The exploration of stable and highly efficient alkaline hydrogen evolution reaction(HER)electrocatalysts is imperative for alkaline water splitting.Herein,Se-doped NiCoP with hierarchical nanoarray structures directly...The exploration of stable and highly efficient alkaline hydrogen evolution reaction(HER)electrocatalysts is imperative for alkaline water splitting.Herein,Se-doped NiCoP with hierarchical nanoarray structures directly grown on carbon cloth(Se-NiCoP/CC)was prepared by hydrothermal reaction and phosphorization/selenization process.The experimental results reveal that Se doping could increase the electrochemical active sites and alter the electronic structure of NiCoP.The optimized Se-NiCoP/CC electrode exhibits outstanding HER activity in alkaline electrolyte,which only needs a low overpotential of 79 mV at the current density of 10 mA/cm^(2).When serving as anode and cathode electrode simultaneously,the Se-NiCoP/CC electrodes achieve current density of 50 mA/cm^(2) at a low voltage of only 1.62 V.This work provides a feasible way to rationally design high active HER electrocatalysts.展开更多
A brief overview of some open questions in general relativity with important consequences for causality theory is presented, aiming to a better understanding of the causal structure of the spacetime. Special attention...A brief overview of some open questions in general relativity with important consequences for causality theory is presented, aiming to a better understanding of the causal structure of the spacetime. Special attention is accorded to the problem of fundamental causal stability conditions. Several questions are raised and some of the potential consequences of recent results regarding the causality problem in general relativity are presented. A key question is whether causality violating regions are locally allowed. The new concept of almost stable causality is introduced; meanwhile, related conditions and criteria for the stability and almost stability of the causal structure are discussed.展开更多
This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal contr...This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal control agent to study the influence of crystalline of ultrafine calcium carbonate. The experimental results show that the different concentrations of CMC as crystal control agent on the morphology and crystal structure of calcium carbonate have obvious effect, which emerge morphology change from square to spherical, crystalline transition from calcite to aragonite. Thus, the results provide experimental data and theoretical basis for the use of different additives, and provide experimental basis and feasible solution for this kind of reaction.展开更多
Shear wave velocity is one of the important dynamic characteristics of soil layers and applied widely in aseismic engineering. In this paper, 500 drill logging data are used to make a linear interpolation based on 0. ...Shear wave velocity is one of the important dynamic characteristics of soil layers and applied widely in aseismic engineering. In this paper, 500 drill logging data are used to make a linear interpolation based on 0. 01° x 0. 01°x lm grid. A shallow 3-D shear wave velocity structure of Tianjin coastal area is obtained. According to the data and geological background, we selected two typical velocity profiles to try to introduce and explain its relationship to basement structure. The results show that the shear wave velocity structure clearly presents the characteristic of stratification and lateral inhomogeneity. Furthermore, the difference of the shear wave structure between tectonic elements is clear and the velocity structure between the two sides of the local or border fault in the Quaternary is disturbed or affected significantly. It intuitively shows that the basement structure and fault activity of this region had good control of sedimentation development and strata formation in the Quaternary period which would have an important effect on engineering seismic and geological condition evaluation.展开更多
The present paper deals with a multiobjective optimization of truss topology by either Sequential Linear Programming （SLP） method or Linear Programming （LP） method. The ground structure approach is often used to s...The present paper deals with a multiobjective optimization of truss topology by either Sequential Linear Programming （SLP） method or Linear Programming （LP） method. The ground structure approach is often used to solve this kind of design problems. In this paper, the topology optimization is formulated as a Multiobjective Optimization Problem （MOP）, which is to find the cross-sectional area of truss members, such that both the total volume of members and the weighted mean compliance are minimized. Based upon the Karush-Kuhn-Tucker conditions （the optimality condition）, the Pareto optimal front of this problem can be obtained theoretically. The truss topology optimization under multiple load cases can be solved by the SLP. On the other hand, the LP such as the Simplex method or the interior point method can be applied to find one of the Pareto optimal solutions of the MOP under single load case. The applications of either the SLP or the LP are illustrated in numerical examples with discussion on characteristics of design results.展开更多
