn broaden Na^(+) diffusion channels and weaken the Na—O bonds,thereby facilitating the diffusion of sodium ions.Simulations indicate that the Sc and Zn dual-substitution decreases the diffusion barrier of Na-ions and improves the conductivity of the material.The dual-substituted NaMn_(0.5)Ni_(0.4)Sc_(0.04)Zn_(0.04)O_(2)(Na MNSZ44)cathode delivers impressive cycle stability with capacity retention of 71.2%after 200 cycles at 1C and 54.8%after 400 cycles at 5C.Additionally,the full cell paired with hard carbon anode exhibits a remarkable long-term cycling stability,showing capacity retention of 64.1%after 250 cycles at 1C.These results demonstrate that Sc and Zn dual-substitution is an effective strategy to improve the Na^(+) diffusion dynamics and structural stability of NaMN.展开更多
Rockburst has perennially posed a formidable challenge to the stability of underground engineering works,particularly under conditions of deep-seated high stress.This paper provides a comprehensive review of recent ad...Rockburst has perennially posed a formidable challenge to the stability of underground engineering works,particularly under conditions of deep-seated high stress.This paper provides a comprehensive review of recent advancements in on-site research related to rockburst occurrences,covering on-site case analyses,monitoring methodologies,early warning systems,and risk(proneness)evaluation.Initially,the concepts and classifications of rockburst based on on-site understanding were summarized.The influences of structural planes(in various spatial distribution combinations),in-situ stress(particularly magnitude and direction of the principal stress),dynamic disturbances,and excavation profiles on rockburst were thoroughly assessed and discussed through the analysis of published rockburst cases and on-site survey results.Subsequently,a compendium of commonly employed on-site monitoring techniques was outlined,delineating their respective technical attributes.Particular emphasis is accorded to the efficacy of microseismic monitoring technology and its prospective utility in facilitating dynamic rockburst early warning mechanisms.Building upon this foundation,the feasibility of assessing rockburst propensity while considering on-site variables is verified,encompassing the selection and quantitative evaluation of pertinent indicators.Ultimately,a comprehensive synthesis of the paper is presented,alongside the articulation of prospective research goals for the future.展开更多
For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were c...For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were conducted. After freezethaw, nuclear magnetic resonance(NMR) tests and impact loading tests were carried out, from which microscopic damage characteristics of sandstone and dynamic mechanical parameters were obtained. The results indicate that the porosity increases with the increase of cycle number, the rate of porosity growth descends at the beginning of freeze-thaw, yet accelerates after a certain number of cycles. The proportion of pores with different sizes changes dynamically and the multi-scale distribution of pores tends to develop on pore structure with the continuing impact of freeze-thaw and thawing. Dynamic compressive stress-strain curve of sandstone undergoing freeze-thaw can be divided into four phases, and the phase of compaction is inconspicuous compared with the static curve. Elastic modulus and dynamic peak intensity of sandstone gradually decrease with freeze-thaw cycles, while peak strain increases. The higher the porosity is, the more serious the degradation of dynamic intensity is. The porosity is of a polynomial relationship with the dynamic peak intensity.展开更多
In order to investigate the influences of the stoichiometric ratio of La/Mg (increasing La and decreasing Mg on the same mole ratio) on the structure and electrochemical performances of the La-Mg-Ni-based A2B7-type ...In order to investigate the influences of the stoichiometric ratio of La/Mg (increasing La and decreasing Mg on the same mole ratio) on the structure and electrochemical performances of the La-Mg-Ni-based A2B7-type electrode alloy, the as-cast and the annealed ternary Lao.8+xMgo.2_xNi3.5 (x=0-0.05) electrode alloys were prepared. The characterization of electrode alloys by X-ray diffraction (XRD) and scanning electron microscopy (SEM) shows that all the as-cast and the annealed alloys hold two major phases of (La,Mg)2Ni7 and LaNi5 as well as a residual phase of LaNi3. Moreover, the increase of La/Mg ratio brings on a decline of (La,Mg)2Ni7 phase and a rise of LaNi5 and LaNi3 phases. The variation of La/Mg ratio gives rise to an evident change of the electrochemical performances of the alloys. The discharge capacities of the as-cast and the annealed alloys evidently decrease with growing the La/Mg ratio, while the cycle stabilities of the alloys visibly augment under the same condition. Furthermore, the high rate discharge ability (HRD), the electrochemical impedance spectrum (EIS), the Tafel polarization curves, and the potential step measurements all indicate that the electrochemical kinetic properties of the alloy electrodes increase with the La/Mg ratio rising.展开更多
