海洋超级碳链化合物的结构鉴定方法研究进展

超级碳链化合物特指骨架为一根高度氧化、碳碳链接从头彻尾而成长碳链的天然产物类型。该类化合物主要来源于海洋甲藻,为海洋特有超级聚酮。其柔性多羟基主碳链上拥有数十个手性碳,结构上无可水解的重复单元,立体化学极其复杂。该文总结了超级碳链化合物结构鉴定方法的研究进展及面临的挑战。

Structural damage identification using test static data based on grey system theory

A new structural damage identification method using limited test static displacement based on grey system theory is proposed in this paper. The grey relation coefficient of displacement curvature is defined and used to locate damage in the structure, and an iterative estimation scheme for solving nonlinear optimization programming problems based on the quadratic programming technique is used to identify the damage magnitude. A numerical example of a cantilever beam with single or multiple damages is used to examine the capability of the proposed grey-theory-based method to localize and identify damages. The factors of meas-urement noise and incomplete test data are also discussed. The numerical results showed that the damage in the structure can be localized correctly through using the grey-related coefficient of displacement curvature, and the damage magnitude can be iden-tified with a high degree of accuracy, regardless of the number of measured displacement nodes. This proposed method only requires limited static test data, which is easily available in practice, and has wide applications in structural damage detection.

Identification of structural entities in NdF_3-LiF melts with cryoscopic method

Nd-F species in NdF3-LiF melts were studied using cryoscopic method.Liquidus temperatures of melts of various compositions were determined by differential thermal analysis(DTA).Based on the different model calculations,NdF4- was identified as the most likely Nd-F entity in the melts in which the mole fraction of NdF3 was lower than 20%,considering only one single Nd species in the melt,and which was formed in accordance with Temkin model or Flood model.Then,activities of different components in the melts were researched.The results show that activity of LiF decreases,and that of NdF3 increases with increasing the mole fraction of NdF3.The value of activity coefficient of NdF3 is higher than 1,and that of LiF is lower than 1.

Substructure isolation and damage identification using free responses

Structural health monitoring （SHM） has become a hot and intensively researched field in civil engineering. Thereinto, damage identification play an important role in maintaining structural integrity and safety. Many effective methods have been proposed for damage identification. However, accurate global identification of large real-world structures is not easy due to their com- plex and often unknown boundary conditions, nonlinear components, insensitivity of glohal response to localized damages, etc. Furthermore, global identification often requires lots of sensors and involves large number of unknowns. This is costly, rarely feasible in practice, and usually yields severely ill-conditioned identification problems. Substructuring approach is a possible solution： substructuring methods can focus on local small substructures; they need only a few sensors placed on the substruc- ture and yield smaller and numerically much more feasible identification problems. This paper proposed an improved sub- structure method using local free response for substructure damage identification. The virtual supports are constructed by Sub- structure Isolation Method （SIM） using the linear combination of the substructural responses. The influence of the global errors is isolated by adding the virtual supports on the main degree of freedoms （DOFs） of the substructure. Through the correlation analysis, the substructural modes are selected and used for damage identification of the substructure. A plain model of cable stayed bridge is used for the verification of the proposed method.