Solid-state wave gyroscope is one kind of high-performance vibrating gyroscopes. The present work develops a new type of solid-state wave gyroscope—a ring vibrating gyroscope driven by piezo-electrodes located on the...Solid-state wave gyroscope is one kind of high-performance vibrating gyroscopes. The present work develops a new type of solid-state wave gyroscope—a ring vibrating gyroscope driven by piezo-electrodes located on the sidewall of the structure. It has advantages of large vibrating amplitude, high energy conversion efficiency and compact structure. The working principle of the piezoelectric ring vibrating gyroscope is based on the inertia effect of the standing wave in the axisymmetric resonator caused by Coriolis force. The finite element method(FEM) analysis has been implemented to characterize the ring type resonator. The prototypal gyroscope was manufactured and has been trimmed by mechanical way. The harmonic response of the ring vibrating gyroscope has been tested. The resonating frequency of the ring type resonator is 3715.6 Hz and the frequency split of the two working modes before trimming was about 5 Hz and was reduced to sub-0.01 Hz after trimming procedure. The Q-factor of the ring type resonator was 2504. Then, the turntable experiment was implemented. The measured scale factor k is 9.24 m V/[(°)·s] and the full scale range of the gyroscope is larger than ±300(°)/s.展开更多
Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency ...Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency of the overall system. This paper presents two optimization strategies to design a predefined multichannel structure of a boost converter which is dedicated to a solar airplane and used to interface PV panels and the battery system. The first strategy is a multi-criterion method that is able to trace the dependency between the converter's efficiency and its power density through the intermediary of the Pareto front. The second method, a mono-criterion approach, maximizes efficiency while respecting the constraint imposed on power density. The mono-criterion method that is applied to maximizing the European efficiency criterion showed that an increase in the number of channels enhanced the quantity of energy collected over a day by increasing the power density of the converter. At the end of the paper, the optimal design calculated was built to give an example of the result obtained by this design methodology. The results of the efficiency measurements made on a realized prototype are presented in this paper.展开更多
Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performanc...Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performance are investigated as a function of precursor solution concentration from 0.1 mol/L to 1.0 mol/L. We demonstrate that the device with 0.1 mol/L precursor concentration of AZO buffer layers enhances the short-circuit current and the fill factor of IOSCs simultaneously. The resulting device shows that the power conversion efficiency is improved by 35.6% relative to that of the 1.0 mol/L device, due to the improved surface morphology and transmittance(300–400 nm) of AZO buffer layer.展开更多
Hybridization of carbon nanotubes (CNT) with graphene provides a promising means of integrating the attributes of both materials, thereby enabling widespread application. Here, we present a method to directly assemb...Hybridization of carbon nanotubes (CNT) with graphene provides a promising means of integrating the attributes of both materials, thereby enabling widespread application. Here, we present a method to directly assemble hybrid CNT- graphene films by a blown bubble method combined with selective substrate annealing. We use polymethylmethacrylate (PMMA) as the polymeric matrix to blow bubbles containing self-assembled multi-walled CNT arrays, and then transform the bubble film into a CNT-graphene hybrid film by thermal annealing on a Cu substrate; PMMA serves as the carbon source for growing single to few-layer graphene among the CNT network until a continuously hybridized structure is formed. Compared to the bare (non-hybridized) CNT networks, the hybrid films exhibit improved electrical conductivity and structural integrity. Our method also enables the fabrication of a multi-walled CNT-Si solar cell, which has high power conversion efficiency, through the assembly of hybrid CNT-graphene structures.展开更多
Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an impo...Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an important structural feature that enables such temperature-dependent aggregation property is the 2nd position branched alkyl chains sitting between two thiophene units.In this report,we demonstrate that an optimal extent of fluorination on the polymer backbone is a second essential structural feature that enables the strong temperature-dependent aggregation property.We compare the properties of three structurally similar polymers with 0,2 or 4 fluorine substitutions in each repeating unit through an in-depth morphological study.We show that the non-fluorinated polymer does not aggregate in solution(0.02 mg mL^(-1) in chlorobenzene) at room temperature,which results in poor polymer crystallinity and extremely large polymer domains.On the other hand,the polymer with four fluorine atoms in each repeating unit exhibits an excessively strong tendency to aggregate,which makes it difficult to process and causes a large domain.Only the polymer with two fluorine atoms in each repeating unit exhibits a suitable extent of temperature-dependent aggregation property.As a result,its blend film achieves a favorable morphology and high power conversion efficiency.This provides another key design rationale for developing donor polymers with suitable temperature-dependent aggregation properties and thus high performance.展开更多
Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling perform...Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).展开更多
Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturb...Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.展开更多
A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was ...A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was firstly fabricated on the FTO(fluorine-doped tin oxide) conducting substrate by an anodization process,then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode.The experiments demonstrated that the nanoporous TiO layer can enhance the light scattering,decrease the contact resistance between TiO2 electrode and FTO,and suppress the recombination of I3-ion with the injected electrons of FTO.The process variables are crucial to obtain the optimized performance of DSSCs.By adopting the optimized process,improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.展开更多
基金Projects(51335011,51275522)supported by the National Natural Science Foundation of ChinaProject(HPCM-2013-08)supported by Key Lab Open Foundation of State Key Laboratory of High Performance(Complex Manufacturing),Central South University,China
文摘Solid-state wave gyroscope is one kind of high-performance vibrating gyroscopes. The present work develops a new type of solid-state wave gyroscope—a ring vibrating gyroscope driven by piezo-electrodes located on the sidewall of the structure. It has advantages of large vibrating amplitude, high energy conversion efficiency and compact structure. The working principle of the piezoelectric ring vibrating gyroscope is based on the inertia effect of the standing wave in the axisymmetric resonator caused by Coriolis force. The finite element method(FEM) analysis has been implemented to characterize the ring type resonator. The prototypal gyroscope was manufactured and has been trimmed by mechanical way. The harmonic response of the ring vibrating gyroscope has been tested. The resonating frequency of the ring type resonator is 3715.6 Hz and the frequency split of the two working modes before trimming was about 5 Hz and was reduced to sub-0.01 Hz after trimming procedure. The Q-factor of the ring type resonator was 2504. Then, the turntable experiment was implemented. The measured scale factor k is 9.24 m V/[(°)·s] and the full scale range of the gyroscope is larger than ±300(°)/s.