La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-xFex (x=0-0.20) hydrogen storage alloys were synthesized by induction melting and subsequent annealing treatment, and phase structure and electrochemical characteristics were inves...La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-xFex (x=0-0.20) hydrogen storage alloys were synthesized by induction melting and subsequent annealing treatment, and phase structure and electrochemical characteristics were investigated. All alloys consist of a single LaNi5 phase with CaCu5 structure, and the lattice constant a and the cell volume (V) of the LaNi5 phase increase with increasing x value. The maximum discharge capacity gradually decreases from 319.0 mA?h/g (x=0) to 291.9 mA?h/g (x=0.20) with the increase in x value. The high-rate dischargeability at the discharge current density of 1200 mA/g decreases monotonically from 53.1% (x=0) to 44.2% (x=0.20). The cycling stability increases with increasing x from 0 to 0.20, which is mainly ascribed to the improvement of the pulverization resistance.展开更多
Four-, six-, and eight-membered ring silica nanotubes at temperatures from 300 K to 1600 K are relaxed by classical molecular dynamics simulations with three potential models. The simulation results indicate that the ...Four-, six-, and eight-membered ring silica nanotubes at temperatures from 300 K to 1600 K are relaxed by classical molecular dynamics simulations with three potential models. The simulation results indicate that the stability of the end rings of the three silica nanotubes gradually decreases with increase in temperature. The validity of the vibrational features of silica nanotubes is shown by the vibrational density of states. Infrared spectra on the silica nanotubes under different temperatures are investigated. A detailed assignment of each spectral peak to the corresponding vibrational mode of the three nanotubes has been addressed. The results are in good agreement with the other theoretical and experimental展开更多
Rubber isolation is the most mature control technology in practical application, and is widely used by short rigid buildings. However, many high isolation buildings have been built around the world in recent years, wh...Rubber isolation is the most mature control technology in practical application, and is widely used by short rigid buildings. However, many high isolation buildings have been built around the world in recent years, which do not follow the existing criterions and codes. Many researchers began to research the special problems caused by larger height-width ratio isolation structures. The overturning effect of high height-width ratio structures with rubber bearing is firstly studied. Considering the main factors, such as the height-width ratio of structures, type of site, the designed basic acceleration of ground motion and the decouple factor in horizon, computing experiment is defined with the Uniform Design Method, which is also known as designing isolation structure. The forces of the bearing under edge of structures based on the position of the rubber bearing are calculated. The result indicates that the rubber bearings will lose its functionality under very high tension and compressing force of earthquake motion in horizon and vertical, when the height-width ratio is over a certain value. Thus, based on the calculation result of isolation structures defined in the uniform design method, regression analysis is conducted, and also the rubber edge force regression formula are gotten, which has higher correlation and smaller standard deviation. This formula can be used to roughly calculate whether the pull force occurs at the edge of the building. By the edge bearings of isolation structure minimum force formula, the height-width ratio limited value of the isolation structure is deducted when rubber bearing has minimum force of zero.展开更多
In a two-dimensional (219) dusty plasma system, the size of particles is considered under two different interparticle potentials (Yukawa potential and Dressed potential). The structural and dynamical characters a...In a two-dimensional (219) dusty plasma system, the size of particles is considered under two different interparticle potentials (Yukawa potential and Dressed potential). The structural and dynamical characters are investigated by molecular dynamics simulation respectively. The results show that the 2D systems via Yukawa and Dressed potentials have a different critical coupling constant F corresponding to the systems beginning to coagulate and exhibit different crystal configurations. Also we find that the size of particles has little influence on the 2D system's structure characters.展开更多
