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草炭溶解态有机物质与Cu^(2+)、Cd^(2+)络合稳定性的研究 被引量:16
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作者 蒋疆 王果 +1 位作者 陈芳育 林亮志 《土壤与环境》 CSCD 2002年第2期116-120,共5页
研究了由草炭提取的胡敏酸(HA)、富里酸(FA)、水溶解态有机物质(WSOM)的基团特征,分子量分布及其与Cu2+、Cd2+两种金属离子之间的络合稳定性。对HA、FA及WSOM的红外光谱研究显示三者的官能团组成相似,只是含量略有不同。固态13C-NMR对HA... 研究了由草炭提取的胡敏酸(HA)、富里酸(FA)、水溶解态有机物质(WSOM)的基团特征,分子量分布及其与Cu2+、Cd2+两种金属离子之间的络合稳定性。对HA、FA及WSOM的红外光谱研究显示三者的官能团组成相似,只是含量略有不同。固态13C-NMR对HA、FA及WSOM结构特征的描述以及水相凝胶色谱法对三种有机质样品的分子量及分子量分布的测定结果显示HA分子最大且含有大量的长链烷烃,而FA分子小得多,结构以碳水化合物及多糖为主,WSOM的分子量略低于FA,结构与FA相近。离子交换平衡法对三种有机质样品与Cu2+、Cd2+的络合配位数和稳定常数的测定结果显示两种介质条件下络合配位数(x)、络合稳定常数(logk)的次序均为:Cu2+>Cd2+;同一介质条件下,对不同有机质而言均满足:M-HA>M-FA>M-WSOM。 展开更多
关键词 草炭 溶解态有机物质 CU^2+ CD^2+ 络合稳定性 胡敏酸 富里酸 稳定常数 配位数 重金属离子
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草炭溶解态有机物质与Pb^(2+)、Zn^(2+)络合稳定性研究
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作者 蒋疆 王果 陈芳育 《福建农业学报》 CAS 2002年第2期125-127,共3页
用离子交换平衡法对两种有机质样品与Pb2+、Zn2+的络合配位数和稳定常数测定结果表明,两种介质条件下,金属离子与HA、FA络合稳定常数序列均为Pb2+>Zn2+,但络合配位数序列相反。随介质pH的增大,络合配位数、稳定常数均有不同程度的增... 用离子交换平衡法对两种有机质样品与Pb2+、Zn2+的络合配位数和稳定常数测定结果表明,两种介质条件下,金属离子与HA、FA络合稳定常数序列均为Pb2+>Zn2+,但络合配位数序列相反。随介质pH的增大,络合配位数、稳定常数均有不同程度的增大。同种金属离子与不同有机质的络合稳定性均满足:M—HA>M—FA。 展开更多
关键词 草炭 溶解态 有机物质 PB^2+ ZN^2+ 络合稳定性 胡敏酸 富里酸 稳定常数 配位数 金属离子
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锂铍络合物稳定性与花岗伟晶岩中锂铍“差异跃迁”耦合关联 被引量:2
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作者 洪涛 翟明国 +5 位作者 王岳军 刘星成 徐兴旺 高俊 胡明曦 马靖 《地学前缘》 EI CAS CSCD 北大核心 2023年第5期93-105,共13页
伟晶岩型锂铍矿床是国家紧缺的战略性金属锂铍的重要供给矿床类型。但伟晶岩成因中深熔作用产生熔体量少、萃取锂铍效率低;岩浆结晶分异能否高度富集和高效萃取锂铍也存在争议;随着富锂铍的硅酸盐熔体、熔体-热液不混溶作用的发现,岩浆... 伟晶岩型锂铍矿床是国家紧缺的战略性金属锂铍的重要供给矿床类型。但伟晶岩成因中深熔作用产生熔体量少、萃取锂铍效率低;岩浆结晶分异能否高度富集和高效萃取锂铍也存在争议;随着富锂铍的硅酸盐熔体、熔体-热液不混溶作用的发现,岩浆不混溶作用可能也是新的成因机制。近年来,针对伟晶岩型锂铍矿床的熔体至热液阶段成矿过程的研究主要集中在:花岗伟晶岩全岩地球化学特征解析;造岩矿物(云母、石英、长石等)与矿石矿物(绿柱石等)的精细微区元素地球化学变化规律的总结;造岩矿物、矿石矿物及副矿物(石榴石等)中熔体-热液包裹体矿物学-地球化学特征解析。但伟晶岩矿床中熔体、流体包裹体类型复杂,且与矿床形成时代也没有明显关联性。锂铍在熔体-热液相间的分配行为和分配过程,以及运移锂铍的络合物稳定性差异是深入认识锂铍超常富集机制的关键。然而,对锂铍在熔体-热液相间分配行为的研究仍然相对薄弱,针对运移锂铍的络合物的稳定性也未开展研究。我们设计了不同矿化溶液的pH值、不同钙和铝含量影响下锂铍络合物结晶锂铍的实验,发现锂铍元素在以上3种不同条件下存在明显的差异性结晶沉淀行为:(1)pH对铍络合物的稳定性控制比锂络合物更明显;(2)在pH值不变的条件下,铝的加入促进了铍的沉淀,却影响锂的沉淀;(3)钙的加入对锂沉淀的影响没有对铍沉淀的影响大。后续将从实验地球化学角度(高温高压实验模拟)剖析锂铍各自络合物的类型、稳定性受控因素,以期建立“锂、铍络合物失稳-成矿”新机制。 展开更多
关键词 锂铍矿床 熔体-热液 锂铍络合稳定性 差异成矿
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靛蓝电化学染色配体络合体系稳定性的研究 被引量:2
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作者 汪康康 李晓燕 姚继明 《印染助剂》 CAS 北大核心 2019年第4期27-31,共5页
针对目前靛蓝电化学染色普遍采用铁-葡萄糖酸钠-三乙醇胺络合体系存在稳定性差、电流效率低且缺乏络合物稳定性具体表征手段等问题,采用具有较强耐碱性和电导性的Abal B和葡萄糖酸钠作为配体与硫酸亚铁、硫酸铁形成络合体系,通过正交实... 针对目前靛蓝电化学染色普遍采用铁-葡萄糖酸钠-三乙醇胺络合体系存在稳定性差、电流效率低且缺乏络合物稳定性具体表征手段等问题,采用具有较强耐碱性和电导性的Abal B和葡萄糖酸钠作为配体与硫酸亚铁、硫酸铁形成络合体系,通过正交实验结合均值和极差分析确定不同质量浓度配体对硫酸铁及硫酸亚铁络合值、CV值及浊度的影响。结果表明:氢氧化钠质量浓度对二价铁离子络合物稳定性的影响最大,葡萄糖酸钠质量浓度对三价铁离子络合物稳定性的影响最大。进一步采用灰色聚类分析法优化了不同价态铁离子络合体系中各组分质量浓度。 展开更多
关键词 铁离子 配体 络合稳定性 正交设计 灰色聚类分析法
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一种适用于非纯水聚驱聚合物溶液的新型络合剂 被引量:6
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作者 何树山 张新军 +1 位作者 党庆功 毕雪亮 《钻井液与完井液》 CAS 北大核心 2002年第1期13-14,共2页
