The KDOT （Kansas Department of Transportation） is currently adopting MEPDG （mechanistic-empirical pavement design guide） to replace the 1993 AASHTO （American Association of State Highway and Transportation Offici...The KDOT （Kansas Department of Transportation） is currently adopting MEPDG （mechanistic-empirical pavement design guide） to replace the 1993 AASHTO （American Association of State Highway and Transportation Officials） design method. The main objective of this study was to compare flexible pavement design using 1993 AASHTO design guide and MEPDG. Five newly built Superior PERforming Asphalt PAVEments （Superpave）, designed using the 1993 AASHTO Design Guide, were selected as test sections for the design simulation study. Deflection data were collected approximately 8 to 10 weeks after construction using FWD （falling weight deflectometer）. The FWD deflection data were used to back-calculate the pavement layer moduli using three different back-calculation programs. The existing pavement structures were analyzed for a 10-year analysis period. The maximum numbers of years the existing pavement structures will be in a serviceable condition as well as the minimum thicknesses of different layers to serve for 10-years were also determined. Effects of changing subgrade modulus, target distress, and reliability were also investigated. The MEPDG design analysis shows that the 1993 AASHTO Guide-designed flexible pavements do not show the distresses currently observed in Kansas for the 10-year design period. The MEPDG design simulation shows that the thinner the pavement sections, the higher the permanent deformation. The existing pavement structures can serve for more than 20 years as per the MEPDG design analysis if the default failure criteria and nationally-calibrated models are used.展开更多
absorption and phosphorescent mechanism of three Au（III） complexes, Au（2,5-F2C6H3-C^CAC）（C = C-C6H4N（C6Hs）2 [Au25FPh], Au（3,5-F2C6Ha-CACAC）（C=C-C6H4N（C6Hs）2 [Au35FPh], and Au（3,5-F2C6H3-CAC^C）（C=C-C6H4N...absorption and phosphorescent mechanism of three Au（III） complexes, Au（2,5-F2C6H3-C^CAC）（C = C-C6H4N（C6Hs）2 [Au25FPh], Au（3,5-F2C6Ha-CACAC）（C=C-C6H4N（C6Hs）2 [Au35FPh], and Au（3,5-F2C6H3-CAC^C）（C=C-C6H4N（1H- indole）2 [Au35FID], are calculated and compared using density functional theory （DFT） and time-dependent DFT （TDDFT）. The calculated results reveal that enlarging the center CACAC ligand will result in the enhanced LMCT participation. This theoretical contribution allows design of new Au（III） complexes with higher phosphorescence efficiency.展开更多
文摘The KDOT （Kansas Department of Transportation） is currently adopting MEPDG （mechanistic-empirical pavement design guide） to replace the 1993 AASHTO （American Association of State Highway and Transportation Officials） design method. The main objective of this study was to compare flexible pavement design using 1993 AASHTO design guide and MEPDG. Five newly built Superior PERforming Asphalt PAVEments （Superpave）, designed using the 1993 AASHTO Design Guide, were selected as test sections for the design simulation study. Deflection data were collected approximately 8 to 10 weeks after construction using FWD （falling weight deflectometer）. The FWD deflection data were used to back-calculate the pavement layer moduli using three different back-calculation programs. The existing pavement structures were analyzed for a 10-year analysis period. The maximum numbers of years the existing pavement structures will be in a serviceable condition as well as the minimum thicknesses of different layers to serve for 10-years were also determined. Effects of changing subgrade modulus, target distress, and reliability were also investigated. The MEPDG design analysis shows that the 1993 AASHTO Guide-designed flexible pavements do not show the distresses currently observed in Kansas for the 10-year design period. The MEPDG design simulation shows that the thinner the pavement sections, the higher the permanent deformation. The existing pavement structures can serve for more than 20 years as per the MEPDG design analysis if the default failure criteria and nationally-calibrated models are used.
基金financially supported by the National Natural Science Foundation of China (20973076, 21003057 and 21173096)Specialized Research Fund for the Doctoral Program of Higher Education(20110061110018)
文摘absorption and phosphorescent mechanism of three Au（III） complexes, Au（2,5-F2C6H3-C^CAC）（C = C-C6H4N（C6Hs）2 [Au25FPh], Au（3,5-F2C6Ha-CACAC）（C=C-C6H4N（C6Hs）2 [Au35FPh], and Au（3,5-F2C6H3-CAC^C）（C=C-C6H4N（1H- indole）2 [Au35FID], are calculated and compared using density functional theory （DFT） and time-dependent DFT （TDDFT）. The calculated results reveal that enlarging the center CACAC ligand will result in the enhanced LMCT participation. This theoretical contribution allows design of new Au（III） complexes with higher phosphorescence efficiency.
