Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm...Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.展开更多
According to the innate characteristic of four types of furnace, the copper flash continuous smelting (CFCS) furnace can be considered a synthetic reactor of two relatively independent processes: flash matte smelti...According to the innate characteristic of four types of furnace, the copper flash continuous smelting (CFCS) furnace can be considered a synthetic reactor of two relatively independent processes: flash matte smelting process (FMSP) and copper continuous converting process (CCCP). Then, the CFCS thermodynamic model was proposed by establishing the multi-phase equilibrium model of FMSP and the local-equilibrium model of CCCP, respectively, and by combining them through the smelting intermediates. Subsequently, the influences of the furnace structures were investigated using the model on the formation of blister copper, the Fe3O4 behavior, the copper loss in slag and the copper recovery rate. The results show that the type D furnace, with double flues and a slag partition wall, is an ideal CFCS reactor compared with the other three types furnaces. For CFCS, it is effective to design a partition wall in the furnace to make FMSP and CCCP perform in two relatively independent zones, respectively, and to make smelting gas and converting gas discharge from respective flues.展开更多
The landfall process of typhoon Haitang which affected East China seriously was simulated by using the MM5 model and the track, intensity, precipitation and structure of typhoon were successfully reproduced. Then thro...The landfall process of typhoon Haitang which affected East China seriously was simulated by using the MM5 model and the track, intensity, precipitation and structure of typhoon were successfully reproduced. Then through the sensitive test, the effects of terrain were analyzed Results show that the irregular track during the period of typhoon passing through Taiwan and later landfalling at Fujian was in relation to the occurring and developing of orthographic impressed depression. The amount of rainfall was enhanced more than one time and the strength of typhoon was weakened 4 to 5 hPa. It is found that the effect of terrain on the structure of typhoon is limited at low level and is backward in space compared with the one at high level. In addition, the phenomenon that the equivalent temperature in the typhoon's moving direction inclines to the west on the eye of landfall may be concerned with the terrain.展开更多
Besides the cross sections of roadways and the tendency and obliquity of roadway axes, the major controlling factors affecting the height of a collapsing roof include the weak lithological structure of surrounding roc...Besides the cross sections of roadways and the tendency and obliquity of roadway axes, the major controlling factors affecting the height of a collapsing roof include the weak lithological structure of surrounding rocks. This thesis analyzes the effect of two single and weak lithological structures of both sides and the roof on the height of a collapsing roof in a deep soft rock road- way. Using the two-dimensional UDEC3.1 software, a numerical structures of both sides of a roadway and of two weak lithological simulation was carried out on the models of weak lithological structures of roof of different depths. We reconstruct the overall processes from a break-away layer, bending, subsidence and the cracking of a collapsing roof. We also illustrate the distribution characteristics of displacement fields in the surrounding rock after the roof collapse in a deep soft rock roadway. The results of our numerical simulations indicate that the form of a roof collapse is side-expanding when the roadway is a weak structure at both sides The height of the roof collapse is related to the lithological combination of the roof when the roadway is a weak structure of the roof.展开更多
The microscopic response characteristics of nuclear magnetic resonance(NMR) are widely used for characterizing complex pore structures of rocks. Due to the prohibitive NMR experiment cost, numerical simulation was emp...The microscopic response characteristics of nuclear magnetic resonance(NMR) are widely used for characterizing complex pore structures of rocks. Due to the prohibitive NMR experiment cost, numerical simulation was employed as an alternative approach to verify some theoretical aspects of NMR responses. Firstly, the basic principles of pore-scale NMR simulation based on random-walk method(RWM) were introduced. The RWM-simulated results were benchmarked with the analytical results for an ideal spherical pore model. Then, the effects of two numerical parameters, namely diffusion radius and walk numbers, were studied on the simulation accuracy. The simulation method is then applied to various pore models with different pore sizes and pore shapes filled with different fluids to study the microscopic NMR response characteristics. The numerical experiments are useful for understanding and interpreting NMR measurements and the simulation code provides a numerical tool to perform pixel-based digital rock analysis.展开更多
In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflec...In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflect actual situations and facilitate their computation and analyses.Given the importance of model building, further processing methods about traditional seismic interpretation results from Landmark should be studied and the processed result can then be directly used in numerical simulation computations.Through this data conversion procedure, Landmark and FLAC(the international general stress software) are seamlessly connected.Thus, the format conversion between the two systems and the pre-and post-processing in simulation computation is realized.A practical application indicates that this method has many advantages such as simple operation, high accuracy of the element subdivision and high speed, which may definitely satisfy the actual needs of floor grid cutting.展开更多
Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction a...Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.展开更多