聚合物驱油已经成为部分油田稳产、挖潜、提高原油采收率的主要措施。但油田使用的聚合物抗盐性能比较差,因此配制聚合物驱油溶液用水必须经过严格处理,这样增大了处理的综合费用。为了降低聚驱中聚丙烯酰胺溶液的配制成本,室内合成了... 聚合物驱油已经成为部分油田稳产、挖潜、提高原油采收率的主要措施。但油田使用的聚合物抗盐性能比较差,因此配制聚合物驱油溶液用水必须经过严格处理,这样增大了处理的综合费用。为了降低聚驱中聚丙烯酰胺溶液的配制成本,室内合成了一种廉价、高络合能力络合剂DG-1。通过对比实验,评价了络合剂DG-1在聚丙烯酰胺溶液中的络合能力,以及络合剂的抗温稳定性、抗酸性、抗碱性和抗盐能力。结果表明,DG-1与EDTA的络合能力比为3:1,DG-1具有良好的络合稳定性,耐酸能力和耐碱能力强,适用于中性、弱碱水质配制条件;加入络合剂DG-1的聚合物溶液粘度稳定性好,DG-1形成的络合物耐温性能较强,可用于地面聚驱中聚合物溶液的配制,充分利用地表非饮用水或油田分离水,对节约水资源,保护环境有着重要意义。 展开更多
关键词 聚合物溶液 络合 络合能力 络合稳定性 提高采收率 石油开采 聚合物驱
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一种新的结合型加脂剂的合成与性质 被引量:1
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作者 袁淑军 方海林 严金龙 《皮革化工》 2005年第2期18-20,共3页
以对甲酚、硬脂酸、氯磺酸等为原料,经过酯化、重排、磺化等反应合成了一种含邻酚酮结构的新型结合型加脂剂。其性质实验结果表明:该加脂剂具有较高的乳化稳定性、与Cr3+ 等离子具有很好的络合性能,对皮革具有良好的加脂性能。
关键词 结合型加脂剂 合成 乳化 络合稳定性
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Structural characteristics and properties of polyurethane modified TDE-85/MeTHPA epoxy resin with interpenetrating polymer networks 被引量:2
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作者 李芝华 黄耀鹏 +1 位作者 任冬燕 郑子樵 《Journal of Central South University of Technology》 EI 2008年第3期305-308,共4页
Diglycidyl-4,5-epoxycyclohexane-1,2-dicarboxylate(TDE-85)/methyl tetrahydrophthalic anhydride (MeTHPA) epoxy resin was modified with polyurethane(PU) and the interpenetrating polymer networks(IPNs) of PU-modified TDE-... Diglycidyl-4,5-epoxycyclohexane-1,2-dicarboxylate(TDE-85)/methyl tetrahydrophthalic anhydride (MeTHPA) epoxy resin was modified with polyurethane(PU) and the interpenetrating polymer networks(IPNs) of PU-modified TDE-85/MeTHPA resin were prepared. The structural characteristics and properties of PU-modified TDE-85/MeTHPA resin were investigated by Fourier transform infrared(FTIR) spectrum,emission scanning electron microscopy(SEM) and thermogravimetry(TG). The results indicate that epoxy polymer network (Ⅰ) and polyurethane polymer network (Ⅱ) of the modified resin can be obtained and the networks (Ⅰ) and (Ⅱ) interpenetrate and tangle highly each other at the phase interface. The micro morphology presents heterogeneous structure. The integrative properties of PU-modified TDE-85/MeTHPA epoxy resin are improved obviously. The PU-modified TDE-85/ MeTHPA resin's tensile strength reaches 69.39 MPa,the impact strength reaches 23.56 kJ/m,the temperature for the system to lose 1% mass (t1%) is 300 ℃,and that for the system to lose 50% mass (t50%) is 378 ℃. Compared with those of TDE-85/MeTHPA resin,the tensile strength,impact strength,t1% and t50% of the PU-modified resin increases by 48%,115%,30 ℃,11 ℃,respectively. The PU-modified TDE-85/MeTHPA resin has the structure characteristics and properties of interpenetrating polymer networks. 展开更多
关键词 POLYURETHANE epoxy resin interpenetrating polymer networks tensile strength impact strength thermal stability
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Rapid Regeneration of Chelated Iron Desulfurization Solution Using Electrochemical Reactor with Rotating Cylindrical Electrodes 被引量:1
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作者 于永 刘有智 祁贵生 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第2期136-140,共5页