文摘Today, energy saving is one of the main objectives for engineers. In the case of mobile applications, energy can be saved by two different ways: decreasing the total masse of the system and increasing the efficiency of the overall system. This paper presents two optimization strategies to design a predefined multichannel structure of a boost converter which is dedicated to a solar airplane and used to interface PV panels and the battery system. The first strategy is a multi-criterion method that is able to trace the dependency between the converter's efficiency and its power density through the intermediary of the Pareto front. The second method, a mono-criterion approach, maximizes efficiency while respecting the constraint imposed on power density. The mono-criterion method that is applied to maximizing the European efficiency criterion showed that an increase in the number of channels enhanced the quantity of energy collected over a day by increasing the power density of the converter. At the end of the paper, the optimal design calculated was built to give an example of the result obtained by this design methodology. The results of the efficiency measurements made on a realized prototype are presented in this paper.
基金supported by the National Natural Science Foundation of China(No.61377031)the Scientific Research Foundation of Zhejiang Ocean University(No.Q1444)
文摘Al-doped ZnO(AZO) has been used as an electron transport and hole blocking buffer layer in inverted organic solar cells(IOSCs). In this paper, the AZO morphology, optical and structural properties and IOSCs performance are investigated as a function of precursor solution concentration from 0.1 mol/L to 1.0 mol/L. We demonstrate that the device with 0.1 mol/L precursor concentration of AZO buffer layers enhances the short-circuit current and the fill factor of IOSCs simultaneously. The resulting device shows that the power conversion efficiency is improved by 35.6% relative to that of the 1.0 mol/L device, due to the improved surface morphology and transmittance(300–400 nm) of AZO buffer layer.
基金This work was financially supported by the National Nature Science Foundation of China (Nos. 91127004 and 51325202).
文摘Hybridization of carbon nanotubes (CNT) with graphene provides a promising means of integrating the attributes of both materials, thereby enabling widespread application. Here, we present a method to directly assemble hybrid CNT- graphene films by a blown bubble method combined with selective substrate annealing. We use polymethylmethacrylate (PMMA) as the polymeric matrix to blow bubbles containing self-assembled multi-walled CNT arrays, and then transform the bubble film into a CNT-graphene hybrid film by thermal annealing on a Cu substrate; PMMA serves as the carbon source for growing single to few-layer graphene among the CNT network until a continuously hybridized structure is formed. Compared to the bare (non-hybridized) CNT networks, the hybrid films exhibit improved electrical conductivity and structural integrity. Our method also enables the fabrication of a multi-walled CNT-Si solar cell, which has high power conversion efficiency, through the assembly of hybrid CNT-graphene structures.
基金supported by the National Basic Research Program of China(2013CB834705)HK JEBN Limited(Hong Kong)+3 种基金the Hong Kong Research Grants Council(T23-407/13-N,N_HKUST623/13,606012)HKUST President's Office through SSTSP scheme(EP201)the National Natural Science Foundation of China(21374090,21504066,21534003,51320105014)supported by the Director,Office of Science,Office of Basic Energy Sciences,of the US Department of Energy under Contract No.DE-AC02-05CH11231
文摘Temperature-dependent aggregation is a key property for some donor polymers to realize favorable bulk-heterojunction(BHJ)morphologies and high-efficiency(>10%) polymer solar cells.Previous studies find that an important structural feature that enables such temperature-dependent aggregation property is the 2nd position branched alkyl chains sitting between two thiophene units.In this report,we demonstrate that an optimal extent of fluorination on the polymer backbone is a second essential structural feature that enables the strong temperature-dependent aggregation property.We compare the properties of three structurally similar polymers with 0,2 or 4 fluorine substitutions in each repeating unit through an in-depth morphological study.We show that the non-fluorinated polymer does not aggregate in solution(0.02 mg mL^(-1) in chlorobenzene) at room temperature,which results in poor polymer crystallinity and extremely large polymer domains.On the other hand,the polymer with four fluorine atoms in each repeating unit exhibits an excessively strong tendency to aggregate,which makes it difficult to process and causes a large domain.Only the polymer with two fluorine atoms in each repeating unit exhibits a suitable extent of temperature-dependent aggregation property.As a result,its blend film achieves a favorable morphology and high power conversion efficiency.This provides another key design rationale for developing donor polymers with suitable temperature-dependent aggregation properties and thus high performance.