The interactions between human erythrocyte spectrin(SP) and Pt(II) complexes with different composition and configuration were studied by fluorescence and circular dichroism spectra. The results showed that there are ...The interactions between human erythrocyte spectrin(SP) and Pt(II) complexes with different composition and configuration were studied by fluorescence and circular dichroism spectra. The results showed that there are 4.7×10 2 binding sites of cisplatin(CDDP) in a spectrin tetramer(SPT). Among them, about 70 sites with apparent binding constant K 1】3.47×10 6 were of highest affinity, 1.8×10 2 sites with K 2 = 3.47×10 6 were of high affinity, and other 2.2×10 2 sites with K 3 = 8.77×10 5 were of low affinity. The conformation change of spectrin, depending on the concentration of Pt(II) complex and molar ratio(R) of Pt(II) complex to spectrin, was induced by the binding of Pt(II) complexes. It indicated that the interaction of both CDDP and cis diaquodiamine platinum(DADP) with SP followed a two step first order kinetic process in the first stage (1 h), and the kinetic constants were determined. In the second stage, the induced conformation change, polymerization and depolymerization of SP were probably involved. It was noticed that in the reaction of SP and Pt(II) complexes with 1,2 cyclohexanediammine isomers as chiral carrier ligand, stereo matching played a more important role than the affinity of Pt(II) to thiol groups of SP.展开更多
基金financial support from the National Natural Science Foundation of China(No.52377220)the Natural Science Foundation of Hunan Province,China(No.kq2208265)。
文摘Sc and Zn were introduced into O3-NaMn_(0.5)Ni_(0.5)O_(2)(NaMN)using the combination of solution combustion and solid-state method.The effect of Sc and Zn dual-substitution on Na^(+) diffusion dynamics and structural stability of NaMN was investigated.The physicochemical characterizations suggest that the introduction of Sc and Zn broaden Na^(+) diffusion channels and weaken the Na—O bonds,thereby facilitating the diffusion of sodium ions.Simulations indicate that the Sc and Zn dual-substitution decreases the diffusion barrier of Na-ions and improves the conductivity of the material.The dual-substituted NaMn_(0.5)Ni_(0.4)Sc_(0.04)Zn_(0.04)O_(2)(Na MNSZ44)cathode delivers impressive cycle stability with capacity retention of 71.2%after 200 cycles at 1C and 54.8%after 400 cycles at 5C.Additionally,the full cell paired with hard carbon anode exhibits a remarkable long-term cycling stability,showing capacity retention of 64.1%after 250 cycles at 1C.These results demonstrate that Sc and Zn dual-substitution is an effective strategy to improve the Na^(+) diffusion dynamics and structural stability of NaMN.
基金Project(2023YFB2603602)supported by the National Key Research and Development Program of ChinaProjects(52222810,52178383)supported by the National Natural Science Foundation of China。
文摘Rockburst has perennially posed a formidable challenge to the stability of underground engineering works,particularly under conditions of deep-seated high stress.This paper provides a comprehensive review of recent advancements in on-site research related to rockburst occurrences,covering on-site case analyses,monitoring methodologies,early warning systems,and risk(proneness)evaluation.Initially,the concepts and classifications of rockburst based on on-site understanding were summarized.The influences of structural planes(in various spatial distribution combinations),in-situ stress(particularly magnitude and direction of the principal stress),dynamic disturbances,and excavation profiles on rockburst were thoroughly assessed and discussed through the analysis of published rockburst cases and on-site survey results.Subsequently,a compendium of commonly employed on-site monitoring techniques was outlined,delineating their respective technical attributes.Particular emphasis is accorded to the efficacy of microseismic monitoring technology and its prospective utility in facilitating dynamic rockburst early warning mechanisms.Building upon this foundation,the feasibility of assessing rockburst propensity while considering on-site variables is verified,encompassing the selection and quantitative evaluation of pertinent indicators.Ultimately,a comprehensive synthesis of the paper is presented,alongside the articulation of prospective research goals for the future.