A new electrochemical reactor with rotating cylindrical electrodes was designed and used to increase the regeneration efficiency of chelated iron desulfurization solution.The influence of operating parameters,such as ... A new electrochemical reactor with rotating cylindrical electrodes was designed and used to increase the regeneration efficiency of chelated iron desulfurization solution.The influence of operating parameters,such as the rotation speed of electrode,voltage,and inlet air and liquid flow rates,on the regeneration rate was investigated.Compared with the traditional tank-type reactor,the regeneration rate with the new electrochemical reactor was increased significantly.Under the optimum conditions,the regeneration rate was increased from 45.3%to 84.8%.Experimental results of continuous operation indicated that the new electrochemical regeneration method had some merits including higher regeneration efficiency,smaller equipment size and good stability in operation. 展开更多
关键词 regeneration^desulfurization chelated iron ELECTROCHEMISTRY reactor
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Synchronization criteria based on a general complex dynamical network model
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作者 章剑林 王昌建 《Journal of Chongqing University》 CAS 2008年第3期221-227,共7页
Many complex dynamical networks display synchronization phenomena. We introduce a general complex dynamical network model. The model is equivalent to a simple vector model of adopting the Kronecker product. Some synch... Many complex dynamical networks display synchronization phenomena. We introduce a general complex dynamical network model. The model is equivalent to a simple vector model of adopting the Kronecker product. Some synchronization criteria,including time-variant networks and time-varying networks,are deduced based on Lyapunov's stability theory,and they are proven on the condition of obtaining a certain synchronous solution of an isolated cell. In particular,the inner-coupling matrix directly determines the synchronization of the time-invariant network; while for a time-varying periodic dynamical network,the asymptotic stability of a synchronous solution is determined by a constant matrix which is related to the fundamental solution matrices of the linearization system. Finally,illustrative examples are given to validate the results. 展开更多
关键词 SYNCHRONIZATION complex network stable matrix
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Exponential Synchronization of Uncertain Complex Dynamical Networks with Delay Coupling
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作者 王立夫 井元伟 孔芝 《Communications in Theoretical Physics》 SCIE CAS CSCD 2010年第3期529-534,共6页
This paper studies the global exponential synchronization of uncertain complex delayed dynamical networks. The network model considered is general dynamical delay networks with unknown network structure and unknown co... This paper studies the global exponential synchronization of uncertain complex delayed dynamical networks. The network model considered is general dynamical delay networks with unknown network structure and unknown coupling functions but bounded. Novel delay-dependent linear controllers are designed via the Lyapunov stability theory. Especially, it is shown that the controlled networks are globally exponentially synchronized with a given convergence rate. An example of typical dynamical network of this class, having the Lorenz system at each node, has been used to demonstrate and verify the novel design proposed. And, the numerical simulation results show the effectiveness of proposed synchronization approaches. 展开更多