This paper constructs a polyconvex stored energy function, satisfying the null condition, for isotropic compressible elastic materials with given Lame constants. The difference between this stored energy function and ...This paper constructs a polyconvex stored energy function, satisfying the null condition, for isotropic compressible elastic materials with given Lame constants. The difference between this stored energy function and St Venant-Kirchhoff's is a three order term.展开更多
The author proves the Poincard lemma on some （n ＋1）-dimensional corank 1 sub-Riemannian structures, formulating the （n-1）n（n2＋3n-2） necessarily and sufficient- s ly ＂curl-vanishing＂ compatibility conditions...The author proves the Poincard lemma on some （n ＋1）-dimensional corank 1 sub-Riemannian structures, formulating the （n-1）n（n2＋3n-2） necessarily and sufficient- s ly ＂curl-vanishing＂ compatibility conditions. In particular, this result solves partially an open problem formulated by Calin and Chang. The proof in this paper is based on a Poincard lemma stated on l：tiemannian manifolds and a suitable Ceskro-Volterra path in- tegral formula established in local coordinates. As a byproduct, a Saint-Venant lemma is also provided on generic Riemannian manifolds. Some examples are presented on the hyperbolic space and Carnot/Heisenberg groups.展开更多
Polyoxometalates （POMs）, with their attractive topological and electronic properties, have been demonstrated over the last few decades to be efficient catalysts for many reactions. In a new direction, POMs having a ...Polyoxometalates （POMs）, with their attractive topological and electronic properties, have been demonstrated over the last few decades to be efficient catalysts for many reactions. In a new direction, POMs having a purely inorganic framework are now being explored as efficient catalysts for water oxidation. This review focuses on very recent developments of POM-based catalysts for water oxidation to O2. In the very extensive family of POMs, tetra-core sandwich-type Ru- and Co-containing POM complexes, namely [Ru404（OH）2（H20）4（y-SiW10O36）2]10- and [CO4（H2O）2（a-PWgO34）2]10- exhibit the ability to facilitate water oxidation under electrocatalytic and/or photocatalytic conditions. However, it is concluded that much work still needs to be done to explain the catalytic mechanisms and optimize these catalytic systems. In addition, recent trends in using ionic liquids as media to modify the electrolytic environment and enhance water oxidation are highlighted.展开更多
Developing low-cost, high-performance elec- trocatalysts for the oxygen reduction reaction （ORR） is crucial for implementation of fuel cells and metal-air batteries into practical applications. Graphene-based cataly...Developing low-cost, high-performance elec- trocatalysts for the oxygen reduction reaction （ORR） is crucial for implementation of fuel cells and metal-air batteries into practical applications. Graphene-based catalysts have been extensively investigated for ORR in alkaline electrolytes. However, their performance in acidic electrolytes still requires further improvement compared to the Pt/C catalyst. Here we report a self-templating approach to prepare graphene-based sandwich-like porous carbon nanosheets for efficient ORR in both alkaline and acidic electrolytes. Graphene oxides were first used to adsorb m-phenylenediamine molecules which can form a nitrogen-rich polymer network after oxidative poly- merization. Then iron （Fe） salt was introduced into the polymer network and transformed into ORR active Fe-N-C sites along with Fe, FeS, and FEN0.05 nanopartides after pyr- olysis, generating ORR active sandwich-like carbon na- nosheets. Due to the presence of multiple ORR active sites. The as-obtained catalyst exhibited prominent ORR activity with a half-wave potential -30 mV more positive than Pt/C in 0.1 mol L-1 KOH, while the half-wave potential of the catalyst was only -40 mV lower than that of commercial Pt/C in 0.1 mol L-1 HClO4. The unique planar sandwich-like structure could expose abundant active sites for ORR. Meanwhile, the graphene layer and porous structure could simultaneously enhance electrical conductivity and facilitate mass transport. The prominent electrocatalytic activity and durability in both alkaline and acidic electrolytes indicate that these carbon na- nosheets hold great potential as alternatives to precious metal- based catalysts, as demonstrated in zinc-air batteries and proton exchange membrane fuel cells.展开更多