基金Project(2013YQ17046310)supported by the National Key Scientific Instrument and Equipment Development Project of ChinaProject(2013M542138)supported by China Postdoctoral Science FoundationProjects(20130162110010,20130162120012)supported by Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘For understanding the rock microscopic damage and dynamic mechanical properties subjected to recurrent freeze-thaw cycles, experiments for five groups of homogeneous sandstone under different freeze-thaw cycles were conducted. After freezethaw, nuclear magnetic resonance(NMR) tests and impact loading tests were carried out, from which microscopic damage characteristics of sandstone and dynamic mechanical parameters were obtained. The results indicate that the porosity increases with the increase of cycle number, the rate of porosity growth descends at the beginning of freeze-thaw, yet accelerates after a certain number of cycles. The proportion of pores with different sizes changes dynamically and the multi-scale distribution of pores tends to develop on pore structure with the continuing impact of freeze-thaw and thawing. Dynamic compressive stress-strain curve of sandstone undergoing freeze-thaw can be divided into four phases, and the phase of compaction is inconspicuous compared with the static curve. Elastic modulus and dynamic peak intensity of sandstone gradually decrease with freeze-thaw cycles, while peak strain increases. The higher the porosity is, the more serious the degradation of dynamic intensity is. The porosity is of a polynomial relationship with the dynamic peak intensity.
基金Projects(51161015,51371094) supported by the National Natural Science Foundation of China
文摘In order to investigate the influences of the stoichiometric ratio of La/Mg (increasing La and decreasing Mg on the same mole ratio) on the structure and electrochemical performances of the La-Mg-Ni-based A2B7-type electrode alloy, the as-cast and the annealed ternary Lao.8+xMgo.2_xNi3.5 (x=0-0.05) electrode alloys were prepared. The characterization of electrode alloys by X-ray diffraction (XRD) and scanning electron microscopy (SEM) shows that all the as-cast and the annealed alloys hold two major phases of (La,Mg)2Ni7 and LaNi5 as well as a residual phase of LaNi3. Moreover, the increase of La/Mg ratio brings on a decline of (La,Mg)2Ni7 phase and a rise of LaNi5 and LaNi3 phases. The variation of La/Mg ratio gives rise to an evident change of the electrochemical performances of the alloys. The discharge capacities of the as-cast and the annealed alloys evidently decrease with growing the La/Mg ratio, while the cycle stabilities of the alloys visibly augment under the same condition. Furthermore, the high rate discharge ability (HRD), the electrochemical impedance spectrum (EIS), the Tafel polarization curves, and the potential step measurements all indicate that the electrochemical kinetic properties of the alloy electrodes increase with the La/Mg ratio rising.
基金Project (51001043) supported by the National Natural Science Foundation of ChinaProject (NCET2011) supported by Program for New Century Excellent Talents in University, China+4 种基金Project (201104390) supported by China Postdoctoral Science Special FoundationProject (20100470990) supported by China Postdoctoral Science FoundationProject (2012IRTSTHN007) supported by Program for Innovative Research Team (in Science and Technology) in the University of Henan Province, ChinaProject (2011J1003) supported by Baotou Science and Technology Project, ChinaProject (B2010-13) supported by the Doctoral Foundation of Henan Polytechnic University, China
文摘La0.7Ce0.3Ni3.75Mn0.35Al0.15Cu0.75-xFex (x=0-0.20) hydrogen storage alloys were synthesized by induction melting and subsequent annealing treatment, and phase structure and electrochemical characteristics were investigated. All alloys consist of a single LaNi5 phase with CaCu5 structure, and the lattice constant a and the cell volume (V) of the LaNi5 phase increase with increasing x value. The maximum discharge capacity gradually decreases from 319.0 mA?h/g (x=0) to 291.9 mA?h/g (x=0.20) with the increase in x value. The high-rate dischargeability at the discharge current density of 1200 mA/g decreases monotonically from 53.1% (x=0) to 44.2% (x=0.20). The cycling stability increases with increasing x from 0 to 0.20, which is mainly ascribed to the improvement of the pulverization resistance.