Numerical simulations of the deep roadway were carried out through application of the strain-softening constitutive model. Differences between the deep and shallow roadway of the rock bearing structure were analyzed. ...Numerical simulations of the deep roadway were carried out through application of the strain-softening constitutive model. Differences between the deep and shallow roadway of the rock bearing structure were analyzed. Influences of the supporting resistance on the rock bearing structure at the deep roadway were discussed. The results show that there is alternation of strong and weak strength-softening region in the surrounding rock of deep roadway. However, the increase in the supporting resistance cuts down the size of strength-softening region of surrounding rock, decreases its strength-softening degree, and im- proves the stress distribution condition of the surrounding rock mass. It is concluded that the supporting resistance can raise the self-supporting ability of surrounding rock through controlling its strength-softening so as to make the rock bearing structure of deep roadway stable.展开更多
Inspired by the idea that bionic non-smooth surfaces(BNSS) can reduce fluid adhesion and resistance, and the effect of bionic V-riblet non-smooth structure arranged in tire tread pattern grooves surface on anti-hydrop...Inspired by the idea that bionic non-smooth surfaces(BNSS) can reduce fluid adhesion and resistance, and the effect of bionic V-riblet non-smooth structure arranged in tire tread pattern grooves surface on anti-hydroplaning performance was investigated by using computational fluid dynamics(CFD). The physical model of the object(model of V-riblet surface distribution, hydroplaning model) and SST k-ω turbulence model were established for numerical analysis of tire hydroplaning. With the help of a orthogonal table L16(45), the parameters of V-riblet structure design compared to the smooth structure were analyzed, and obtained the priority level of the experimental factors as well as the best combination within the scope of the experiment. The simulation results show that V-riblet structure can reduce water flow resistance by disturbing the eddy movement in boundary layers. Then, the preferred type of V-riblet non-smooth structure was arranged on the bottom of tire grooves for hydroplaning performance analysis. The results show that bionic V-riblet non-smooth structure can effectively increase hydroplaning velocity and improve tire anti-hydroplaning performance. Bionic design of tire tread pattern grooves is a good way to promote anti-hydroplaning performance without increasing additional groove space, so that tire grip performance and roll noise are avoided due to grooves space enlargement.展开更多
In this study,the effect of varied loading ratio(mass of the explosive/mass of flyer plate)on the nature of interface,temperature and pressure developed in aluminum-steel explosive cladding is presented.Increase in th...In this study,the effect of varied loading ratio(mass of the explosive/mass of flyer plate)on the nature of interface,temperature and pressure developed in aluminum-steel explosive cladding is presented.Increase in the loading ratio,R,enhances the pressure developed,kinetic energy utilization and deformation work performed.Interfacial microstructures exhibit the formation of molten layer at few spots,owing to the increase in temperature beyond the melting point of parent alloy.The increase in temperature and the quantum of pressure developed were determined by numerical simulation performed in Ansys AUTODYN by employing smoothed particle hydrodynamics(SPH)method.The positioning of the experimental conditions on the weldability window is presented as well.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52074130)the Engineering Research Center of Resource Utilization of Carbon-containing Waste with Carbon Neutrality,Ministry of Education。
文摘Alkaline water electrolysis(AWE)is the most mature technology for hydrogen production by water electrolysis.Alkaline water electrolyzer consists of multiple electrolysis cells,and a single cell consists of a diaphragm,electrodes,bipolar plates and end plates,etc.The existing industrial bipolar plate channel is concave-convex structure,which is manufactured by complicated and high-cost mold punching.This structure still results in uneven electrolyte flow and low current density in the electrolytic cell,further increasing in energy consumption and cost of AWE.Thereby,in this article,the electrochemical and flow model is firstly constructed,based on the existing industrial concave and convex flow channel structure of bipolar plate,to study the current density,electrolyte flow and bubble distribution in the electrolysis cell.The reliability of the model was verified by comparison with experimental data in literature.Among which,the electrochemical current density affects the bubble yield,on the other hand,the generated bubbles cover the electrode surface,affecting the active specific surface area and ohmic resistance,which in turn affects the electrochemical reaction.The result indicates that the flow velocity near the bottom of the concave ball approaches zero,while the flow velocity on the convex ball surface is significantly higher.Additionally,vortices are observed within the flow channel structure,leading to an uneven distribution of electrolyte.Next,modelling is used to optimize the bipolar plate structure of AWE by simulating the electrochemistry and fluid flow performances of four kinds of structures,namely,concave and convex,rhombus,wedge and expanded mesh,in the bipolar plate of alkaline water electrolyzer.The results show that the expanded mesh channel structure has the largest current density of 3330 A/m^(2)and electrolyte flow velocity of 0.507 m/s in the electrolytic cell.Under the same current density,the electrolytic cell with the expanded mesh runner structure has the smallest potential and energy consumption.This work provides a useful guide for the comprehensive understanding and optimization of channel structures,and a theoretical basis for the design of large-scale electrolyzer.