基金Projects(51772086,51872087,51971089)supported by the National Natural Science Foundation of ChinaProject(2018TP1037-202102)supported by Open Fund of Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion,China+1 种基金Project supported by Student National SIT Innovation Program,ChinaProject(2020CB1007)supported by Hunan Joint International Laboratory of Advanced Materials and Technology for Clean Energy,China。
文摘The exploration of stable and highly efficient alkaline hydrogen evolution reaction(HER)electrocatalysts is imperative for alkaline water splitting.Herein,Se-doped NiCoP with hierarchical nanoarray structures directly grown on carbon cloth(Se-NiCoP/CC)was prepared by hydrothermal reaction and phosphorization/selenization process.The experimental results reveal that Se doping could increase the electrochemical active sites and alter the electronic structure of NiCoP.The optimized Se-NiCoP/CC electrode exhibits outstanding HER activity in alkaline electrolyte,which only needs a low overpotential of 79 mV at the current density of 10 mA/cm^(2).When serving as anode and cathode electrode simultaneously,the Se-NiCoP/CC electrodes achieve current density of 50 mA/cm^(2) at a low voltage of only 1.62 V.This work provides a feasible way to rationally design high active HER electrocatalysts.
文摘A brief overview of some open questions in general relativity with important consequences for causality theory is presented, aiming to a better understanding of the causal structure of the spacetime. Special attention is accorded to the problem of fundamental causal stability conditions. Several questions are raised and some of the potential consequences of recent results regarding the causality problem in general relativity are presented. A key question is whether causality violating regions are locally allowed. The new concept of almost stable causality is introduced; meanwhile, related conditions and criteria for the stability and almost stability of the causal structure are discussed.
文摘This article adopts the double decomposition method, select the appropriate experimental conditions and operation process, respectively add appropriate amount of sodium carboxymethyl cellulose （CMC） as crystal control agent to study the influence of crystalline of ultrafine calcium carbonate. The experimental results show that the different concentrations of CMC as crystal control agent on the morphology and crystal structure of calcium carbonate have obvious effect, which emerge morphology change from square to spherical, crystalline transition from calcite to aragonite. Thus, the results provide experimental data and theoretical basis for the use of different additives, and provide experimental basis and feasible solution for this kind of reaction.
基金jointly sponsored by the Special Program of Science and Technology Innovation of Tianjin Municipality ( 07FDZDSF02102 )the Geological Program of Mineral Resources Compensation of Tianjin Municipality,China
文摘Shear wave velocity is one of the important dynamic characteristics of soil layers and applied widely in aseismic engineering. In this paper, 500 drill logging data are used to make a linear interpolation based on 0. 01° x 0. 01°x lm grid. A shallow 3-D shear wave velocity structure of Tianjin coastal area is obtained. According to the data and geological background, we selected two typical velocity profiles to try to introduce and explain its relationship to basement structure. The results show that the shear wave velocity structure clearly presents the characteristic of stratification and lateral inhomogeneity. Furthermore, the difference of the shear wave structure between tectonic elements is clear and the velocity structure between the two sides of the local or border fault in the Quaternary is disturbed or affected significantly. It intuitively shows that the basement structure and fault activity of this region had good control of sedimentation development and strata formation in the Quaternary period which would have an important effect on engineering seismic and geological condition evaluation.
文摘The present paper deals with a multiobjective optimization of truss topology by either Sequential Linear Programming （SLP） method or Linear Programming （LP） method. The ground structure approach is often used to solve this kind of design problems. In this paper, the topology optimization is formulated as a Multiobjective Optimization Problem （MOP）, which is to find the cross-sectional area of truss members, such that both the total volume of members and the weighted mean compliance are minimized. Based upon the Karush-Kuhn-Tucker conditions （the optimality condition）, the Pareto optimal front of this problem can be obtained theoretically. The truss topology optimization under multiple load cases can be solved by the SLP. On the other hand, the LP such as the Simplex method or the interior point method can be applied to find one of the Pareto optimal solutions of the MOP under single load case. The applications of either the SLP or the LP are illustrated in numerical examples with discussion on characteristics of design results.