文摘Four-, six-, and eight-membered ring silica nanotubes at temperatures from 300 K to 1600 K are relaxed by classical molecular dynamics simulations with three potential models. The simulation results indicate that the stability of the end rings of the three silica nanotubes gradually decreases with increase in temperature. The validity of the vibrational features of silica nanotubes is shown by the vibrational density of states. Infrared spectra on the silica nanotubes under different temperatures are investigated. A detailed assignment of each spectral peak to the corresponding vibrational mode of the three nanotubes has been addressed. The results are in good agreement with the other theoretical and experimental
文摘Rubber isolation is the most mature control technology in practical application, and is widely used by short rigid buildings. However, many high isolation buildings have been built around the world in recent years, which do not follow the existing criterions and codes. Many researchers began to research the special problems caused by larger height-width ratio isolation structures. The overturning effect of high height-width ratio structures with rubber bearing is firstly studied. Considering the main factors, such as the height-width ratio of structures, type of site, the designed basic acceleration of ground motion and the decouple factor in horizon, computing experiment is defined with the Uniform Design Method, which is also known as designing isolation structure. The forces of the bearing under edge of structures based on the position of the rubber bearing are calculated. The result indicates that the rubber bearings will lose its functionality under very high tension and compressing force of earthquake motion in horizon and vertical, when the height-width ratio is over a certain value. Thus, based on the calculation result of isolation structures defined in the uniform design method, regression analysis is conducted, and also the rubber edge force regression formula are gotten, which has higher correlation and smaller standard deviation. This formula can be used to roughly calculate whether the pull force occurs at the edge of the building. By the edge bearings of isolation structure minimum force formula, the height-width ratio limited value of the isolation structure is deducted when rubber bearing has minimum force of zero.
基金The project supported by National Natural Science Foundation of China under Grant Nos. 10547121 and 10175036
文摘In a two-dimensional (219) dusty plasma system, the size of particles is considered under two different interparticle potentials (Yukawa potential and Dressed potential). The structural and dynamical characters are investigated by molecular dynamics simulation respectively. The results show that the 2D systems via Yukawa and Dressed potentials have a different critical coupling constant F corresponding to the systems beginning to coagulate and exhibit different crystal configurations. Also we find that the size of particles has little influence on the 2D system's structure characters.
文摘The interactions between human erythrocyte spectrin(SP) and Pt(II) complexes with different composition and configuration were studied by fluorescence and circular dichroism spectra. The results showed that there are 4.7×10 2 binding sites of cisplatin(CDDP) in a spectrin tetramer(SPT). Among them, about 70 sites with apparent binding constant K 1】3.47×10 6 were of highest affinity, 1.8×10 2 sites with K 2 = 3.47×10 6 were of high affinity, and other 2.2×10 2 sites with K 3 = 8.77×10 5 were of low affinity. The conformation change of spectrin, depending on the concentration of Pt(II) complex and molar ratio(R) of Pt(II) complex to spectrin, was induced by the binding of Pt(II) complexes. It indicated that the interaction of both CDDP and cis diaquodiamine platinum(DADP) with SP followed a two step first order kinetic process in the first stage (1 h), and the kinetic constants were determined. In the second stage, the induced conformation change, polymerization and depolymerization of SP were probably involved. It was noticed that in the reaction of SP and Pt(II) complexes with 1,2 cyclohexanediammine isomers as chiral carrier ligand, stereo matching played a more important role than the affinity of Pt(II) to thiol groups of SP.