基金supported by the National Natural Science Foundation of China(21905148)China Postdoctoral Science Foundation(2019T120567 and 2017M612184)+2 种基金the 1000-Talents Planthe World-Class Discipline Programthe Taishan Scholars Advantageous and Distinctive Discipline Program of Shandong province for supporting the research team of energy storage materials.
文摘Conversion-type anode materials hold great potential for Li+storage applications owing to their high specific capacity,while large volume expansion and poor electrical conductivity limit their rate and cycling performances.Herein,a bimetal ZnMn-based metal-organic framework(ZnMn-MOF)is engineered for in situ conversion of MnO-encapsulated porous carbon(MnO/PC)composite.The templating and activation effects of coordinated Zn endow the converted PC matrix with a highly porous structure.This enhances the compatibility of PC matrix with MnO particles,resulting in the full encapsulation of MnO particles in the PC matrix.More significantly,the PC matrix provides enough void space to buffer the volume change,which fully wraps the MnO without crack or fracture during repeated cycling.As a result,MnO/PC shows high charge storage capability,extraordinary rate performance,and long-term cycling stability at the same time.Thus MnO/PC exhibits high delithiation capacities of 768mA h g^(-1)at 0.1Ag^(-1)and 487mA h g^(-1)at a high rate of 0.7Ag^(-1),combined with an unattenuated cycling performance after 500 cycles at 0.3Ag^(-1).More significantly,MnO/PC demonstrates a well-matched performance with the capacitive activated carbon electrode in a Li-ion capacitor(LIC)full cell.LIC demonstrates a high specific energy of 153.6W h kg^(-1)at 210W kg^(-1),combined with a specific energy of 71.8W h kg^(-1)at a high specific power of 63.0kW kg^(-1).
基金supported by the Agency for Science,Technology and Research (A*STAR) of Singapore (A1983c0036)the Singapore Ministry of Education (MOE2018-T2-2043)A*STAR IAF-ICP 11801E0036。
文摘Antiferromagnetic (AFM) materials have attracted wide attention in spin-orbit torque (SOT)-based spintronic due to its abundant spin-dependent properties and unique advantage of immunity against external field perturbations.To act as the charge-to-spin conversion source in energy-saving spintronic devices,it is of great importance for the AFM material to possess a large spin torque efficiency(ξDL).In this work,using the spin torque ferromagnetic resonance (ST-FMR) technique and a Mn2Au/Ni Fe(Py) bilayer system,we systemically study the ξDLof AFM Mn2Au films with different crystal structures.Compared with polycrystalline Mn2Au with effective ξDL<0.051,we show a much larger ξDLof~0.333 in single-crystal Mn2Au,which arises from the large spin Hall conductivity instead of electrical resistivity.Moreover,with a further contribution of interfacial effects,the effective ξDLof single-crystalline Mn2Au/Py system increases to 0.731,which is more than two times larger than the value of ~0.22 reported for the Mn2Au/CoFeB system.By utilizing the largeξDLof Mn2Au in a perpendicularly magnetized Mn Ga/Mn2Au system,energy-efficient deterministic magnetization switching with a current density at ~10^(6)A cm^(-2)is achieved.Our results reveal a significant potential of Mn2Au as an efficient SOT source and shed light on its application in future AFM material-based SOT integration technology.
基金supported by the National Natural Science Foundation of China (Grant Nos. 60906040,60925015)the Shanghai Nano Project(Grant No. 11nm0500600)
文摘A novel complex nanostructured TiO2 electrode and fabrication process were proposed and demonstrated to improve the performance of dye-sensitized solar cells(DSSCs).In the proposed process,a nanoporous TiO2 layer was firstly fabricated on the FTO(fluorine-doped tin oxide) conducting substrate by an anodization process,then a nanoparticulate TiO2 film was deposited on the nanoporous TiO2 layer by the screen printed method to form the complex nanostructured TiO2 electrode.The experiments demonstrated that the nanoporous TiO layer can enhance the light scattering,decrease the contact resistance between TiO2 electrode and FTO,and suppress the recombination of I3-ion with the injected electrons of FTO.The process variables are crucial to obtain the optimized performance of DSSCs.By adopting the optimized process,improved conversion efficiency of DSSCs was achieved at AM 1.5 sunlight.