现代性、自律与画意:论现代主义色彩的结构性生成

现代性为现代主义色彩的自律性提供了思想基础,使现代主义艺术在自律性实践过程中,将色彩从传统的古典艺术律令中解放出来,成为现代主义绘画的表现主题之一,成就了现代艺术的画意品质。这些现代主义色彩的结构性生成原因,证明了色彩可以成为现代艺术的表现主题,而非匹配现实的附属形式。同样,现代主义的色彩更证明了现代主义艺术的本质就是用"形式来再现形式"。

Hydrothermal synthesis, characterization and optical properties of La_2Sn_2O_7:Eu^(3+) micro-octahedra

Pyrochlore structure La2Sn2O7：Eu3＋ microcrystals with uniform octahedron shape were successfully synthesized via a hydrothermal route at 180 °C for 36 h. The crystal structure, particle size, morphologies, and optical properties of the as-synthesized products were investigated by XRD, TEM, SEM, EDS, FT-IR, Raman spectroscopy and PL. The effects of pH of precursor solution, precursor concentration, reaction temperature, and time were investigated. The results reveal that pH of the precursor solution not only plays an important role in determining the phase of the as-synthesized products, but also has a significant influence on the morphologies of the samples. High-quality and uniform octahedrons with an average size of about 700 nm could be easily obtained at the pH value of 12. The possible formation mechanism of octahedral-like La2Sn2O7：Eu3＋ microcrystals was briefly proposed. The photoluminescence spectra show that La2Sn2O7：Eu3＋ micro-octahedra display stronger emission in the range of 582-592 nm compared with the samples with other shapes.

Archaeal and bacterial communities in acid mine drainage from metal-rich abandoned tailing ponds, Tongling, China

To expand knowledge on microbial communities of various metal-rich levels of mine drainage environments in Anhui province, China, the archaeal and bacterial diversities were examined using a PCR-based cloning approach. Eight acid mine water samples were collected from five areas in Tongling. Phylogenetic analyses revealed that bacteria mainly fell into ten divisions, which were Betaproteobacteria, Gammaproteobacteria, Alphaproteobacteria, Deinococcus-Thermus, Nitrospira, Firmicutes, Actinobacteria, Deltaproteobacteria, Bacteroidetes, Chloroflexi. Archaea fell into three phylogenetic divisions, Thermoplasma, Ferroplasma and Thermogymnomonas. The unweighted pair group method with arithmetic mean（UPGMA） cluster analysis based on the microbial communities’ compositions revealed that five samples shared similarity with the dominance of Meiothermus and Thermomonas. Two samples had the preponderant existence of Acidithiobacillus and Leptospirillum. The remaining sample owned higher microbial communities’ diversity with the Shannon-Weaver H up to 2.91. Canonical correlation analysis（CCA） suggested that microbial community structures had great association with p H and the concentration of Hg2＋, Pb2＋, Fe3＋, Cl-, SO2- 4in water.

Synthesis and Crystal Structure of 3,3′-(Hexane-1,6-diyl)bis(1-acetyl-5,5-dimethylhydantoin),a New Inducer of Differentiation

The title compound (C20H30N4O6, Mr = 422.48) was synthesized and its crystal structure was determined by X-ray diffraction method. It crystallizes in the triclinic system, space group P with cell parameters: a = 8.330(2), b = 8.468(2), c = 16.017(3) ? ?= 97.30(3), ?= 92.33(3), ?= 103.94(3)? V = 1084.7(4) ?, Dc = 1.294 g/cm3, Z = 2, F(000) = 452 and ?= 0.096 mm-1. The structure was refined to R = 0.0483 for 3732 observed reflections with I > 2s(I) and wR = 0.1335 for 4828 unique reflections. The hydantoin rings are planar and the two ring planes of one molecule are paralleled to each other.