基金Project (50904027) supported by the National Natural Science Foundation of ChinaProject (2013BAB03B05) supported by the National Key Technology R&D Program of China+1 种基金Project (20133BCB23018) supported by the Foundation for Young Scientist(Jinggang Star)of Jiangxi Province,ChinaProject (2012ZBAB206002) supported by the Natural Science Foundation of Jiangxi Province,China
文摘According to the innate characteristic of four types of furnace, the copper flash continuous smelting (CFCS) furnace can be considered a synthetic reactor of two relatively independent processes: flash matte smelting process (FMSP) and copper continuous converting process (CCCP). Then, the CFCS thermodynamic model was proposed by establishing the multi-phase equilibrium model of FMSP and the local-equilibrium model of CCCP, respectively, and by combining them through the smelting intermediates. Subsequently, the influences of the furnace structures were investigated using the model on the formation of blister copper, the Fe3O4 behavior, the copper loss in slag and the copper recovery rate. The results show that the type D furnace, with double flues and a slag partition wall, is an ideal CFCS reactor compared with the other three types furnaces. For CFCS, it is effective to design a partition wall in the furnace to make FMSP and CCCP perform in two relatively independent zones, respectively, and to make smelting gas and converting gas discharge from respective flues.
文摘The landfall process of typhoon Haitang which affected East China seriously was simulated by using the MM5 model and the track, intensity, precipitation and structure of typhoon were successfully reproduced. Then through the sensitive test, the effects of terrain were analyzed Results show that the irregular track during the period of typhoon passing through Taiwan and later landfalling at Fujian was in relation to the occurring and developing of orthographic impressed depression. The amount of rainfall was enhanced more than one time and the strength of typhoon was weakened 4 to 5 hPa. It is found that the effect of terrain on the structure of typhoon is limited at low level and is backward in space compared with the one at high level. In addition, the phenomenon that the equivalent temperature in the typhoon's moving direction inclines to the west on the eye of landfall may be concerned with the terrain.
基金supported by the National Basic Research Program of China (No2006 CB202200)
文摘Besides the cross sections of roadways and the tendency and obliquity of roadway axes, the major controlling factors affecting the height of a collapsing roof include the weak lithological structure of surrounding rocks. This thesis analyzes the effect of two single and weak lithological structures of both sides and the roof on the height of a collapsing roof in a deep soft rock road- way. Using the two-dimensional UDEC3.1 software, a numerical structures of both sides of a roadway and of two weak lithological simulation was carried out on the models of weak lithological structures of roof of different depths. We reconstruct the overall processes from a break-away layer, bending, subsidence and the cracking of a collapsing roof. We also illustrate the distribution characteristics of displacement fields in the surrounding rock after the roof collapse in a deep soft rock roadway. The results of our numerical simulations indicate that the form of a roof collapse is side-expanding when the roadway is a weak structure at both sides The height of the roof collapse is related to the lithological combination of the roof when the roadway is a weak structure of the roof.
基金Project(265201248) supported by the Fundamental Research Funds for the Central Universities,ChinaProject(41172130) supported by the National Natural Science Foundation of China+2 种基金Project(2011ZX05014-001) supported by the Major State S&T Special Fund,ChinaProject(201205002) supported by the China Scholarship CouncilProject(2011D-5006-0305) supported by the China National Petroleum Co.Innovation Foundation,China
文摘The microscopic response characteristics of nuclear magnetic resonance(NMR) are widely used for characterizing complex pore structures of rocks. Due to the prohibitive NMR experiment cost, numerical simulation was employed as an alternative approach to verify some theoretical aspects of NMR responses. Firstly, the basic principles of pore-scale NMR simulation based on random-walk method(RWM) were introduced. The RWM-simulated results were benchmarked with the analytical results for an ideal spherical pore model. Then, the effects of two numerical parameters, namely diffusion radius and walk numbers, were studied on the simulation accuracy. The simulation method is then applied to various pore models with different pore sizes and pore shapes filled with different fluids to study the microscopic NMR response characteristics. The numerical experiments are useful for understanding and interpreting NMR measurements and the simulation code provides a numerical tool to perform pixel-based digital rock analysis.