基金Project supported by the National Natural Science of Foundation of China (No. 19871015)
文摘This paper constructs a polyconvex stored energy function, satisfying the null condition, for isotropic compressible elastic materials with given Lame constants. The difference between this stored energy function and St Venant-Kirchhoff's is a three order term.
文摘The author proves the Poincard lemma on some （n ＋1）-dimensional corank 1 sub-Riemannian structures, formulating the （n-1）n（n2＋3n-2） necessarily and sufficient- s ly ＂curl-vanishing＂ compatibility conditions. In particular, this result solves partially an open problem formulated by Calin and Chang. The proof in this paper is based on a Poincard lemma stated on l：tiemannian manifolds and a suitable Ceskro-Volterra path in- tegral formula established in local coordinates. As a byproduct, a Saint-Venant lemma is also provided on generic Riemannian manifolds. Some examples are presented on the hyperbolic space and Carnot/Heisenberg groups.
基金financed by the Australian Research Council Discovery Scheme and UNSW Science Faculty Research Grants Program
文摘Polyoxometalates （POMs）, with their attractive topological and electronic properties, have been demonstrated over the last few decades to be efficient catalysts for many reactions. In a new direction, POMs having a purely inorganic framework are now being explored as efficient catalysts for water oxidation. This review focuses on very recent developments of POM-based catalysts for water oxidation to O2. In the very extensive family of POMs, tetra-core sandwich-type Ru- and Co-containing POM complexes, namely [Ru404（OH）2（H20）4（y-SiW10O36）2]10- and [CO4（H2O）2（a-PWgO34）2]10- exhibit the ability to facilitate water oxidation under electrocatalytic and/or photocatalytic conditions. However, it is concluded that much work still needs to be done to explain the catalytic mechanisms and optimize these catalytic systems. In addition, recent trends in using ionic liquids as media to modify the electrolytic environment and enhance water oxidation are highlighted.
基金supported by the National Basic Research Program of China (973 Program, 2015CB351903)the National Key Research and Development Program (2017YFA0207301)+1 种基金the National Natural Science Foundation of China (51402282, 21474095 and 21476104)CAS Key Research Program of Frontier Sciences (QYZDB-SSW-SLH018)
文摘Developing low-cost, high-performance elec- trocatalysts for the oxygen reduction reaction （ORR） is crucial for implementation of fuel cells and metal-air batteries into practical applications. Graphene-based catalysts have been extensively investigated for ORR in alkaline electrolytes. However, their performance in acidic electrolytes still requires further improvement compared to the Pt/C catalyst. Here we report a self-templating approach to prepare graphene-based sandwich-like porous carbon nanosheets for efficient ORR in both alkaline and acidic electrolytes. Graphene oxides were first used to adsorb m-phenylenediamine molecules which can form a nitrogen-rich polymer network after oxidative poly- merization. Then iron （Fe） salt was introduced into the polymer network and transformed into ORR active Fe-N-C sites along with Fe, FeS, and FEN0.05 nanopartides after pyr- olysis, generating ORR active sandwich-like carbon na- nosheets. Due to the presence of multiple ORR active sites. The as-obtained catalyst exhibited prominent ORR activity with a half-wave potential -30 mV more positive than Pt/C in 0.1 mol L-1 KOH, while the half-wave potential of the catalyst was only -40 mV lower than that of commercial Pt/C in 0.1 mol L-1 HClO4. The unique planar sandwich-like structure could expose abundant active sites for ORR. Meanwhile, the graphene layer and porous structure could simultaneously enhance electrical conductivity and facilitate mass transport. The prominent electrocatalytic activity and durability in both alkaline and acidic electrolytes indicate that these carbon na- nosheets hold great potential as alternatives to precious metal- based catalysts, as demonstrated in zinc-air batteries and proton exchange membrane fuel cells.