Syntheses and Crystal Structures of Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)](I) and Bis[oxo-bis(β-ferrocenoylpropionyloxy di-n-propyltin )](II)

Bis-[oxo-bis(p-ferrocenylbenzoxy di-n-propyltin)] I and bis-[oxo-bis(-ferrocenoyl- propionyloxy di-n-propyltin)] II were synthesized and their crystal structures have been determined by X-ray diffraction analysis. The compound I2C6H6 ([(FcC6H4COOSnPr2)2O]22C6H6 or C92H108Fe4O10Sn42C6H6, Mr = 2384.16) is of triclinic, space group P?with a = 12.826(4), b = 13.099(5), c = 17.539(5) ? = 78.229(5), ?= 71.852(5), = 62.746(5)? V = 2483(1) ?, Z = 1, Dc = 1.490 g/cm3, = 0.71073 ? (MoK? =1.611 mm-1 and F(000) = 1128. The structure was refined to R = 0.0491 and wR = 0.1053 for 4690 unique reflections with I > 2(I). The compound IIC6H6 ([(FcCOCH2CH2COOSnPr2)2O]2C6H6 or C80H108Fe4O14Sn4C6H6, Mr = 2115.93) is of triclinic, space group P?with a = 11.260(4), b = 14.126(5), c = 15.961(6) ? = 91.400(6), = 110.654(6), = 104.931(6), V = 2277(1) 3, Z = 1, Dc = 1.510 g/cm3, = 0.71073 ? (MoK? = 1.750 mm-1 and F(000) = 1046. The structure was refined to R = 0.0466 and wR = 0.1138 for 5061 unique reflections with I > 2(I). The two compounds have the similar structures: both are dimers containing centrosymmetric Sn2O2 cores. But there are some differences in the ligating modes between the carboxylate groups and the Sn atoms.

The nonlinear evolution of rogue waves generated by means of wave focusing technique

Generating the rogue waves in offshore engineering is investigated,first of all,to forecast its occurrence to protect the offshore structure from being attacked,to study the mechanism and hydrodynamic properties of rouge wave experimentally as well as the rouge/structure interaction for the structure design.To achieve these purposes demands an accurate wave generation and calculation.In this paper,we establish a spatial domain model of fourth order nonlinear Schrdinger(NLS) equation for describing deep-water wave trains in the moving coordinate system.In order to generate rogue waves in the experimental tank efficiently,we take care that the transient water wave(TWW) determines precisely the concentration of time/place.First we simulate the three-dimensional wave using TWW in the numerical tank and modeling the deepwater basin with a double-side multi-segmented wave-maker in Shanghai Jiao Tong University(SJTU) under the linear superposing theory.To discuss its nonlinearity for guiding the experiment,we set the TWW as the initial condition of the NLS equation.The differences between the linear and nonlinear simulations are presented.Meanwhile,the characteristics of the transient water wave,including water particle velocity and wave slope,are investigated,which are important factors in safeguarding the offshore structures.

Structural properties and generative model of non-giant connected components in social networks

Most previous studies have mainly focused on the analyses of one entire network(graph) or the giant connected components of networks. In this paper, we investigate the disconnected components(non-giant connected component) of some real social networks, and report some interesting discoveries about structural properties of disconnected components. We study three diverse, real networks and compute the significance profile of each component. We discover some similarities in the local structure between the giant connected component and disconnected components in diverse social networks. Then we discuss how to detect network attacks based on the local structure properties of networks. Furthermore, we propose an empirical generative model called i Friends to generate networks that follow our observed patterns.

Theoretical studies on phosphoraniminato derivatives of Keggin-type polyoxometalates [PW_(11)O_(39){M^VNPPh_3}]^(3-)(M = Fe,Ru):Electronic structures and bonding features

Transition metal phosphoraniminato derivatives of Keggin-type polyoxometalates(POMs) are important intermediates in N-transfer reactions.Density functional theory(DFT) has been employed to calculate the electronic structures,bonding features and redox properties of the iron and ruthenium phosphoraniminato derivatives of Keggin-type POMs,[PW11O39{MVNPPh3}] 3-(M = Fe,Ru).Our DFT calculations show that both anions have the same qualitative M-N single bond features.However,the calculations predict that the FeN system possesses a lower energy and more accessible metalnitrogen antibonding orbital than the RuN system.This results in a greater weakening of the Fe-N bond in the reduction process,and thus enhances its N-transfer reactivity.