基金Projects 50221402, 50490271 and 50025413 supported by the National Natural Science Foundation of Chinathe National Basic Research Program of China (2009CB219603, 2009 CB724601, 2006CB202209 and 2005CB221500)+1 种基金the Key Project of the Ministry of Education (306002)the Program for Changjiang Scholars and Innovative Research Teams in Universities of MOE (IRT0408)
文摘In order to carry out numerical simulation using geologic structural data obtained from Landmark(seismic interpretation system), underground geological structures are abstracted into mechanical models which can reflect actual situations and facilitate their computation and analyses.Given the importance of model building, further processing methods about traditional seismic interpretation results from Landmark should be studied and the processed result can then be directly used in numerical simulation computations.Through this data conversion procedure, Landmark and FLAC(the international general stress software) are seamlessly connected.Thus, the format conversion between the two systems and the pre-and post-processing in simulation computation is realized.A practical application indicates that this method has many advantages such as simple operation, high accuracy of the element subdivision and high speed, which may definitely satisfy the actual needs of floor grid cutting.
基金Project(2010AA065201)supported by the High Technology Research and Development Program of ChinaProject(2013zzts038)supported by the Fundamental Research Funds for the Central Universities of ChinaProject(ZB2011CBBCe1)supported by the Major Program for Aluminum Corporation of China Limited,China
文摘Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.
文摘Numerical simulations of the deep roadway were carried out through application of the strain-softening constitutive model. Differences between the deep and shallow roadway of the rock bearing structure were analyzed. Influences of the supporting resistance on the rock bearing structure at the deep roadway were discussed. The results show that there is alternation of strong and weak strength-softening region in the surrounding rock of deep roadway. However, the increase in the supporting resistance cuts down the size of strength-softening region of surrounding rock, decreases its strength-softening degree, and im- proves the stress distribution condition of the surrounding rock mass. It is concluded that the supporting resistance can raise the self-supporting ability of surrounding rock through controlling its strength-softening so as to make the rock bearing structure of deep roadway stable.
基金Project(51405201)supported by the National Natural Science Foundation of ChinaProject(1291120046)supported by the Jiangsu University Advanced Talents Initial Funding,China+1 种基金Project(QC201303)supported by the Open Fund of Automotive Engineering Key Laboratory,ChinaProject(2014M551509)supported by the China Postdoctoral Science Foundation
文摘Inspired by the idea that bionic non-smooth surfaces(BNSS) can reduce fluid adhesion and resistance, and the effect of bionic V-riblet non-smooth structure arranged in tire tread pattern grooves surface on anti-hydroplaning performance was investigated by using computational fluid dynamics(CFD). The physical model of the object(model of V-riblet surface distribution, hydroplaning model) and SST k-ω turbulence model were established for numerical analysis of tire hydroplaning. With the help of a orthogonal table L16(45), the parameters of V-riblet structure design compared to the smooth structure were analyzed, and obtained the priority level of the experimental factors as well as the best combination within the scope of the experiment. The simulation results show that V-riblet structure can reduce water flow resistance by disturbing the eddy movement in boundary layers. Then, the preferred type of V-riblet non-smooth structure was arranged on the bottom of tire grooves for hydroplaning performance analysis. The results show that bionic V-riblet non-smooth structure can effectively increase hydroplaning velocity and improve tire anti-hydroplaning performance. Bionic design of tire tread pattern grooves is a good way to promote anti-hydroplaning performance without increasing additional groove space, so that tire grip performance and roll noise are avoided due to grooves space enlargement.
文摘In this study,the effect of varied loading ratio(mass of the explosive/mass of flyer plate)on the nature of interface,temperature and pressure developed in aluminum-steel explosive cladding is presented.Increase in the loading ratio,R,enhances the pressure developed,kinetic energy utilization and deformation work performed.Interfacial microstructures exhibit the formation of molten layer at few spots,owing to the increase in temperature beyond the melting point of parent alloy.The increase in temperature and the quantum of pressure developed were determined by numerical simulation performed in Ansys AUTODYN by employing smoothed particle hydrodynamics(SPH)method.The positioning of the experimental conditions on the weldability window is presented as well.