关键词 exponential synchronization uncertain complex dynamical networks coupling delays decentral- ized control
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Lag Synchronization Between Two Coupled Networks via Open-Plus-Closed-Loop and Adaptive Controls
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作者 胡桐春 吴永庆 李时兴 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第1期33-38,共6页
In this paper,we study lag synchronization between two coupled networks and apply two types of control schemes,including the open-plus-closed-loop(OPCL) and adaptive controls.We then design the corresponding control a... In this paper,we study lag synchronization between two coupled networks and apply two types of control schemes,including the open-plus-closed-loop(OPCL) and adaptive controls.We then design the corresponding control algorithms according to the OPCL and adaptive feedback schemes.With the designed controllers,we obtain two theorems on the lag synchronization based on Lyapunov stability theory and Barbalat's lemma.Finally we provide numerical examples to show the effectiveness of the obtained controllers and see that the adaptive control is stronger than the OPCL control when realizing the lag synchronization between two coupled networks with different coupling structures. 展开更多
关键词 lag synchronization open-plus--closed-loop control adaptive control
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Comparison of Synchronization Ability of Four Types of Regular Coupled Networks
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作者 王海侠 陆启韶 石霞 《Communications in Theoretical Physics》 SCIE CAS CSCD 2012年第11期681-685,共5页
We investigate the synchronization ability of four types of regular coupled networks. By introducing the proper error variables and Lyapunov functions, we turn the stability of synchronization manifold into that of nu... We investigate the synchronization ability of four types of regular coupled networks. By introducing the proper error variables and Lyapunov functions, we turn the stability of synchronization manifold into that of null solution of error equations, further, into the negative definiteness of some symmetric matrices, thus we get the sufficient synchronization stability conditions. To test the valid of the results, we take the Chua's circuit as an example. Although the theoretical synchronization thresholds appear to be very conservative, they provide new insights about the influence of topology and scale of networks on synchronization, and that the theoretical results and our numerical simulations are consistent. 展开更多
关键词 SYNCHRONIZATION regular coupled networks Lipschitz condition Lyapunov function
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